Yiqie Dong , Jirong Lan , Meng Zang , Haijun Lu , Dong Zhang , Bo-Tao Huang
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The results indicated that when the ball grinding rotational speed was 550 rpm, the mass ratio of NAS to SAD was 1:1, and 5% calcium oxide was added, a 360-day compressive strength of 8.57 MPa was achieved for self-bonding materials. Under the synergistic action of mechanical collisions and high temperature, the mineral lattice of SAD was defected, and amorphous substances was appeared, the majority of the Si-O chemical bonds and Al-N bonds were broken by alkaline attack, forming a more stable structure (Si-O-Al). This approach enables the full-volume materialization of hazardous and bulk solid wastes while opening up new possibilities for municipal building materials in desert areas. 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引用次数: 0
摘要
沙漠地区由于温度极端、湿度低和缺水,给建筑施工带来了挑战。这些因素导致自粘合材料快速干燥,从而导致材料稳定性差。本研究旨在通过合作利用天然风化砂(NAS)和二次铝渣(SAD)合成自粘合材料的新方法来解决这些问题。利用 CaO 作为碱活化剂,对 NAS 和 SAD 进行机械研磨,首次成功生产出自粘合材料。结果表明,当球磨转速为 550 转/分,NAS 与 SAD 的质量比为 1:1,并添加 5%的氧化钙时,自粘合材料的 360 天抗压强度达到 8.57 兆帕。在机械碰撞和高温的协同作用下,SAD 的矿物晶格被破坏,出现了无定形物质,大部分 Si-O 化学键和 Al-N 键被碱性侵蚀破坏,形成了更稳定的结构(Si-O-Al)。这种方法实现了危险废物和大宗固体废物的全量物化,同时为沙漠地区的市政建筑材料提供了新的可能性。此外,所提出的方法还为中国 130 万平方公里沙漠和 200 万吨 SAD 的处理提供了经济可行且环保的解决方案。
Eco-friendly preparation of self-bonding materials from natural aeolian sand and secondary aluminum dross for sustainable desert construction
Desert areas pose challenges for building construction due to extreme temperatures, low humidity, and water scarcity. These factors contribute to the rapid drying of self-bonding materials, leading to poor stability of materials. This study aims to address these issues through a novel approach involving the collaborative utilization of natural aeolian sand (NAS) and secondary aluminum dross (SAD) for the synthesis of self-bonding materials. By utilizing CaO as an alkali activator, NAS, and SAD are subjected to mechanical grinding, leading to the successful production of self-bonding materials for the first time. The results indicated that when the ball grinding rotational speed was 550 rpm, the mass ratio of NAS to SAD was 1:1, and 5% calcium oxide was added, a 360-day compressive strength of 8.57 MPa was achieved for self-bonding materials. Under the synergistic action of mechanical collisions and high temperature, the mineral lattice of SAD was defected, and amorphous substances was appeared, the majority of the Si-O chemical bonds and Al-N bonds were broken by alkaline attack, forming a more stable structure (Si-O-Al). This approach enables the full-volume materialization of hazardous and bulk solid wastes while opening up new possibilities for municipal building materials in desert areas. Furthermore, the proposed method provides an economically viable and environmentally friendly solution for the treatment of 1.3 million km2 of desert and two million tons of SAD in China.
期刊介绍:
The Journal of Cleaner Production is an international, transdisciplinary journal that addresses and discusses theoretical and practical Cleaner Production, Environmental, and Sustainability issues. It aims to help societies become more sustainable by focusing on the concept of 'Cleaner Production', which aims at preventing waste production and increasing efficiencies in energy, water, resources, and human capital use. The journal serves as a platform for corporations, governments, education institutions, regions, and societies to engage in discussions and research related to Cleaner Production, environmental, and sustainability practices.