Anke Blume, Frances van Elburg, Fabian Grunert, Auke Talma
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Since Charles Goodyear discovered the method of sulfur curing Natural Rubber in 1839, many studies have been carried out to understand its mechanism. Currently, the broadly accepted mechanism includes an activated accelerator complex formed by Zinc oxide, stearic acid, accelerators and sulfur. Furthermore, it is also broadly accepted that the coupling of the sulfur to the polymer takes place in the allylic position to the double bond. Modern passenger car tire treads no longer contain Natural Rubber but instead a blend of Solution Styrene Butadiene Rubber and Butadiene Rubber, filled with a silica/silane system. Is it possible to transfer all the gained knowledge from the Natural Rubber crosslink reaction to such modern passenger car tire tread formulations, or is it required to "re-think" sulfur curing?
期刊介绍：
Molecules (ISSN 1420-3049, CODEN: MOLEFW) is an open access journal of synthetic organic chemistry and natural product chemistry. All articles are peer-reviewed and published continously upon acceptance. Molecules is published by MDPI, Basel, Switzerland. Our aim is to encourage chemists to publish as much as possible their experimental detail, particularly synthetic procedures and characterization information. There is no restriction on the length of the experimental section. In addition, availability of compound samples is published and considered as important information. Authors are encouraged to register or deposit their chemical samples through the non-profit international organization Molecular Diversity Preservation International (MDPI). Molecules has been launched in 1996 to preserve and exploit molecular diversity of both, chemical information and chemical substances.
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