具有四价 N-杂环碳烯酰胺配体的中性镍络合物用于电催化氢进化

IF 3.5 3区化学 Q2 CHEMISTRY, INORGANIC & NUCLEAR Dalton Transactions Pub Date : 2024-11-15 DOI:10.1039/d4dt02746a

Si Si, Wenxun Song, Jie Chen, Weimin Zhang, Wenhua Ji, Wonwoo Nam, Bin Wang

{"title":"具有四价 N-杂环碳烯酰胺配体的中性镍络合物用于电催化氢进化","authors":"Si Si, Wenxun Song, Jie Chen, Weimin Zhang, Wenhua Ji, Wonwoo Nam, Bin Wang","doi":"10.1039/d4dt02746a","DOIUrl":null,"url":null,"abstract":"Neutral nickel complexes bearing tetradentate N-heterocyclic carbene (NHC) amidate ligands were prepared; the effects of coordination geometry of the nickel center and the electronic properties of the ligand on the redox behavior as well as the electrocatalytic activity for hydrogen evolution reaction (HER) were investigated.","PeriodicalId":71,"journal":{"name":"Dalton Transactions","volume":"1 1","pages":""},"PeriodicalIF":3.5000,"publicationDate":"2024-11-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Neutral nickel complexes with tetradentate N-heterocyclic carbene amidate ligands for electrocatalytic hydrogen evolution\",\"authors\":\"Si Si, Wenxun Song, Jie Chen, Weimin Zhang, Wenhua Ji, Wonwoo Nam, Bin Wang\",\"doi\":\"10.1039/d4dt02746a\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Neutral nickel complexes bearing tetradentate N-heterocyclic carbene (NHC) amidate ligands were prepared; the effects of coordination geometry of the nickel center and the electronic properties of the ligand on the redox behavior as well as the electrocatalytic activity for hydrogen evolution reaction (HER) were investigated.\",\"PeriodicalId\":71,\"journal\":{\"name\":\"Dalton Transactions\",\"volume\":\"1 1\",\"pages\":\"\"},\"PeriodicalIF\":3.5000,\"publicationDate\":\"2024-11-15\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Dalton Transactions\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://doi.org/10.1039/d4dt02746a\",\"RegionNum\":3,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, INORGANIC & NUCLEAR\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Dalton Transactions","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1039/d4dt02746a","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}

引用次数: 0

摘要

研究了镍中心的配位几何和配体的电子特性对氧化还原行为以及氢进化反应（HER）电催化活性的影响。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

查看原文

微信好友朋友圈 QQ好友复制链接

本刊更多论文

Neutral nickel complexes with tetradentate N-heterocyclic carbene amidate ligands for electrocatalytic hydrogen evolution

Neutral nickel complexes bearing tetradentate N-heterocyclic carbene (NHC) amidate ligands were prepared; the effects of coordination geometry of the nickel center and the electronic properties of the ligand on the redox behavior as well as the electrocatalytic activity for hydrogen evolution reaction (HER) were investigated.

求助全文

通过发布文献求助，成功后即可免费获取论文全文。去求助

来源期刊

Dalton Transactions 化学-无机化学与核化学

CiteScore

6.60

自引率

7.50%

发文量

1832

审稿时长

1.5 months

期刊介绍： Dalton Transactions is a journal for all areas of inorganic chemistry, which encompasses the organometallic, bioinorganic and materials chemistry of the elements, with applications including synthesis, catalysis, energy conversion/storage, electrical devices and medicine. Dalton Transactions welcomes high-quality, original submissions in all of these areas and more, where the advancement of knowledge in inorganic chemistry is significant.