基于 CoWO4/多壁碳纳米管的灵敏电化学传感器用于选择性测定盐酸氯丙嗪

IF 3.6 3区 化学 Q2 CHEMISTRY, ANALYTICAL Analyst Pub Date : 2024-11-15 DOI:10.1039/d4an01298d
Si Zeng, Peiyao Zhu, Deyu Liu, Yongmei Hu, Qitong Huang, Haiping Huang
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引用次数: 0

摘要

在这项研究中,一种基于钨酸钴/多壁碳纳米管(CoWO4/MWCNTs)纳米复合材料的新型电化学传感器被用于检测盐酸氯丙嗪(CPZ)。CoWO4/MWCNTs 纳米复合材料是通过溶热技术和超声波法获得的,并通过扫描电子显微镜(SEM)、X 射线衍射仪(XRD)、能量色散光谱(EDS)和 X 射线光电子能谱(XPS)等不同的表征技术进行了分析。使用循环伏安法 (CV) 探索了 CoWO4/MWCNTs/GCE 的电化学行为。电化学实验证实,CoWO4/MWCNTs/GCE 对 CPZ 具有优异的电催化活性,并具有良好的选择性、重现性和稳定性。CPZ 的线性动态范围为 1-2000 µM,检测限为 0.33 µM。此外,还使用湖水对实际样品进行了分析,结果令人满意。
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A sensitive electrochemical sensor based on CoWO4/multi-walled carbon nanotubes for the selective determination of chlorpromazine hydrochloride
In this work, a novel electrochemical sensor based on cobalt tungstate/multi-walled carbon nanotubes (CoWO4/MWCNTs) nanocomposite has been used to detect chlorpromazine hydrochloride (CPZ). The CoWO4/MWCNTs nanocomposite was obtained by solvothermal technology and ultrasonic method and analyzed via different characterization techniques of scanning electron microscope (SEM), X-ray diffractometer (XRD), energy dispersive spectroscopy (EDS) and X-ray photoelectron spectroscopy (XPS). The electrochemical behavior of CoWO4/MWCNTs/GCE was explored using cyclic voltammetry (CV). Electrochemical experiments have confirmed that CoWO4/MWCNTs/GCE exhibits excellent electrocatalytic activity towards CPZ with good selectivity, reproducibility and stability. The linear dynamic range of CPZ was observed to be 1-2000 µM with a detection limit of 0.33 µM. Moreover, the actual sample was analyzed using lake water with satisfactory results, which endows the sensor as potential candidates for the detection of CPZ.
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来源期刊
Analyst
Analyst 化学-分析化学
CiteScore
7.80
自引率
4.80%
发文量
636
审稿时长
1.9 months
期刊介绍: The home of premier fundamental discoveries, inventions and applications in the analytical and bioanalytical sciences
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