{"title":"氧化石墨烯改性土工聚合物综述:分散制备、力学性能和微观机理","authors":"Mengqi Xu , Jiajia Fu , Tianhong Feng , Wei Wang","doi":"10.1016/j.rineng.2024.103320","DOIUrl":null,"url":null,"abstract":"<div><div>In recent years, graphene oxide (GO) has been widely used in various fields owing to its high specific surface area and rich oxygen-containing functional groups. Adding an appropriate amount of GO (about 0.01–0.1 wt%) is beneficial to strengthen the soft soil foundation, which can improve the mechanical properties of the geopolymers, promote the hydration reaction, and improve the pore structure. The main mechanisms include the distortion effect, intercalation effect, template effect, bridge effect, active catalytic effect, adsorption cementation effect, and nucleation effect. Currently, GO research on cement materials mainly focuses on mortar and concrete and pays less attention to geotechnical engineering fields, such as cement soil. Therefore, to fully understand the unique advantages of GO, to clarify the method and mechanism of GO strengthening soft soil foundations, and to expand its application in geotechnical engineering, we briefly summarise the characterisation methods, dispersion of GO, analyse the influence of the single incorporation of GO on the mechanical properties of geopolymers, and discuss its microscopic mechanism. The environmental and safety effects are also discussed. Finally, the problems existing in the current research are analysed and future research directions are discussed.</div></div>","PeriodicalId":36919,"journal":{"name":"Results in Engineering","volume":"24 ","pages":"Article 103320"},"PeriodicalIF":6.0000,"publicationDate":"2024-11-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Critical review on graphene oxide modified geopolymers: Dispersion preparation, mechanical properties, and microscopic mechanisms\",\"authors\":\"Mengqi Xu , Jiajia Fu , Tianhong Feng , Wei Wang\",\"doi\":\"10.1016/j.rineng.2024.103320\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>In recent years, graphene oxide (GO) has been widely used in various fields owing to its high specific surface area and rich oxygen-containing functional groups. Adding an appropriate amount of GO (about 0.01–0.1 wt%) is beneficial to strengthen the soft soil foundation, which can improve the mechanical properties of the geopolymers, promote the hydration reaction, and improve the pore structure. The main mechanisms include the distortion effect, intercalation effect, template effect, bridge effect, active catalytic effect, adsorption cementation effect, and nucleation effect. Currently, GO research on cement materials mainly focuses on mortar and concrete and pays less attention to geotechnical engineering fields, such as cement soil. Therefore, to fully understand the unique advantages of GO, to clarify the method and mechanism of GO strengthening soft soil foundations, and to expand its application in geotechnical engineering, we briefly summarise the characterisation methods, dispersion of GO, analyse the influence of the single incorporation of GO on the mechanical properties of geopolymers, and discuss its microscopic mechanism. The environmental and safety effects are also discussed. Finally, the problems existing in the current research are analysed and future research directions are discussed.</div></div>\",\"PeriodicalId\":36919,\"journal\":{\"name\":\"Results in Engineering\",\"volume\":\"24 \",\"pages\":\"Article 103320\"},\"PeriodicalIF\":6.0000,\"publicationDate\":\"2024-11-04\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Results in Engineering\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S2590123024015743\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"ENGINEERING, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Results in Engineering","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S2590123024015743","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"ENGINEERING, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
摘要
近年来,氧化石墨烯(GO)因其高比表面积和丰富的含氧官能团而被广泛应用于各个领域。添加适量的 GO(约 0.01-0.1 wt%)有利于加固软土地基,可提高土工聚合物的力学性能,促进水化反应,改善孔隙结构。主要机理包括变形效应、插层效应、模板效应、架桥效应、活性催化效应、吸附胶结效应和成核效应等。目前,GO 对水泥材料的研究主要集中在砂浆和混凝土方面,对岩土工程领域(如水泥土)的关注较少。因此,为了充分认识 GO 的独特优势,阐明 GO 加固软土地基的方法和机理,拓展其在岩土工程中的应用,我们简要总结了 GO 的表征方法、分散性,分析了单一掺入 GO 对土工聚合物力学性能的影响,探讨了其微观机理。此外,还讨论了对环境和安全的影响。最后,分析了当前研究中存在的问题,并讨论了未来的研究方向。
Critical review on graphene oxide modified geopolymers: Dispersion preparation, mechanical properties, and microscopic mechanisms
In recent years, graphene oxide (GO) has been widely used in various fields owing to its high specific surface area and rich oxygen-containing functional groups. Adding an appropriate amount of GO (about 0.01–0.1 wt%) is beneficial to strengthen the soft soil foundation, which can improve the mechanical properties of the geopolymers, promote the hydration reaction, and improve the pore structure. The main mechanisms include the distortion effect, intercalation effect, template effect, bridge effect, active catalytic effect, adsorption cementation effect, and nucleation effect. Currently, GO research on cement materials mainly focuses on mortar and concrete and pays less attention to geotechnical engineering fields, such as cement soil. Therefore, to fully understand the unique advantages of GO, to clarify the method and mechanism of GO strengthening soft soil foundations, and to expand its application in geotechnical engineering, we briefly summarise the characterisation methods, dispersion of GO, analyse the influence of the single incorporation of GO on the mechanical properties of geopolymers, and discuss its microscopic mechanism. The environmental and safety effects are also discussed. Finally, the problems existing in the current research are analysed and future research directions are discussed.