Yanze Wang, Biyun Ren, Weilin Zheng, Dengfeng Peng, Feng Wang
{"title":"合成低声子能量的 SrZnOSe 晶体以增强近红外机械发光能力","authors":"Yanze Wang, Biyun Ren, Weilin Zheng, Dengfeng Peng, Feng Wang","doi":"10.1002/adma.202406899","DOIUrl":null,"url":null,"abstract":"Near-infrared (NIR) light is promising for bioimaging and information technology due to its high penetration ability and resistance to interference with environmental radiation. Here, a new class of lanthanide-doped SrZnOSe crystals are developed for the self-sustainable generation of NIR emissions under mechanical excitation. It is shown that the SrZnOSe crystals render ≈5-fold stronger NIR emissions than the well-established CaZnOS due to the low phonon energies of the selenide host, as confirmed by Raman spectroscopy. The potential utility of the crystals is demonstrated by integration with a mouthguard, which can generate bright NIR emissions by bite force to transmit encrypted optical signals through thick tissues (up to 8 mm) in ambient environments. The findings provide a powerful addition to the toolbox of self-recovery mechanoluminescent materials and open new possibilities for applied research.","PeriodicalId":114,"journal":{"name":"Advanced Materials","volume":null,"pages":null},"PeriodicalIF":27.4000,"publicationDate":"2024-11-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Synthesis of SrZnOSe Crystals with Low Phonon Energy for Enhancing Near-Infrared Mechanoluminescence\",\"authors\":\"Yanze Wang, Biyun Ren, Weilin Zheng, Dengfeng Peng, Feng Wang\",\"doi\":\"10.1002/adma.202406899\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Near-infrared (NIR) light is promising for bioimaging and information technology due to its high penetration ability and resistance to interference with environmental radiation. Here, a new class of lanthanide-doped SrZnOSe crystals are developed for the self-sustainable generation of NIR emissions under mechanical excitation. It is shown that the SrZnOSe crystals render ≈5-fold stronger NIR emissions than the well-established CaZnOS due to the low phonon energies of the selenide host, as confirmed by Raman spectroscopy. The potential utility of the crystals is demonstrated by integration with a mouthguard, which can generate bright NIR emissions by bite force to transmit encrypted optical signals through thick tissues (up to 8 mm) in ambient environments. The findings provide a powerful addition to the toolbox of self-recovery mechanoluminescent materials and open new possibilities for applied research.\",\"PeriodicalId\":114,\"journal\":{\"name\":\"Advanced Materials\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":27.4000,\"publicationDate\":\"2024-11-12\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Advanced Materials\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://doi.org/10.1002/adma.202406899\",\"RegionNum\":1,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Advanced Materials","FirstCategoryId":"88","ListUrlMain":"https://doi.org/10.1002/adma.202406899","RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Synthesis of SrZnOSe Crystals with Low Phonon Energy for Enhancing Near-Infrared Mechanoluminescence
Near-infrared (NIR) light is promising for bioimaging and information technology due to its high penetration ability and resistance to interference with environmental radiation. Here, a new class of lanthanide-doped SrZnOSe crystals are developed for the self-sustainable generation of NIR emissions under mechanical excitation. It is shown that the SrZnOSe crystals render ≈5-fold stronger NIR emissions than the well-established CaZnOS due to the low phonon energies of the selenide host, as confirmed by Raman spectroscopy. The potential utility of the crystals is demonstrated by integration with a mouthguard, which can generate bright NIR emissions by bite force to transmit encrypted optical signals through thick tissues (up to 8 mm) in ambient environments. The findings provide a powerful addition to the toolbox of self-recovery mechanoluminescent materials and open new possibilities for applied research.
期刊介绍:
Advanced Materials, one of the world's most prestigious journals and the foundation of the Advanced portfolio, is the home of choice for best-in-class materials science for more than 30 years. Following this fast-growing and interdisciplinary field, we are considering and publishing the most important discoveries on any and all materials from materials scientists, chemists, physicists, engineers as well as health and life scientists and bringing you the latest results and trends in modern materials-related research every week.