Chemical and Rheological Evaluation of the Ageing Behaviour of High-Content Crumb Rubber Asphalt Binder.

High-Content Crumb Rubber Asphalt (HCRA) binder improves road performance and address waste tyre pollution, yet its ageing behaviour is not fully understood. In this study, 70# neat asphalt binder and HCRA with rubber contents of 35% and 50% were selected and aged through the Thin Film Oven Test (TFOT) and Pressure Ageing Vessel (PAV) tests. FTIR (Fourier Transform Infrared Spectroscopy) and DSR (Dynamic Shear Rheometer) were employed to investigate their chemical composition and rheological properties. The FTIR results show that HCRA's chemical test results are similar to those of 70#, but HCRA is more susceptible to ageing. I(C=C) strength decreases with age. The DSR results show that HCRA outperforms 70# neat asphalt binder in terms of viscoelasticity, high temperature performance and fatigue resistance, and exhibits greater resistance to ageing. The ageing index (AI) was obtained through a calculation using the formula, and overall, 70# neat asphalt binder is more sensitive to ageing behaviour and less resistant to ageing, and HCRA is particularly outstanding for fatigue resistance. A strong correlation is observed between chemical composition and some rheological property indicators. Therefore, we are able to predict the rheological properties using chemical composition indicators. This study provides insight into the ageing behaviour of a neat asphalt binder and an HCRA binder and demonstrates that the HCRA binder outperforms conventional asphalt in several performance areas. It also provides theoretical support for the consumption of waste tyres to prepare high content crumb rubber asphalt.