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Investigation of a novel hybrid-absorber wave energy converter combining linear (Raft-type) and point (Wavestar) absorbers for improved power extraction 结合线性(raft型)和点(Wavestar型)吸收器的新型混合吸收波能转换器的研究
IF 1 1区 环境科学与生态学 Q1 ENGINEERING, ENVIRONMENTAL Pub Date : 2025-12-13 DOI: 10.1016/j.jclepro.2025.147284
Alireza Abbasi , Hassan Ghassemi
The development of hybrid-absorbers wave energy converters (HAWECs) has gained significant attention due to their enhanced energy absorption capabilities and integration potential with various renewable sources. This study introduces an innovative HAWEC configuration, incorporating a Raft-Type (RTP) linear-absorbers wave energy converter (LAWEC) coupled with Wavestars (WS) point-absorbers wave energy converters (PAWECs), forming the linear point absorber system (LPASYS). The research investigates the impact of WS positioning on energy extraction and system synergy across three different scenarios: LPS.1, with the widest WS separation on each raft; LPS.2, featuring moderate spacing; and LPS.3, where WSs are positioned far from the RTP hinge. The distance between two WSs in each raft changes by 25 % of the raft's length. Numerical simulations employ the finite volume method (FVM) with the k-ω SST turbulence model, optimizing computational efficiency through adaptive grid refinement (AGR) and adaptive time step (ATS) techniques. Key findings indicate that the RTP achieves peak power at 1.9 rad/s, while WS.1 dominates energy absorption. WS.4 exhibits improved power generation in scenario LPS.3, with efficiency gains at 1.9 rad/s and 2.7 rad/s. Scenario LPS.3 ensures optimal survivability, with the LPASYS reaching high average power outputs of 2.8 kW at 1.6 rad/s and 1.9 kW at 1.9 rad/s. Consequently, LPASYS achieves annual energy outputs of 25.57 MWh/yr, 24.34 MWh/yr, and 24.59 MWh/yr for LPS.1, LPS.2, and LPS.3, respectively, highlighting the system's overall efficiency across different operational conditions.
混合吸收波能转换器(HAWECs)的发展由于其增强的能量吸收能力和与各种可再生能源的集成潜力而受到广泛关注。本研究介绍了一种创新的HAWEC配置,将Raft-Type (RTP)线性吸收波能转换器(LAWEC)与Wavestars (WS)点吸收波能转换器(PAWECs)相结合,形成线性点吸收系统(LPASYS)。该研究调查了三种不同情况下WS定位对能量提取和系统协同的影响:LPS.1,每个筏上WS分离最宽;LPS.2,间距适中;和LPS.3,其中WSs位于远离RTP铰链的位置。每个筏上两个WSs之间的距离变化为筏长的25%。数值模拟采用k-ω海表温度湍流模型的有限体积法(FVM),通过自适应网格细化(AGR)和自适应时间步长(ATS)技术优化计算效率。主要研究结果表明,RTP的峰值功率为1.9 rad/s,而能量吸收以WS.1为主。在情景LPS.3中,WS.4表现出改进的发电能力,效率提高到1.9 rad/s和2.7 rad/s。方案LPS.3确保了最佳的生存能力,LPASYS在1.6 rad/s时达到2.8 kW的高平均输出功率,在1.9 rad/s时达到1.9 kW的高平均输出功率。因此,LPASYS的LPS.1、LPS.2和LPS.3的年发电量分别为25.57兆瓦时/年、24.34兆瓦时/年和24.59兆瓦时/年,突出了系统在不同运行条件下的整体效率。
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引用次数: 0
Predicting microplastic impacts on microalgae: A machine learning approach to understand dynamic interactions in aquatic ecosystems 预测微塑料对微藻的影响:一种理解水生生态系统动态相互作用的机器学习方法
IF 1 1区 环境科学与生态学 Q1 ENGINEERING, ENVIRONMENTAL Pub Date : 2025-12-13 DOI: 10.1016/j.jclepro.2025.147147
Yazhou Xu , Yalei Zhang , Libin Yang , Kunsen Lin , Bo-Yu Peng , Jiabin Chen , Xuefei Zhou
Aquatic ecosystems are increasingly threatened by microplastic (MP) pollution, with microalgae, which are critical primary producers, exhibiting high sensitivity to MP-induced physiological stress. However, current models are inadequate for capturing the time-dependent dynamics of MP-microalgae interactions, particularly those shaped by environmental variability and the evolving physicochemical properties of MPs. In this study, we propose a comprehensive machine learning (ML) framework to model and predict the effects of MPs on microalgal growth. This study introduces a comprehensive machine learning (ML) framework to model