{"title":"利用水热前驱体制备多孔钼氧化物","authors":"Huaqiang Xie, Yongjie Zhan","doi":"10.1016/j.inoche.2024.113549","DOIUrl":null,"url":null,"abstract":"<div><div>Molybdenum oxides Mo<sub>4</sub>O<sub>11</sub> and MoO<sub>2</sub> of porous structures have been synthesized by annealing of precursor prepared in hydrothermal process, which is a facile route that different from the usual reducing treatment from MoO<sub>3</sub> precursor. The converting from Mo<sub>4</sub>O<sub>11</sub> to MoO<sub>2</sub> has been identified and a hypothesis based on disproportionation reaction been verified. The solubility of as-prepared precursor can help to embed those molybdenum oxides in other porous materials to build up composite structures. And combined with MoO<sub>2</sub> sample with large specific surface areas, structurally enhanced MoO<sub>2</sub> product with designed shapes can also be provided.</div></div>","PeriodicalId":13609,"journal":{"name":"Inorganic Chemistry Communications","volume":"171 ","pages":"Article 113549"},"PeriodicalIF":5.4000,"publicationDate":"2025-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Porous molybdenum oxides prepared from hydrothermal precursor\",\"authors\":\"Huaqiang Xie, Yongjie Zhan\",\"doi\":\"10.1016/j.inoche.2024.113549\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>Molybdenum oxides Mo<sub>4</sub>O<sub>11</sub> and MoO<sub>2</sub> of porous structures have been synthesized by annealing of precursor prepared in hydrothermal process, which is a facile route that different from the usual reducing treatment from MoO<sub>3</sub> precursor. The converting from Mo<sub>4</sub>O<sub>11</sub> to MoO<sub>2</sub> has been identified and a hypothesis based on disproportionation reaction been verified. The solubility of as-prepared precursor can help to embed those molybdenum oxides in other porous materials to build up composite structures. And combined with MoO<sub>2</sub> sample with large specific surface areas, structurally enhanced MoO<sub>2</sub> product with designed shapes can also be provided.</div></div>\",\"PeriodicalId\":13609,\"journal\":{\"name\":\"Inorganic Chemistry Communications\",\"volume\":\"171 \",\"pages\":\"Article 113549\"},\"PeriodicalIF\":5.4000,\"publicationDate\":\"2025-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Inorganic Chemistry Communications\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S1387700324015399\",\"RegionNum\":3,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"2024/11/13 0:00:00\",\"PubModel\":\"Epub\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, INORGANIC & NUCLEAR\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Inorganic Chemistry Communications","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S1387700324015399","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"2024/11/13 0:00:00","PubModel":"Epub","JCR":"Q1","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}
Porous molybdenum oxides prepared from hydrothermal precursor
Molybdenum oxides Mo4O11 and MoO2 of porous structures have been synthesized by annealing of precursor prepared in hydrothermal process, which is a facile route that different from the usual reducing treatment from MoO3 precursor. The converting from Mo4O11 to MoO2 has been identified and a hypothesis based on disproportionation reaction been verified. The solubility of as-prepared precursor can help to embed those molybdenum oxides in other porous materials to build up composite structures. And combined with MoO2 sample with large specific surface areas, structurally enhanced MoO2 product with designed shapes can also be provided.
期刊介绍：
Launched in January 1998, Inorganic Chemistry Communications is an international journal dedicated to the rapid publication of short communications in the major areas of inorganic, organometallic and supramolecular chemistry. Topics include synthetic and reaction chemistry, kinetics and mechanisms of reactions, bioinorganic chemistry, photochemistry and the use of metal and organometallic compounds in stoichiometric and catalytic synthesis or organic compounds.
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