日本卷轴模型样品中绘画纸和第一层衬纸之间剥离强度的变化

IF 3.2 3区 材料科学 Q2 ENGINEERING, CHEMICAL International Journal of Adhesion and Adhesives Pub Date : 2024-10-30 DOI:10.1016/j.ijadhadh.2024.103875
Kang Lee , Toshiharu Enomae , Masamitsu Inaba
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引用次数: 0

摘要

为了保持挂轴上的画作在后续修复前的永久性,不仅要抑制画作和衬纸的老化,还要抑制它们之间粘合力的下降,这一点非常重要,因为第一道衬纸工序会通过附着物对画纸的机械支撑产生重大影响。已经对衬里系统各组成部分的老化情况进行了多项研究。本研究根据不同浓度的油漆和衬里材料以及衬里纸的纤维类型,通过剥离强度评估了衬里复合材料的粘附性能。由未经处理的油漆纸组成的内衬复合材料显示出最高的初始剥离强度,这是因为小麦淀粉糊层具有显著的粘附性,而这要归功于油漆纸较高的润湿性和渗透性,尽管在较长的老化时间内会出现基底失效。油漆纸中颜料所含的 Cu2+ 等降解物质分解淀粉的速度最快,粘附性也降低得最快。由于润湿性和渗透性较低,涂有含有明矾或 Cu2+ 的动物胶的内衬复合物在老化过程中保持最低的剥离强度,导致动物胶和小麦淀粉糊层之间的界面失效。此外,粘合力随衬纸纤维类型的不同而变化,这取决于纤维长度、表面粗糙度、形状和羟基强度等综合因素。因此,由纤维特性、衬里所用材料和油漆纸中的降解产物造成的不同条件影响了附着力和粘合力的变化。这种变化导致了不同的衬里效果,从而影响了挂轴的预期寿命,并决定了后续修复工作的效率。
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Changes in the peel strength between the painting and first lining papers in Japanese scroll model samples
To maintain the permanence of a painting in a hanging scroll until subsequent repairs are made, inhibiting not only the deterioration of the painting and lining papers but also inhibiting decrease in the adhesiveness between them is important because the first lining process significantly influences the mechanical support to the painting paper by attachment. Several studies have been conducted on the deterioration attributed to each component of the lining system. This study evaluated the adhesiveness behaviour by peel strength in the lined complex depending on the painting and lining materials with varied concentrations, as well as the fibre type of the lining paper. The lined complex consisting of the untreated painting paper showed the highest initial peel strength owing to the significant cohesiveness of the wheat starch paste layer, which was attributed to the paper's higher wettability and permeability, even though substrate failure occurred with longer ageing times. Degradative materials such as Cu2+ attributed to pigments in the painting paper decomposed starch and decreased adhesiveness the fastest. Lined complexes coated with animal glue containing alum or Cu2+ in the painting paper maintained the lowest peel strength during ageing owing to lower wettability and permeability, resulting in interfacial failure between the animal glue and the wheat starch paste layer. In addition, adhesiveness varied with different fibre types of the lining paper, depending on combined factors such as fibre length, surface roughness, shape, and intensity of hydroxyl groups. Thus, variable conditions attributed to fibre characteristics, materials used for lining, and degradative products in the painting paper influenced the changes in adhesion and adhesiveness. This variation contributed to different lining effects that influenced the life expectancy of the hanging scroll and determined the efficiency of the subsequent repair work.
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来源期刊
International Journal of Adhesion and Adhesives
International Journal of Adhesion and Adhesives 工程技术-材料科学:综合
CiteScore
6.90
自引率
8.80%
发文量
200
审稿时长
8.3 months
期刊介绍: The International Journal of Adhesion and Adhesives draws together the many aspects of the science and technology of adhesive materials, from fundamental research and development work to industrial applications. Subject areas covered include: interfacial interactions, surface chemistry, methods of testing, accumulation of test data on physical and mechanical properties, environmental effects, new adhesive materials, sealants, design of bonded joints, and manufacturing technology.
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