通过光催化应用的绿色方法,利用涂有银纳米粒子的耐用抗菌纤维素棉织物

IF 5.3 2区 化学 Q2 CHEMISTRY, PHYSICAL Journal of Molecular Liquids Pub Date : 2024-11-10 DOI:10.1016/j.molliq.2024.126483
Chandra Sekhar Espenti , T.V. Surendra , K.S.V. Krishna Rao , Mushtaq Ahmad Ansari , Kummara Madhusudana Rao , Sung Soo Han
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引用次数: 0

摘要

人们对微生物感染的关注与日俱增,促使人们对抗菌纺织品进行了大量研究。本研究提出了一种绿色、环保的方法,即通过沉积以银莲花(Bryophyllum pinnatum,BP)叶提取物为天然还原剂合成的银纳米粒子(AgNPs),为纤维素棉织物(CCF)赋予抗菌特性。为了提高 AgNPs 在 CCF 上的耐久性,采用了一种环境友好型方法来合成 AgNPs,然后用 BP 叶提取物作为天然还原剂将其应用到生物相容性 CCF 上。由于植物化学物质的存在,AgNPs 在环境条件下迅速生成,且大小和形状均一。利用紫外可见光谱、傅立叶变换红外光谱(FTIR)、扫描电子显微镜(SEM)和能量色散 X 射线(EDX)分光光度法以及 X 射线衍射(XRD)分析等技术对合成的纳米粒子进行了表征,以确定其尺寸(平均尺寸为 60.4 ± 8.5 nm)、形态和晶体结构。随后,采用环保沉积法在 CCF 上涂覆了这些 AgNPs。对处理后织物的机械性能进行了评估,以确保涂层过程不会损害织物的完整性或人体使用的安全性。结果表明,CCF-BP-AgNPs 保持了其机械强度,并且没有表现出细胞毒性效应,因此适用于医疗保健、服装和家用纺织品的各种应用。通过测量对大肠杆菌、枯草杆菌和金黄色葡萄球菌的抑菌区,评估了 CCF-BP-AgNPs 的抗菌活性。通过观察有机染料刚果红(CR)在模拟阳光下的分解情况,评估了涂层布的光催化活性。有趣的是,CCF-BP-AgNPs 能有效光催化降解刚果红,揭示了其在废水处理和环境修复方面的应用潜力。在整个光催化过程中,织物的抗菌特性保持不变,使消毒和污染物分解同时进行。
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Harnessing durable antimicrobial cellulose cotton fabric coated with silver nanoparticles via a green approach for photocatalytic applications
Growing concern regarding microbial infections has prompted significant research into antimicrobial textiles. This study presents a green, eco-friendly approach to imparting antimicrobial properties to cellulose cotton fabric (CCF) by depositing silver nanoparticles (AgNPs) synthesized using Bryophyllum pinnatum (BP) leaf extract as a natural reducing agent. To improve the durability of AgNPs on CCF, an environmentally friendly method was used to synthesize AgNPs, which were subsequently applied to biocompatible CCF using BP leaf extract as a natural reducing agent. Owing to the presence of phytochemicals, the AgNPs were rapidly produced with a uniform size and shape under ambient conditions. The synthesized nanoparticles were characterized using techniques such as ultraviolet–visible spectroscopy, Fourier-transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM) coupled with energy dispersive X-ray (EDX) spectrophotometry, and X-ray diffraction (XRD) analysis to confirm their size (average size 60.4 ± 8.5 nm), morphology, and crystalline structure. Subsequently, the CCF was coated with these AgNPs using an eco-friendly deposition method. The mechanical properties of the treated fabric were assessed to ensure that the coating process did not compromise the fabric’s integrity or safety for human use. The results indicated that the CCF–BP–AgNPs retained its mechanical strength and exhibited no cytotoxic effects, regarding it suitable for various applications in healthcare, apparel, and household textiles. The antibacterial activity of the CCF–BP–AgNPs was evaluated by measuring zone inhibition against Escherichia coli, Bacillus subtilis, and Staphylococcus aureus. The photocatalytic activity of the coated cloth was assessed by observing the breakdown of organic dye Congo Red (CR) in simulated sunlight. Interestingly, the CCF–BP–AgNPs demonstrated effective photocatalytic degradation of CR, revealing its potential for wastewater treatment and environmental remediation applications. The fabric’s antimicrobial properties remained intact throughout the photocatalytic process, enabling disinfection and pollutant breakdown to occur simultaneously.
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来源期刊
Journal of Molecular Liquids
Journal of Molecular Liquids 化学-物理:原子、分子和化学物理
CiteScore
10.30
自引率
16.70%
发文量
2597
审稿时长
78 days
期刊介绍: The journal includes papers in the following areas: – Simple organic liquids and mixtures – Ionic liquids – Surfactant solutions (including micelles and vesicles) and liquid interfaces – Colloidal solutions and nanoparticles – Thermotropic and lyotropic liquid crystals – Ferrofluids – Water, aqueous solutions and other hydrogen-bonded liquids – Lubricants, polymer solutions and melts – Molten metals and salts – Phase transitions and critical phenomena in liquids and confined fluids – Self assembly in complex liquids.– Biomolecules in solution The emphasis is on the molecular (or microscopic) understanding of particular liquids or liquid systems, especially concerning structure, dynamics and intermolecular forces. The experimental techniques used may include: – Conventional spectroscopy (mid-IR and far-IR, Raman, NMR, etc.) – Non-linear optics and time resolved spectroscopy (psec, fsec, asec, ISRS, etc.) – Light scattering (Rayleigh, Brillouin, PCS, etc.) – Dielectric relaxation – X-ray and neutron scattering and diffraction. Experimental studies, computer simulations (MD or MC) and analytical theory will be considered for publication; papers just reporting experimental results that do not contribute to the understanding of the fundamentals of molecular and ionic liquids will not be accepted. Only papers of a non-routine nature and advancing the field will be considered for publication.
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