论非晶硅薄膜中氦填充纳米孔的特性

IF 6.3 2区 材料科学 Q2 CHEMISTRY, PHYSICAL Applied Surface Science Pub Date : 2024-11-17 DOI:10.1016/j.apsusc.2024.161772
Bertrand Lacroix, Asunción Fernández, N.C. Pyper, Alex J.W. Thom, Colm T. Whelan
{"title":"论非晶硅薄膜中氦填充纳米孔的特性","authors":"Bertrand Lacroix, Asunción Fernández, N.C. Pyper, Alex J.W. Thom, Colm T. Whelan","doi":"10.1016/j.apsusc.2024.161772","DOIUrl":null,"url":null,"abstract":"A joint theory–experimental study is presented of irregularly shaped nano-pores in amorphous silicon. STEM– ELLS spectra were measured for each pore. The observed helium <span><math><mrow is=\"true\"><mn is=\"true\">1</mn><msup is=\"true\"><mrow is=\"true\"><mi is=\"true\">s</mi></mrow><mrow is=\"true\"><mn is=\"true\">2</mn></mrow></msup><mo is=\"true\">→</mo><mn is=\"true\">1</mn><mi is=\"true\">s</mi><mn is=\"true\">2</mn><mi is=\"true\">p</mi></mrow></math></span>(<sup>1</sup><em>P</em>) excitation energies were found to be shifted from that of a free atom. The relation between the helium density in the pore and these energy shifts is explored and shown to be completely consistent with earlier studies of helium in its bulk condensed phases as well as encapsulated as bubbles in solid silicon. The density, pressure and depth of the pores, all key properties for applications, were determined. An alternative and novel method for determining the depth of the pores more accurately is presented.","PeriodicalId":247,"journal":{"name":"Applied Surface Science","volume":"21 1","pages":""},"PeriodicalIF":6.3000,"publicationDate":"2024-11-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"On the characteristics of helium filled nano-pores in amorphous silicon thin films\",\"authors\":\"Bertrand Lacroix, Asunción Fernández, N.C. Pyper, Alex J.W. Thom, Colm T. Whelan\",\"doi\":\"10.1016/j.apsusc.2024.161772\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"A joint theory–experimental study is presented of irregularly shaped nano-pores in amorphous silicon. STEM– ELLS spectra were measured for each pore. The observed helium <span><math><mrow is=\\\"true\\\"><mn is=\\\"true\\\">1</mn><msup is=\\\"true\\\"><mrow is=\\\"true\\\"><mi is=\\\"true\\\">s</mi></mrow><mrow is=\\\"true\\\"><mn is=\\\"true\\\">2</mn></mrow></msup><mo is=\\\"true\\\">→</mo><mn is=\\\"true\\\">1</mn><mi is=\\\"true\\\">s</mi><mn is=\\\"true\\\">2</mn><mi is=\\\"true\\\">p</mi></mrow></math></span>(<sup>1</sup><em>P</em>) excitation energies were found to be shifted from that of a free atom. The relation between the helium density in the pore and these energy shifts is explored and shown to be completely consistent with earlier studies of helium in its bulk condensed phases as well as encapsulated as bubbles in solid silicon. The density, pressure and depth of the pores, all key properties for applications, were determined. An alternative and novel method for determining the depth of the pores more accurately is presented.\",\"PeriodicalId\":247,\"journal\":{\"name\":\"Applied Surface Science\",\"volume\":\"21 1\",\"pages\":\"\"},\"PeriodicalIF\":6.3000,\"publicationDate\":\"2024-11-17\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Applied Surface Science\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://doi.org/10.1016/j.apsusc.2024.161772\",\"RegionNum\":2,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, PHYSICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Applied Surface Science","FirstCategoryId":"88","ListUrlMain":"https://doi.org/10.1016/j.apsusc.2024.161772","RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
引用次数: 0

摘要

本论文对非晶硅中的不规则纳米孔隙进行了理论与实验相结合的研究。测量了每个孔的 STEM- ELLS 光谱。研究发现,观测到的氦 1s2→1s2p(1P) 激发能量与自由原子的激发能量相比发生了偏移。孔隙中的氦密度与这些能量偏移之间的关系得到了探讨,结果表明,这种关系与早先对氦在大块凝聚相中以及作为气泡封装在固体硅中的情况进行的研究完全一致。孔隙的密度、压力和深度都是应用中的关键特性。此外,还介绍了另一种更准确地确定孔隙深度的新方法。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

摘要图片

查看原文
分享 分享
微信好友 朋友圈 QQ好友 复制链接
本刊更多论文
On the characteristics of helium filled nano-pores in amorphous silicon thin films
A joint theory–experimental study is presented of irregularly shaped nano-pores in amorphous silicon. STEM– ELLS spectra were measured for each pore. The observed helium 1s21s2p(1P) excitation energies were found to be shifted from that of a free atom. The relation between the helium density in the pore and these energy shifts is explored and shown to be completely consistent with earlier studies of helium in its bulk condensed phases as well as encapsulated as bubbles in solid silicon. The density, pressure and depth of the pores, all key properties for applications, were determined. An alternative and novel method for determining the depth of the pores more accurately is presented.
求助全文
通过发布文献求助,成功后即可免费获取论文全文。 去求助
来源期刊
Applied Surface Science
Applied Surface Science 工程技术-材料科学:膜
CiteScore
12.50
自引率
7.50%
发文量
3393
审稿时长
67 days
期刊介绍: Applied Surface Science covers topics contributing to a better understanding of surfaces, interfaces, nanostructures and their applications. The journal is concerned with scientific research on the atomic and molecular level of material properties determined with specific surface analytical techniques and/or computational methods, as well as the processing of such structures.
期刊最新文献
Ultrathin Ti3C2Tx MXene/Cellulose nanofiber composite film for enhanced mechanics & EMI shielding via freeze-thaw intercalation In-situ homologous bromine vacancies for enhanced C-Br bond activation and rapid debromination of decabromodiphenyl ether Oxygen vacancies-promoted oxidative esterification of ethylene glycol to methyl glycolate over Au/ZnO catalyst Photocatalytic dye removal with ZnO/Laser-Induced graphene nanocomposite Corrigendum to “A comparative nanotribological investigation on amorphous and polycrystalline forms of MoS2” [Appl. Surf. Sci. 672 (2024) 16042]
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
已复制链接
已复制链接
快去分享给好友吧!
我知道了
×
扫码分享
扫码分享
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1