and predict the impacts of MPs on microalgae growth. By integrating key MP characteristics (e.g., particle size, zeta potential, polymer type) with environmental parameters (e.g., temperature, light intensity), we constructed predictive models using six ML algorithms, including random forest and XGBoost, to evaluate both their predictive accuracy and explanatory power. Feature importance was quantified using SHAP analysis, which highlighted temperature, MP type, and zeta potential as dominant drivers of microalgal response. Furthermore, partial dependence plots (PDP) and individual conditional expectation (ICE) analyses revealed a temporal shift in influencing factors: environmental variables governed early-stage growth, whereas MP-specific properties became increasingly impactful over time. Among all models, XGBoost consistently demonstrated superior performance across time intervals. These results offer novel insights into the complex, time-resolved interplay between MPs, environmental stressors, and microalgae, informing strategies for managing microplastic pollution in aquatic environments.
微塑料污染对水生生态系统的威胁日益严重,而微藻作为重要的初级生产者,对微塑料引起的生理胁迫表现出高度敏感性。然而,目前的模型不足以捕捉mp -微藻相互作用的时间依赖性动力学,特别是那些由环境可变性和mp不断变化的物理化学性质形成的动力学。在这项研究中,我们提出了一个全面的机器学习(ML)框架来建模和预测MPs对微藻生长的影响。本研究引入了一个全面的机器学习(ML)框架来建模和预测MPs对微藻生长的影响。通过将关键MP特征(如粒径、zeta电位、聚合物类型)与环境参数(如温度、光照强度)相结合,我们使用包括随机森林和XGBoost在内的六种ML算法构建了预测模型,以评估其预测准确性和解释力。利用SHAP分析量化特征重要性,强调温度、MP类型和zeta电位是微藻反应的主要驱动因素。此外,部分依赖图(PDP)和个体条件期望(ICE)分析揭示了影响因素的时间变化:环境变量控制早期生长,而mp特异性随着时间的推移变得越来越有影响力。在所有模型中,XGBoost在不同的时间间隔内始终表现出卓越的性能。这些结果为MPs、环境压力源和微藻之间复杂的、时间解决的相互作用提供了新的见解,为管理水生环境中微塑料污染的策略提供了信息。
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引用次数: 0
Comparative analysis of ethylene-vinyl acetate debonding with D-limonene and Trichloroethylene in a life cycle perspective: Towards the directional separation of end-of-life photovoltaic panels 生命周期视角下乙烯-醋酸乙烯与d-柠檬烯和三氯乙烯脱粘的对比分析:面向报废光伏板的定向分离
IF 1 1区 环境科学与生态学 Q1 ENGINEERING, ENVIRONMENTAL Pub Date : 2025-12-12 DOI: 10.1016/j.jclepro.2025.147310
Yanlin Wu , Shuangyi Liu , Bolin Chen , Gilles Mailhot , Jie Yang , Min Zhao , Xiaojiao Zhang , Qin Xu , Yaoguang Guo , Shuai Chen , Weiguo Dong , Jie Guan
The reuse of end-of-life (EOL) photovoltaic (PV) panels, which had become a prevalent renewable energy technology worldwide over recent decades, posed significant challenges. This study started the research with 7 different organic solvent, including trichloroethylene (TCE), toluene (TOL), D-limonene, isopropanol (IPA), ethyl acetate (EAC), ethanol and methanol, to create an innovative swelling-dissolution process and aim at facilitating the directional separation of EOL-PV components and reusing them. D-limonene showed the best efficiency and most environmental-friendly. Experimental findings revealed that with the solid-liquid ratio of 1:15 and the ultrasonic power setting of 200 W for 40 min, D-limonene achieved an ethylene-vinyl acetate (EVA) dissolution rate of 96.2 %. Characterization of the recovered materials showed that the glass, solar cell and backsheet maintained high physicochemical integrity, indicating significant potential for reuse. The byproducts of D-limonene and TCE systems were analyzed by GC-MS. Toxicity evaluation showed the byproducts of D-limonene system were less toxic than TCE system. Life cycle assessment (LCA) indicated its environmental superiority across multiple impact categories, highlighting the considerable environmental advantages of D-limonene. This research presented an effective and environmentally sustainable solution for EOL-PV recycling, offering a highly efficient approach for directional separation of EOL-PV panels.
