揭示原油粘度和流变特性:纳米二氧化硅和纳米二硫化钼在巴扎尔甘油田的实验比较

IF 6.7 1区 工程技术 Q2 ENERGY & FUELS Fuel Pub Date : 2024-11-12 DOI:10.1016/j.fuel.2024.133698
Salem J. Alhamd , Farhan Lafta Rashid , Mudhar A. Al-Obaidi , Abass K. Aldami
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引用次数: 0

摘要

本研究旨在通过实验研究在不同纳米颗粒浓度和原油温度下,加入二氧化硅纳米颗粒和纳米二硫化钼对巴扎尔甘原油(伊拉克)的粘度特性和原油流变特性的影响。结果表明,添加纳米颗粒、增加纳米颗粒浓度和提高工作温度都会显著降低原油粘度。据统计,加入 0.3 wt% 的二氧化硅纳米粒子后,原油粘度从 25 °C 时的 57.15 cP 降至 55 °C 时的 31.27 cP,而加入 0.3 wt% 的二硫化钼纳米粒子后,原油粘度从 25 °C 时的 57.15 cP 降至 55 °C 时的 31.37 cP。为了量化添加纳米颗粒后粘度降低的估计值,确定了粘度降低程度(DVR%)。具体来说,在 25 °C 时,添加 0.3 wt% 的纳米二氧化硅颗粒可确保 31.58 % 的最大 DVR%,而添加 0.3 wt% 的纳米二硫化钼后的最大 DVR% 为 29.27 %。在这方面,添加不同浓度的纳米粒子会降低屈服应力、塑性粘度和有效粘度。这表明原油正在向牛顿流体行为过渡,具体表现为加入纳米材料后屈服应力减小并逐渐趋近于零。
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Unveiling crude oil viscosity and rheological Properties: An experimental comparison of Nano silica and Nano Molybdenum disulfide in Bazargan Oilfield
The present study intends to experimentally investigate the impact of incorporating silica nanoparticles and Nano Molybdenum disulfide on the viscosity property and crude oil rheological properties of Bazargan crude oil (Iraq) at different nanoparticles concentrations and crude oil temperatures. The results indicate a notable reduction of crude oil viscosity as a result to adding the nanoparticles, increasing the nanoparticles concentration, and increasing the operating temperature. Statistically, the viscosity has been reduced from 57.15 cP at 25 °C to 31.27 cP at 55 °C after adding 0.3 wt% of silica nanoparticles compared to a reduction of viscosity from 57.15 cP at 25 °C to 31.37 cP after the inclusion of 0.3 wt% of Nano Molybdenum disulfide at 55 °C. To quantify the estimation of viscosity reduction after the addition of nanoparticles, the degree of viscosity reduction (DVR%) is established. Specifically, the addition of silica nanoparticles assures the maximum DVR% of 31.58 %. using 0.3 wt% at 25 °C compared to the maximum DVR% of 29.27 % after the addition of 0.3 wt% of Nano Molybdenum disulfide.
A critical analysis of the crude oil rheological properties indicates that the crude oil can exhibit a Bingham fluid behavior. In this regard, the addition of nanoparticles at variable concentrations resulted in a decrease in yield stress, plastic viscosity, and effective viscosity. This proposes that the crude oil is transitioning towards Newtonian behavior, as demonstrated by the lessening yield stress and its gradual approach to zero after the combination of nanomaterials.
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来源期刊
Fuel
Fuel 工程技术-工程:化工
CiteScore
12.80
自引率
20.30%
发文量
3506
审稿时长
64 days
期刊介绍: The exploration of energy sources remains a critical matter of study. For the past nine decades, fuel has consistently held the forefront in primary research efforts within the field of energy science. This area of investigation encompasses a wide range of subjects, with a particular emphasis on emerging concerns like environmental factors and pollution.
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