颗粒界面结构与冷喷 CuCrZr 沉积物性能的关系

IF 6.3 2区 材料科学 Q2 CHEMISTRY, PHYSICAL Applied Surface Science Pub Date : 2024-11-14 DOI:10.1016/j.apsusc.2024.161794
Min Yu, Yunzhe Zhang, Peiyuan Lv, Hui Chen
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引用次数: 0

摘要

冷喷技术具有明显的塑性变形特征,因此被认为是制造 CuCrZr 沉积物的一种有前途的技术。在本研究中,通过探索界面微观结构与机械性能和热性能之间的相关性,验证了这种技术的可行性。利用电子反向散射衍射、纳米压痕、粘合剪切强度和热传导测试,根据颗粒界面特征、铬和锆析出物以及机械和热性能,尝试评估结构与性能之间的相关性。结果表明,退火热处理通过超细晶粒的恢复和生长重建了颗粒界面,从而降低了孔隙率,提高了剪切强度和韧性。再加上细晶粒的再结晶以及氧化铬和 CuxZry 相的沉淀强化,退火沉积物中因加工硬化释放而导致的硬度下降可以得到补偿,从而表现出良好的热稳定性。最后,孔隙率的降低和界面结合力的增强共同导致了退火镀层导热率的提高。因此,冷喷涂和退火热处理相结合的技术可能是平衡 CuCrZr 强度和导热性的一种潜在解决方案。
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Relationship between particle interface structure and performance of cold sprayed CuCrZr deposit
Cold spraying is considered as a promising technique for fabricating CuCrZr deposits attributed to its distinct plastic deformation feature. In the present study, the feasibility of this technique is validated through exploring correlations between the interface microstructure with mechanical and thermal properties. Assessment of structure–property correlations was attempted based on particle interface characteristics, together with Cr and Zr precipitates, and mechanical and thermal properties using electron backscatter diffraction, nanoindentation, adhesive shear strength and thermal conduction tests. Results show that annealing heat treatment reconstructs the particle interface through recovery and growth of ultrafine grains, leading to the reduction of porosity and enhancement of shear strength and toughness. Coupled with the re-crystallized fine grains and precipitation strengthening of the Cr oxide and CuxZry phase, the decrease in hardness due to the release of work hardening in the annealed deposits could be compensated, thereby demonstrating good thermal stability. Finally, the combination of decreased porosity and strengthened interface bonding causes the increased heat conductivity of the annealed deposits. Therefore, the combined technique of cold spraying and annealing heat treatment may be a potential solution for balancing the strength and thermal conductivity of CuCrZr.
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来源期刊
Applied Surface Science
Applied Surface Science 工程技术-材料科学:膜
CiteScore
12.50
自引率
7.50%
发文量
3393
审稿时长
67 days
期刊介绍: Applied Surface Science covers topics contributing to a better understanding of surfaces, interfaces, nanostructures and their applications. The journal is concerned with scientific research on the atomic and molecular level of material properties determined with specific surface analytical techniques and/or computational methods, as well as the processing of such structures.
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