Wenxian Hu , Yifan Chai , Peijun Liu , Shengli An , Jun Peng
{"title":"CeO2 对功能陶瓷石制备的影响及氨氮废水处理的吸附效果","authors":"Wenxian Hu , Yifan Chai , Peijun Liu , Shengli An , Jun Peng","doi":"10.1016/j.ceramint.2024.09.315","DOIUrl":null,"url":null,"abstract":"<div><div>This study investigates the effect of rare earth oxide CeO<sub>2</sub> on the physical properties of ceramsite and its efficiency in treating ammonia-nitrogen wastewater. Ceramsite was prepared from solid waste with 10 % coal gangue added as a pore-forming agent. Ceramsite sample I with CeO<sub>2</sub> and sample II without CeO<sub>2</sub> were prepared using pure reagents. The process parameters for both samples were optimized using an orthogonal test. Additionally, the effects of CeO<sub>2</sub> on ceramsite performance and the treatment of ammonia-nitrogen wastewater were studied, and the adsorption mechanism of CeO<sub>2</sub> on ammonia-nitrogen wastewater was clarified. The process parameters for preparing ceramsite sample Ⅰ were: preheating for 30 min at 600 °C, followed by roasting for 20 min at 1090 °C. The parameters for preparing ceramsite sample Ⅱ were: preheating for 30 min at 600 °C, followed by roasting time for 15 min at 1090 °C. The presence of CeO<sub>2</sub> increased the porosity of the ceramsite by 0.89 % and the specific surface area by 0.66 m<sup>2</sup>/g. Under neutral environmental conditions of water samples, CeO<sub>2</sub> increased the removal rate of ammonia nitrogen by 1.85 %. Ceramsite has a high porosity and specific surface area, indicating that it has abundant internal pores, a large contact area with ammonia-nitrogen, a strong ability to remove ammonia nitrogen, and resistance to erosion and water flow shear, which are conducive to the treatment of ammonia-nitrogen wastewater.</div></div>","PeriodicalId":267,"journal":{"name":"Ceramics International","volume":"50 23","pages":"Pages 49712-49723"},"PeriodicalIF":5.1000,"publicationDate":"2024-09-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Effect of CeO2 on the preparation of functional ceramsite and the adsorption effect of ammonia-nitrogen wastewater treatment\",\"authors\":\"Wenxian Hu , Yifan Chai , Peijun Liu , Shengli An , Jun Peng\",\"doi\":\"10.1016/j.ceramint.2024.09.315\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>This study investigates the effect of rare earth oxide CeO<sub>2</sub> on the physical properties of ceramsite and its efficiency in treating ammonia-nitrogen wastewater. Ceramsite was prepared from solid waste with 10 % coal gangue added as a pore-forming agent. Ceramsite sample I with CeO<sub>2</sub> and sample II without CeO<sub>2</sub> were prepared using pure reagents. The process parameters for both samples were optimized using an orthogonal test. Additionally, the effects of CeO<sub>2</sub> on ceramsite performance and the treatment of ammonia-nitrogen wastewater were studied, and the adsorption mechanism of CeO<sub>2</sub> on ammonia-nitrogen wastewater was clarified. The process parameters for preparing ceramsite sample Ⅰ were: preheating for 30 min at 600 °C, followed by roasting for 20 min at 1090 °C. The parameters for preparing ceramsite sample Ⅱ were: preheating for 30 min at 600 °C, followed by roasting time for 15 min at 1090 °C. The presence of CeO<sub>2</sub> increased the porosity of the ceramsite by 0.89 % and the specific surface area by 0.66 m<sup>2</sup>/g. Under neutral environmental conditions of water samples, CeO<sub>2</sub> increased the removal rate of ammonia nitrogen by 1.85 %. Ceramsite has a high porosity and specific surface area, indicating that it has abundant internal pores, a large contact area with ammonia-nitrogen, a strong ability to remove ammonia nitrogen, and resistance to erosion and water flow shear, which are conducive to the treatment of ammonia-nitrogen wastewater.</div></div>\",\"PeriodicalId\":267,\"journal\":{\"name\":\"Ceramics International\",\"volume\":\"50 23\",\"pages\":\"Pages 49712-49723\"},\"PeriodicalIF\":5.1000,\"publicationDate\":\"2024-09-26\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Ceramics International\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0272884224043505\",\"RegionNum\":2,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"MATERIALS SCIENCE, CERAMICS\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Ceramics International","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0272884224043505","RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"MATERIALS SCIENCE, CERAMICS","Score":null,"Total":0}
Effect of CeO2 on the preparation of functional ceramsite and the adsorption effect of ammonia-nitrogen wastewater treatment
This study investigates the effect of rare earth oxide CeO2 on the physical properties of ceramsite and its efficiency in treating ammonia-nitrogen wastewater. Ceramsite was prepared from solid waste with 10 % coal gangue added as a pore-forming agent. Ceramsite sample I with CeO2 and sample II without CeO2 were prepared using pure reagents. The process parameters for both samples were optimized using an orthogonal test. Additionally, the effects of CeO2 on ceramsite performance and the treatment of ammonia-nitrogen wastewater were studied, and the adsorption mechanism of CeO2 on ammonia-nitrogen wastewater was clarified. The process parameters for preparing ceramsite sample Ⅰ were: preheating for 30 min at 600 °C, followed by roasting for 20 min at 1090 °C. The parameters for preparing ceramsite sample Ⅱ were: preheating for 30 min at 600 °C, followed by roasting time for 15 min at 1090 °C. The presence of CeO2 increased the porosity of the ceramsite by 0.89 % and the specific surface area by 0.66 m2/g. Under neutral environmental conditions of water samples, CeO2 increased the removal rate of ammonia nitrogen by 1.85 %. Ceramsite has a high porosity and specific surface area, indicating that it has abundant internal pores, a large contact area with ammonia-nitrogen, a strong ability to remove ammonia nitrogen, and resistance to erosion and water flow shear, which are conducive to the treatment of ammonia-nitrogen wastewater.
期刊介绍:
Ceramics International covers the science of advanced ceramic materials. The journal encourages contributions that demonstrate how an understanding of the basic chemical and physical phenomena may direct materials design and stimulate ideas for new or improved processing techniques, in order to obtain materials with desired structural features and properties.
Ceramics International covers oxide and non-oxide ceramics, functional glasses, glass ceramics, amorphous inorganic non-metallic materials (and their combinations with metal and organic materials), in the form of particulates, dense or porous bodies, thin/thick films and laminated, graded and composite structures. Process related topics such as ceramic-ceramic joints or joining ceramics with dissimilar materials, as well as surface finishing and conditioning are also covered. Besides traditional processing techniques, manufacturing routes of interest include innovative procedures benefiting from externally applied stresses, electromagnetic fields and energetic beams, as well as top-down and self-assembly nanotechnology approaches. In addition, the journal welcomes submissions on bio-inspired and bio-enabled materials designs, experimentally validated multi scale modelling and simulation for materials design, and the use of the most advanced chemical and physical characterization techniques of structure, properties and behaviour.
Technologically relevant low-dimensional systems are a particular focus of Ceramics International. These include 0, 1 and 2-D nanomaterials (also covering CNTs, graphene and related materials, and diamond-like carbons), their nanocomposites, as well as nano-hybrids and hierarchical multifunctional nanostructures that might integrate molecular, biological and electronic components.