Yunyun Ge , Jiangbo Cheng , Lin Xue , Baosen Zhang , Sheng Hong , Xiubing Liang , Shaogang Wang , Xiancheng Zhang
{"title":"HVAF 喷射 Co21Fe14Ni8Cr16Mo16C15B10 高熵金属玻璃涂层的孔隙缺陷和腐蚀行为","authors":"Yunyun Ge , Jiangbo Cheng , Lin Xue , Baosen Zhang , Sheng Hong , Xiubing Liang , Shaogang Wang , Xiancheng Zhang","doi":"10.1016/j.corsci.2024.112564","DOIUrl":null,"url":null,"abstract":"<div><div>Pore defect is a primary bottleneck limiting corrosion resistance of the coatings. The relationship between porosity and corrosion behaviors of HVAF-sprayed Co<sub>21</sub>Fe<sub>14</sub>Ni<sub>8</sub>Cr<sub>16</sub>Mo<sub>16</sub>C<sub>15</sub>B<sub>10</sub> high entropy metallic glass (HE-MG) coatings was investigated by 3D XRT, XPS, SKPFM and SVET techniques. The potential difference between pores and surrounding regions expedites corrosion tendency. The corrosion current density of the coating and concentration of defects in passivation film increase as a function of porosity, thereby degrading corrosion resistance. The lowest porosity coating displays exceptional anti-corrosion due to compact films enriched with Cr<sub>2</sub>O<sub>3</sub> and Mo<sup>4+</sup> oxides. These findings provide valuable insights for designing corrosion-resistance coatings.</div></div>","PeriodicalId":290,"journal":{"name":"Corrosion Science","volume":"242 ","pages":"Article 112564"},"PeriodicalIF":7.4000,"publicationDate":"2024-11-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Pore defect and corrosion behavior of HVAF-sprayed Co21Fe14Ni8Cr16Mo16C15B10 high entropy metallic glass coatings\",\"authors\":\"Yunyun Ge , Jiangbo Cheng , Lin Xue , Baosen Zhang , Sheng Hong , Xiubing Liang , Shaogang Wang , Xiancheng Zhang\",\"doi\":\"10.1016/j.corsci.2024.112564\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>Pore defect is a primary bottleneck limiting corrosion resistance of the coatings. The relationship between porosity and corrosion behaviors of HVAF-sprayed Co<sub>21</sub>Fe<sub>14</sub>Ni<sub>8</sub>Cr<sub>16</sub>Mo<sub>16</sub>C<sub>15</sub>B<sub>10</sub> high entropy metallic glass (HE-MG) coatings was investigated by 3D XRT, XPS, SKPFM and SVET techniques. The potential difference between pores and surrounding regions expedites corrosion tendency. The corrosion current density of the coating and concentration of defects in passivation film increase as a function of porosity, thereby degrading corrosion resistance. The lowest porosity coating displays exceptional anti-corrosion due to compact films enriched with Cr<sub>2</sub>O<sub>3</sub> and Mo<sup>4+</sup> oxides. These findings provide valuable insights for designing corrosion-resistance coatings.</div></div>\",\"PeriodicalId\":290,\"journal\":{\"name\":\"Corrosion Science\",\"volume\":\"242 \",\"pages\":\"Article 112564\"},\"PeriodicalIF\":7.4000,\"publicationDate\":\"2024-11-14\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Corrosion Science\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0010938X24007601\",\"RegionNum\":1,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"MATERIALS SCIENCE, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Corrosion Science","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0010938X24007601","RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
Pore defect and corrosion behavior of HVAF-sprayed Co21Fe14Ni8Cr16Mo16C15B10 high entropy metallic glass coatings
Pore defect is a primary bottleneck limiting corrosion resistance of the coatings. The relationship between porosity and corrosion behaviors of HVAF-sprayed Co21Fe14Ni8Cr16Mo16C15B10 high entropy metallic glass (HE-MG) coatings was investigated by 3D XRT, XPS, SKPFM and SVET techniques. The potential difference between pores and surrounding regions expedites corrosion tendency. The corrosion current density of the coating and concentration of defects in passivation film increase as a function of porosity, thereby degrading corrosion resistance. The lowest porosity coating displays exceptional anti-corrosion due to compact films enriched with Cr2O3 and Mo4+ oxides. These findings provide valuable insights for designing corrosion-resistance coatings.
期刊介绍：
Corrosion occurrence and its practical control encompass a vast array of scientific knowledge. Corrosion Science endeavors to serve as the conduit for the exchange of ideas, developments, and research across all facets of this field, encompassing both metallic and non-metallic corrosion. The scope of this international journal is broad and inclusive. Published papers span from highly theoretical inquiries to essentially practical applications, covering diverse areas such as high-temperature oxidation, passivity, anodic oxidation, biochemical corrosion, stress corrosion cracking, and corrosion control mechanisms and methodologies.
This journal publishes original papers and critical reviews across the spectrum of pure and applied corrosion, material degradation, and surface science and engineering. It serves as a crucial link connecting metallurgists, materials scientists, and researchers investigating corrosion and degradation phenomena. Join us in advancing knowledge and understanding in the vital field of corrosion science.
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