近几十年来,报废(EOL)光伏(PV)面板的再利用已成为全球流行的可再生能源技术,但也面临着重大挑战。本研究以三氯乙烯(TCE)、甲苯(TOL)、d -柠檬烯(d -柠檬烯)、异丙醇(IPA)、乙酸乙酯(EAC)、乙醇和甲醇等7种不同的有机溶剂为研究对象,建立了一种创新的溶胀-溶解工艺,旨在促进EOL-PV组分的定向分离和再利用。d -柠檬烯效率最高,最环保。实验结果表明,在料液比为1:15、超声功率为200 W、作用时间为40 min的条件下,d-柠檬烯对乙酸乙烯酯(EVA)的溶出率为96.2%。对回收材料的表征表明,玻璃、太阳能电池和背板保持了很高的物理化学完整性,表明了再利用的巨大潜力。采用气相色谱-质谱分析了d -柠檬烯和TCE体系的副产物。毒性评价表明,d -柠檬烯体系副产物毒性低于TCE体系。生命周期评价(LCA)显示了d -柠檬烯在多个影响类别上的环境优势,突出了其显著的环境优势。本研究提出了一种有效且环境可持续的EOL-PV回收解决方案,为EOL-PV面板的定向分离提供了一种高效的方法。
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引用次数: 0
Valorization of yellow phosphorus slag toward high-performance NaA zeolite for CO2 capture 黄磷渣为捕集CO2的高性能NaA沸石的增值研究
IF 1 1区 环境科学与生态学 Q1 ENGINEERING, ENVIRONMENTAL Pub Date : 2025-12-12 DOI: 10.1016/j.jclepro.2025.147272
Fangyuan Li , Wei Jiang , Zhongqiu Luo , Xiunan Cai , Fengmei Zhang , Pingyan Wang , Kuaimei Li , Xintao Zhou
Zeolitic materials are central to scalable CO2 capture technologies, yet challenges remain in optimizing raw materials and enhancing performance characteristics. In this study, the direct conversion of yellow phosphorus slag (YPS), an abundant industrial by-product, into high-performance NaA zeolite was realized via a sequential acid leaching–fusion–crystallization strategy. The effect of NaAlO2 dosage on the evolution of structural and textural properties was systematically investigated, revealing a progression from amorphous precursors to poorly crystalline phases and ultimately to highly crystalline NaA zeolite. However, crystallinity did not directly correlate with CO2 uptake. The optimized NZ-4.6 sample, pretreated at 350 °C, exhibited breakthrough and saturation capacities of 2.47 and 3.54 mmol/g at 25 °C and 1.4 mL/min CO2 flow in a fixed-bed reactor, outperforming commercial NaA zeolite (2.32 and 3.02 mmol/g). Kinetic analysis confirmed pseudo-first-order adsorption behavior with a rate constant approximately 3.2 times higher than that of the commercial counterpart, while Langmuir–Freundlich modeling predicted a theoretical maximum capacity of 5.25 mmol/g. NZ-4.6 retained over 99 % of its CO2 capacity after 15 cycles, indicating excellent stability. Mechanistic insights from in situ FT-IR revealed that synergistic physisorption–chemisorption, mediated by (Na+ … CO2)2 adducts and bidentate carbonates, was responsible for the enhanced performance. This study demonstrates how industrial waste can be transformed into advanced sorbents, providing a “waste-treats-waste” approach to CO2 mitigation. This work offers a high-value pathway for YPS treatment and provides practical insights for the preparation of derived zeolite adsorbents, advancing the “waste-treats-waste” approach to CO2 mitigation.
