草莓中的农药残留量和人类健康风险评估

IF 4 2区 农林科学 Q2 CHEMISTRY, APPLIED Journal of Food Composition and Analysis Pub Date : 2024-11-06 DOI:10.1016/j.jfca.2024.106943
Mehmet Keklik , Eylem Odabas , Ozgur Golge , Bulent Kabak
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引用次数: 0

摘要

农药一直是全球虫害管理的主要工具。然而,农药污染是新鲜食品供应链中的一个主要食品安全风险。本研究旨在监测 245 个草莓样本中的 240 种农药残留,并评估土耳其成人和儿童消费群体的健康风险。在连续三个收获年度(2021-2023 年),研究人员从土耳其艾登地区的农户处采集草莓样品,并采用液相色谱-串联质谱法(LC-MS/MS)进行分析。在分析的 245 份草莓样品中,61.6% 含有 32 种不同的农药(17 种杀菌剂和 15 种杀虫剂),其中 5 种未经批准。此外,6.5%的草莓样品超过了欧盟最高残留限量(MRL)。42.9%的草莓样品中出现了多重残留。嘧菌酯是最常见的农药(30.2%),其次是啶虫脒(27.4%)、氟虫氨(17.1%)和联苯胺(15.1%)。在最坏的情况下,成人和儿童通过食用草莓累积接触农药的比例分别为 6.5 × 10-⁵ mg kg-¹ b.w. day-¹ 和 2.0 × 10-⁴ mg kg-¹ b.w. day-¹ 。根据最坏情况下的危害指数(HI)值计算,成人为 0.32%,儿童为 0.97%。这些结果表明,没有理由担心土耳其人因食用草莓而累积接触残留物。
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Pesticide residue levels in strawberries and human health risk assessment
Pesticides have been a primary tool in pest management worldwide. However, pesticide contamination is a major food safety risk in the fresh food supply chain. This study aims to monitor 240 pesticide residues in 245 strawberry samples and assess the health risk for Turkish adult and child consumer groups. Over three consecutive harvest years (2021–2023), strawberries were collected from farmers in the Aydın region of Turkey and analysed by liquid chromatography-tandem mass spectrometry (LC-MS/MS). Out of the 245 strawberry samples analysed, 61.6 % contained 32 different pesticides (17 fungicides and 15 insecticides), five of which were non-approved. Additionally, 6.5 % of the strawberry samples exceeded the European Union Maximum Residue Limits (MRLs). Multiple residues were recorded in 42.9 % of strawberry samples. Pyrimethanil was the most commonly identified pesticide (30.2 %), followed by boscalid (27.4 %), fluopyram (17.1 %), and bifenazate (15.1 %). In the worst-case scenario, cumulative exposure to pesticides through strawberry consumption was determined to be 6.5 × 10⁻⁵ mg kg⁻¹ b.w. day⁻¹ for adults and 2.0 × 10⁻⁴ mg kg⁻¹ b.w. day⁻¹ for children. The hazard index (HI) values, under the worst-case scenario, were calculated to be 0.32 % for adults and 0.97 % for children. These results indicate that there is no cause for concern regarding cumulative exposure to residues through strawberry consumption for the Turkish population.
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来源期刊
Journal of Food Composition and Analysis
Journal of Food Composition and Analysis 工程技术-食品科技
CiteScore
6.20
自引率
11.60%
发文量
601
审稿时长
53 days
期刊介绍: The Journal of Food Composition and Analysis publishes manuscripts on scientific aspects of data on the chemical composition of human foods, with particular emphasis on actual data on composition of foods; analytical methods; studies on the manipulation, storage, distribution and use of food composition data; and studies on the statistics, use and distribution of such data and data systems. The Journal''s basis is nutrient composition, with increasing emphasis on bioactive non-nutrient and anti-nutrient components. Papers must provide sufficient description of the food samples, analytical methods, quality control procedures and statistical treatments of the data to permit the end users of the food composition data to evaluate the appropriateness of such data in their projects. The Journal does not publish papers on: microbiological compounds; sensory quality; aromatics/volatiles in food and wine; essential oils; organoleptic characteristics of food; physical properties; or clinical papers and pharmacology-related papers.
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