{"title":"用于评估纳米流体动态粘度的新半经验相关性","authors":"Gianluca Coccia, Feliciano Falcone","doi":"10.1016/j.molliq.2024.126456","DOIUrl":null,"url":null,"abstract":"<div><div>Thanks to their excellent heat transfer coefficient, nanofluids can be considered as ideal heat transfer fluids for a large number of relevant engineering and scientific applications. Precise assessments of their thermophysical properties are thus essential for reliable calculations. In this work, a new semi-empirical scaled correlation based on 8 parameters (volume fraction, temperature, base fluid critical temperature, base fluid density, base fluid critical density, nanoparticle diameter, base fluid molar mass, nanoparticle density) is introduced to evaluate the dynamic viscosity of nanofluids. The correlation is regressed and evaluated using a dynamic viscosity dataset for 32 nanofluids, including a total of 737 experimental points: 10 nanofluids have water as base fluid (Ag, Al<sub>2</sub>O<sub>3</sub>, Al<sub>2</sub>O<sub>3</sub>/CuO, C, CuO, diamond, Fe/Si, MWCNT, ND-Ni, TiO<sub>2</sub>), 6 nanofluids have ethylene glycol (Ag, Al2O3, CeO<sub>2</sub>, Co<sub>3</sub>O<sub>4</sub>, SiC, TiO<sub>2</sub>/CuO), 11 nanofluids comprise different mixtures of water and ethylene glycol (Al<sub>2</sub>O<sub>3</sub>, MWCNT/WO<sub>3</sub>, CB, fGnP, G/Dp, G/Dr, nD87, nD97, TiO<sub>2</sub>), 1 nanofluid has propylene glycol (SiC) and 4 nanofluids comprise different mixtures of water and propylene glycol (TiB<sub>2</sub>, TiB<sub>2</sub>/B<sub>4</sub>C, fGnP). The dynamic viscosity dataset was derived from experimental measurements documented in the scientific literature and conducted with samples that were prepared using consistent and reliable methods. The study evaluates the dynamic viscosity of nanofluids using 14 literature equations to verify their accuracy against the proposed correlation. Results show that the correlation has an average absolute relative deviation of 8.16%, which is significantly lower than that of the literature equations. A 4-fold cross-validation also shows that the correlation is resilient and accurate with different regression datasets.</div></div>","PeriodicalId":371,"journal":{"name":"Journal of Molecular Liquids","volume":"416 ","pages":"Article 126456"},"PeriodicalIF":5.3000,"publicationDate":"2024-11-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"A new semi-empirical correlation for the evaluation of the dynamic viscosity of nanofluids\",\"authors\":\"Gianluca Coccia, Feliciano Falcone\",\"doi\":\"10.1016/j.molliq.2024.126456\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>Thanks to their excellent heat transfer coefficient, nanofluids can be considered as ideal heat transfer fluids for a large number of relevant engineering and scientific applications. Precise assessments of their thermophysical properties are thus essential for reliable calculations. In this work, a new semi-empirical scaled correlation based on 8 parameters (volume fraction, temperature, base fluid critical temperature, base fluid density, base fluid critical density, nanoparticle diameter, base fluid molar mass, nanoparticle density) is introduced to evaluate the dynamic viscosity of nanofluids. The correlation is regressed and evaluated using a dynamic viscosity dataset for 32 nanofluids, including a total of 737 experimental points: 10 nanofluids have water as base fluid (Ag, Al<sub>2</sub>O<sub>3</sub>, Al<sub>2</sub>O<sub>3</sub>/CuO, C, CuO, diamond, Fe/Si, MWCNT, ND-Ni, TiO<sub>2</sub>), 6 nanofluids have ethylene glycol (Ag, Al2O3, CeO<sub>2</sub>, Co<sub>3</sub>O<sub>4</sub>, SiC, TiO<sub>2</sub>/CuO), 11 nanofluids comprise different mixtures of water and ethylene glycol (Al<sub>2</sub>O<sub>3</sub>, MWCNT/WO<sub>3</sub>, CB, fGnP, G/Dp, G/Dr, nD87, nD97, TiO<sub>2</sub>), 1 nanofluid has propylene glycol (SiC) and 4 nanofluids comprise different mixtures of water and propylene glycol (TiB<sub>2</sub>, TiB<sub>2</sub>/B<sub>4</sub>C, fGnP). The dynamic viscosity dataset was derived from experimental measurements documented in the scientific literature and conducted with samples that were prepared using consistent and reliable methods. The study evaluates the dynamic viscosity of nanofluids using 14 literature equations to verify their accuracy against the proposed correlation. Results show that the correlation has an average absolute relative deviation of 8.16%, which is significantly lower than that of the literature equations. A 4-fold cross-validation also shows that the correlation is resilient and accurate with different regression datasets.