六氰合铁酸钾(II)作为环境友好型氰化物源的偶联反应最新进展

IF 1.9 4区 化学 Q3 CHEMISTRY, MULTIDISCIPLINARY ChemistrySelect Pub Date : 2024-11-15 DOI:10.1002/slct.202403742
Prof. Yijun Ma, Dr. Fei Wen, Guangyuan Chen, Prof. Yonghe Zhang, Prof. Zheng Li
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引用次数: 0

摘要

氰化反应是生成 C─CN 键的重要方法。传统的氰化反应通常需要使用剧毒且不稳定的氰化物,如 NaCN、KCN、CuCN 和 TMSCN。K4[Fe(CN)6]是一种煤化工产品,具有收率高、毒性低的优点。它是一种非常环保、安全和稳定的氰化物来源。自 2004 年以来,K4[Fe(CN)6] 已成为氰化反应中 NaCN 和 KCN 等传统、剧毒和危险氰化物源的可行替代品。在过去二十年中,涉及 K4[Fe(CN)6] 的绿色氰化反应研究取得了重大进展。本文回顾了 K4[Fe(CN)6]与芳基卤化物、磺酸盐、芳基羧酸、芳香醛、酰基氯、酚、苄醇和芳基锍盐等底物之间氰化偶联反应的研究进展。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

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Recent Progress on Coupling Reaction of Potassium Hexacyanoferrate(II) as an Environmentally Friendly Cyanide Source

Cyanidation reactions are an essential method for creating C─CN bonds. Traditional cyanidation reactions usually require the use of highly toxic and unstable cyanide sources, such as NaCN, KCN, CuCN, and TMSCN. K4[Fe(CN)6], a product of the coal chemical industry, has the advantages of high yield and low toxicity. It is a very environmentally friendly, safe, and stable cyanide source. Since 2004, K4[Fe(CN)6] has emerged as a viable alternative to conventional, highly toxic, and hazardous cyanide sources like NaCN and KCN in cyanidation reactions. Over the past two decades, significant progress has been made in studying green cyanidation reactions involving K4[Fe(CN)6]. This paper reviews the advancements in the study of cyanidation coupling reactions between substrates such as aryl halides, sulfonates, aryl carboxylic acids, aromatic aldehydes, acyl chlorides, phenols, benzyl alcohols, and aryl sulfonium salts with K4[Fe(CN)6].

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来源期刊
ChemistrySelect
ChemistrySelect Chemistry-General Chemistry
CiteScore
3.30
自引率
4.80%
发文量
1809
审稿时长
1.6 months
期刊介绍: ChemistrySelect is the latest journal from ChemPubSoc Europe and Wiley-VCH. It offers researchers a quality society-owned journal in which to publish their work in all areas of chemistry. Manuscripts are evaluated by active researchers to ensure they add meaningfully to the scientific literature, and those accepted are processed quickly to ensure rapid online publication.
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