Liexin Wu, Dr. Lu Zhang, Dr. Jiandong Guo, Jihui Gao, Yang Ding, Dr. Jie Ke, Prof. Dr. Chuan He
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引用次数: 0
摘要
不对称氢硅烷化。在他们的通讯(e202413753)中,Chuan He 等人报告了一种高效的铜催化不对称级联氢硅烷化协议,该协议可快速组装碳和硅立体硅环戊烷,并具有良好至卓越的对映选择性和非对映选择性。
Frontispiz: Catalytic Asymmetric Construction of C- and Si-Stereogenic Silacyclopentanes via Hydrosilylation of Arylmethylenecyclopropanes
Asymmetric Hydrosilylation. In their Communication (e202413753), Chuan He et al. report an efficient Cu-catalyzed asymmetric cascade hydrosilylation protocol, which allows the rapid assembly of carbon- and silicon-stereogenic silacyclopentanes with good to excellent enantioselectivities and diastereoselectivities.