</div></div>\",\"PeriodicalId\":371,\"journal\":{\"name\":\"Journal of Molecular Liquids\",\"volume\":\"416 \",\"pages\":\"Article 126456\"},\"PeriodicalIF\":5.3000,\"publicationDate\":\"2024-11-09\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Molecular Liquids\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0167732224025157\",\"RegionNum\":2,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, PHYSICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Molecular Liquids","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0167732224025157","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
A new semi-empirical correlation for the evaluation of the dynamic viscosity of nanofluids
Thanks to their excellent heat transfer coefficient, nanofluids can be considered as ideal heat transfer fluids for a large number of relevant engineering and scientific applications. Precise assessments of their thermophysical properties are thus essential for reliable calculations. In this work, a new semi-empirical scaled correlation based on 8 parameters (volume fraction, temperature, base fluid critical temperature, base fluid density, base fluid critical density, nanoparticle diameter, base fluid molar mass, nanoparticle density) is introduced to evaluate the dynamic viscosity of nanofluids. The correlation is regressed and evaluated using a dynamic viscosity dataset for 32 nanofluids, including a total of 737 experimental points: 10 nanofluids have water as base fluid (Ag, Al2O3, Al2O3/CuO, C, CuO, diamond, Fe/Si, MWCNT, ND-Ni, TiO2), 6 nanofluids have ethylene glycol (Ag, Al2O3, CeO2, Co3O4, SiC, TiO2/CuO), 11 nanofluids comprise different mixtures of water and ethylene glycol (Al2O3, MWCNT/WO3, CB, fGnP, G/Dp, G/Dr, nD87, nD97, TiO2), 1 nanofluid has propylene glycol (SiC) and 4 nanofluids comprise different mixtures of water and propylene glycol (TiB2, TiB2/B4C, fGnP). The dynamic viscosity dataset was derived from experimental measurements documented in the scientific literature and conducted with samples that were prepared using consistent and reliable methods. The study evaluates the dynamic viscosity of nanofluids using 14 literature equations to verify their accuracy against the proposed correlation. Results show that the correlation has an average absolute relative deviation of 8.16%, which is significantly lower than that of the literature equations. A 4-fold cross-validation also shows that the correlation is resilient and accurate with different regression datasets.
期刊介绍:
The journal includes papers in the following areas:
– Simple organic liquids and mixtures
– Ionic liquids
– Surfactant solutions (including micelles and vesicles) and liquid interfaces
– Colloidal solutions and nanoparticles
– Thermotropic and lyotropic liquid crystals
– Ferrofluids
– Water, aqueous solutions and other hydrogen-bonded liquids
– Lubricants, polymer solutions and melts
– Molten metals and salts
– Phase transitions and critical phenomena in liquids and confined fluids
– Self assembly in complex liquids.– Biomolecules in solution
The emphasis is on the molecular (or microscopic) understanding of particular liquids or liquid systems, especially concerning structure, dynamics and intermolecular forces. The experimental techniques used may include:
– Conventional spectroscopy (mid-IR and far-IR, Raman, NMR, etc.)
– Non-linear optics and time resolved spectroscopy (psec, fsec, asec, ISRS, etc.)
– Light scattering (Rayleigh, Brillouin, PCS, etc.)
– Dielectric relaxation
– X-ray and neutron scattering and diffraction.
Experimental studies, computer simulations (MD or MC) and analytical theory will be considered for publication; papers just reporting experimental results that do not contribute to the understanding of the fundamentals of molecular and ionic liquids will not be accepted. Only papers of a non-routine nature and advancing the field will be considered for publication.