基于 3-(1-苯基-2,3-二甲基吡唑酮-5)偶氮戊二酮-2,4 的新型化合物的合成、X 射线分析、比电导率研究和抗氧化活性

IF 3.2 4区 化学 Q2 CHEMISTRY, MULTIDISCIPLINARY Journal of the Indian Chemical Society Pub Date : 2024-11-13 DOI:10.1016/j.jics.2024.101473
Esmira Eyyubova , Famil Chiragov , Faik Musayev , Khalil Nagiyev , Namiq Shikhaliyev , Vagif Farzaliyev , Afsun Sujayev
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引用次数: 0

摘要

一种试剂 3-(1-苯基-2,3-二甲基吡唑酮-5)偶氮戊二酮-2,4 以 4-氨基安替比林和乙酰丙酮为基础被合成并分离成晶体状。随后,2 个分子的 3-(1-苯基-2,3-二甲基吡唑酮-5)偶氮戊二酮-2,4 与乙二胺和一种新型试剂 4-((E)-(2-((2-((1R)-2-(1、2-((2-((1R)-2-(1,5-二甲基-3-氧代-2-苯基吡唑烷-4-基)-4,4,5-三甲基-4,5-二氢-1H-1λ4,2λ4,3-三唑-1-基)乙基)氨基)-4-氧代戊烷-3-基)偶氮)-1,5-二甲基-2-苯基吡唑烷-3-酮。我们获得了所得产物的单晶体,并对其主要特征进行了研究。通过 X 射线衍射分析,研究了合成产物的结构,并确定了晶胞参数。计算了 R2 与 Fe3+、Cu2+、Cd2+、Zn2+、Co2+、Mn2+、Ni2+ 离子形成的络合物的稳定常数和比电导率。研究发现,合成的化合物是有效的碳氢化合物氧化抑制剂。
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Synthesis, X-ray analysis, specific electric conductivity study and antioxidant activity of novel compound based on 3-(1-phenyl-2,3-dimethylpyrazolone-5)azopentadione-2,4
A reagent 3-(1-phenyl-2,3-dimethylpyrazolone-5)azopentadione-2,4 was synthesized and isolated into crystalline form based on 4-amino-antipyrine and acetylacetone. Subsequently, 2 molecules of 3-(1-phenyl-2,3-dimethylpyrazolone-5)azopentadione-2,4 were cross-linked with ethylenediamine and a novel reagent 4-((E)-(2-((2-((1R)-2-(1,5-dimethyl-3-oxo-2-phenylpyrazolidin-4-yl)-4,4,5-trimethyl-4,5-dihydro-1H-1λ4,2λ4,3-triazol-1-yl)ethyl)amino)-4-oxopentan-3-yl)diazenyl)-1,5-dimethyl-2 phenylpyrazolidin-3-one.
Single crystals of the resulting product were obtained and its main characteristics were studied. Using X-ray diffraction analysis, the structure of the synthesized product was studied and the parameters of the crystal cell were determined. The stability constants and specific electric conductivity of resulting complexes of R2 with Fe3+, Cu2+, Cd2+, Zn2+, Co2+, Mn2+, Ni2+ ions were calculated.
The antioxidant properties of the synthesized compounds were investigated in model reactions using the kinetic method. It was found that the synthesized compounds are effective inhibitors of hydrocarbon oxidation.
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来源期刊
CiteScore
3.50
自引率
7.70%
发文量
492
审稿时长
3-8 weeks
期刊介绍: The Journal of the Indian Chemical Society publishes original, fundamental, theorical, experimental research work of highest quality in all areas of chemistry, biochemistry, medicinal chemistry, electrochemistry, agrochemistry, chemical engineering and technology, food chemistry, environmental chemistry, etc.
期刊最新文献
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