利用连翘残渣合成的荧光碳纳米点检测铁离子

IF 2.6 4区 化学 Q2 BIOCHEMICAL RESEARCH METHODS Journal of Fluorescence Pub Date : 2024-11-16 DOI:10.1007/s10895-024-04035-7
Zhaoxia Li, Jia Dong, Panchen Wang, Dongchun Li, Xinyi Li, Huiling Geng
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引用次数: 0

摘要

为了充分利用传统中草药的废弃物,本研究以连翘渣为原料,通过一步水热法制备了一种基于铁离子传感器的高功能化荧光碳纳米点(CDs)。在透射电子显微镜(TEM)下,可以观察到纳米碳点呈球形,直径在 5-20 纳米之间。综合分析表明,CD 具有良好的形貌、多样的官能团、高水溶性、显著的光学特性以及在各种环境条件下的优异稳定性。此外,这些光盘还具有良好的光学特性,在紫外线(UV)照射下可发出鲜艳的绿色光致发光(PL)。此外,所制备的光盘对铁离子具有选择性荧光淬灭行为,灵敏度令人满意,检测限(LOD)低至 4.3 µM。此外,CD 对 Fe3+ 具有良好的选择性,对其他几种金属离子的干扰最小。因此,这种策略可以有效地应用于实际水样,证明其具有更广泛的应用潜力。
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Detection of Ferric Ion by Fluorescent Carbon Nano Dots Synthesized from Forsythia Residue.

To fully utilize the wastes of the traditional Chinese herbs, a highly functionalized fluorescent carbon nano dots (CDs) based ferric ion sensor was prepared from forsythia residue via a one-step hydrothermal method. Under transmission electron microscope (TEM), the CDs were observed to be spherical with the diameter in the range of 5-20 nm. Comprehensive analyses documented the CDs' favorable morphology, diverse functional groups, high water solubility, remarkable optical properties, and exceptional stability under various environmental conditions. Moreover, the CDs exhibited good optical properties with vivid green photoluminescence (PL) when they were exposed to ultraviolet (UV) light. Furthermore, the prepared CDs demonstrated selective fluorescence quenching behavior towards ferric ions with satisfactory sensitivity and a low limit of detection (LOD) of 4.3 µM. Additionally, the CDs displayed good selectivity towards Fe3+ and the least interference with several other metal ions. Consequently, this strategy could be effectively applied to real water samples, demonstrating its potential for broader applications.

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来源期刊
Journal of Fluorescence
Journal of Fluorescence 化学-分析化学
CiteScore
4.60
自引率
7.40%
发文量
203
审稿时长
5.4 months
期刊介绍: Journal of Fluorescence is an international forum for the publication of peer-reviewed original articles that advance the practice of this established spectroscopic technique. Topics covered include advances in theory/and or data analysis, studies of the photophysics of aromatic molecules, solvent, and environmental effects, development of stationary or time-resolved measurements, advances in fluorescence microscopy, imaging, photobleaching/recovery measurements, and/or phosphorescence for studies of cell biology, chemical biology and the advanced uses of fluorescence in flow cytometry/analysis, immunology, high throughput screening/drug discovery, DNA sequencing/arrays, genomics and proteomics. Typical applications might include studies of macromolecular dynamics and conformation, intracellular chemistry, and gene expression. The journal also publishes papers that describe the synthesis and characterization of new fluorophores, particularly those displaying unique sensitivities and/or optical properties. In addition to original articles, the Journal also publishes reviews, rapid communications, short communications, letters to the editor, topical news articles, and technical and design notes.
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