氯盐和直流杂散电流耦合作用下模拟混凝土孔隙溶液中钢筋的腐蚀行为

IF 7.4 1区 工程技术 Q1 CONSTRUCTION & BUILDING TECHNOLOGY Construction and Building Materials Pub Date : 2024-11-16 DOI:10.1016/j.conbuildmat.2024.139126
Peng Zhao , Gang Xu , Qing Wang , Zhen Zeng
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引用次数: 0

摘要

位于沿海和盐碱地地区的轨道交通工程在运营过程中产生的杂散电流,往往使沿线混凝土结构处于氯盐和杂散电流共存的恶化环境中,大大加速了钢筋的腐蚀过程,危及工程结构的安全。本文采用电化学方法研究了低直流杂散电流和氯离子共同作用下模拟孔隙溶液中钢筋的去钝化行为和腐蚀行为。结果表明,当直流杂散电流和氯离子共存时,钢棒容易发生去钝化,二者相互促进,耦合效应明显。在氯离子浓度不变的情况下,腐蚀介质的 pH 值、氯离子浓度和电流密度都会影响腐蚀电流效率。在高 pH 值环境中,电流效率随氯离子浓度的增加而逐渐增大,但随着 pH 值的降低或氯离子浓度的继续增加,电流效率略大于 1.0。当氯离子浓度不一致时,局部区域的氯离子浓度越高,该区域的钢筋腐蚀越严重。氯离子浓度差异造成的钢筋与阴极之间的电阻差异,是造成各区域耗电量不同和整体腐蚀不均匀的主要原因。
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Corrosion behavior of steel bars in simulated concrete pore solution under the coupling action of chloride salt and DC stray current
The stray current generated during the operation of rail transit projects located in coastal and saline soil areas often makes the concrete structures along the line in a deteriorating environment with the coexistence of chloride salt and stray current, which significantly accelerates the corrosion process of steel bars and endangers the safety of engineering structures. In this paper, the depassivation behavior and corrosion behavior of steel bars in simulated pore solution under the combined action of low DC stray current and chloride ion were studied by electrochemical method. The results show that when the DC stray current and chloride ion coexist, the steel bar is easy to depassivate, and the two promote each other, the coupling effect is obvious. At a constant chloride ion concentration, the pH, chloride ion concentration of the corrosive medium and current density will affect the corrosion current efficiency. In the high pH environment, the current efficiency gradually increases with the increase of chloride ion concentration, but as the pH decreases or the chloride ion concentration continues to increase, the current efficiency is slightly greater than 1.0. When the concentration of chloride ions is inconsistent, the higher the concentration of chloride ions in a local area, the more severe the corrosion of the rebar in that area. The difference in resistance between the steel bar and the cathode caused by the concentration difference of chloride ions is the main reason for the different electricity consumption in each region and the overall uneven corrosion.
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来源期刊
Construction and Building Materials
Construction and Building Materials 工程技术-材料科学:综合
CiteScore
13.80
自引率
21.60%
发文量
3632
审稿时长
82 days
期刊介绍: Construction and Building Materials offers an international platform for sharing innovative and original research and development in the realm of construction and building materials, along with their practical applications in new projects and repair practices. The journal publishes a diverse array of pioneering research and application papers, detailing laboratory investigations and, to a limited extent, numerical analyses or reports on full-scale projects. Multi-part papers are discouraged. Additionally, Construction and Building Materials features comprehensive case studies and insightful review articles that contribute to new insights in the field. Our focus is on papers related to construction materials, excluding those on structural engineering, geotechnics, and unbound highway layers. Covered materials and technologies encompass cement, concrete reinforcement, bricks and mortars, additives, corrosion technology, ceramics, timber, steel, polymers, glass fibers, recycled materials, bamboo, rammed earth, non-conventional building materials, bituminous materials, and applications in railway materials.
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