沸石材料是可扩展的二氧化碳捕获技术的核心,但在优化原材料和提高性能特征方面仍然存在挑战。本研究采用顺序酸浸-熔融结晶策略,实现了黄磷渣(YPS)直接转化为高性能NaA沸石。系统研究了NaAlO2用量对NaA分子筛结构和织构性能的影响,揭示了NaA分子筛从无定形前驱物到低晶相,再到高晶相的演变过程。然而,结晶度与二氧化碳吸收没有直接关系。优化后的NZ-4.6样品经350℃预处理,在固定床反应器中,在25℃和1.4 mL/min CO2流量下,突破容量和饱和容量分别为2.47和3.54 mmol/g,优于商用NaA沸石(2.32和3.02 mmol/g)。动力学分析证实了伪一级吸附行为,其速率常数约为商业对应物的3.2倍,而Langmuir-Freundlich模型预测的理论最大容量为5.25 mmol/g。经过15次循环后,NZ-4.6保留了超过99%的二氧化碳容量,表明了出色的稳定性。原位FT-IR的机理分析表明,由(Na+…CO2)2加合物和双齿碳酸盐介导的协同物理吸附-化学吸附是性能增强的原因。这项研究展示了如何将工业废物转化为高级吸附剂,为减少二氧化碳排放提供了一种“废物-处理-废物”的方法。这项工作为YPS的处理提供了一条高价值的途径,并为衍生沸石吸附剂的制备提供了实用的见解,推进了二氧化碳减排的“废物-处理-废物”方法。
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引用次数: 0
Bio-based anhydride crosslinked furan-derived vitrimeric epoxy networks with intrinsic flame retardancy, self-healing capacity and recyclability 具有内在阻燃性、自愈性和可回收性的生物基酸酐交联呋喃衍生的丙烯酸环氧树脂网络
IF 1 1区 环境科学与生态学 Q1 ENGINEERING, ENVIRONMENTAL Pub Date : 2025-12-12 DOI: 10.1016/j.jclepro.2025.147301
Tian-Mo Yang , Hao-Xin Niu , Wen-Jie Zheng , Hao-Ran Jiang , Yuan Hu , Xin Wang
To address the depletion of petroleum resources and the challenge of recycling epoxy resin, the development of green and recyclable bio-based alternatives to bisphenol A-type epoxy resins is urgently needed. In this study, a furan-derived epoxy monomer (diglycidyl furfurylamine, DGFA) was synthesized from furfurylamine, and a flame-retardant curing agent (9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide-maleic anhydride adduct, DOPO-MA) containing ester bonds was prepared via the addition of DOPO and maleic anhydride. Furan-derived epoxy vitrimers based on transesterification were fabricated by curing DGFA with a proportional mixture of DOPO-MA and glutaric anhydride. Compared with the neat vitrimer (DGFA-D0G1), the flame-retardant composites (DGFA-D1G1, DGFA-D1G1.5, DGFA-D1G2) all achieved a UL-94 V-0 rating, with the limiting oxygen index (LOI) increasing from 23.0 % to 32.0 %, 30.0 %, and 29.0 %, respectively. The peak heat release rate (PHRR) and total heat release (THR) were reduced by up to 48.6 % and 56.4 %, respectively. With the incorporation of DOPO-MA, the glass transition temperature (Tg) and rigidity of the flame-retardant vitrimers significantly increased. Notably, these composites exhibited excellent solvent resistance, even under strongly acidic conditions, and their degradation rate could be tailored by adjusting the temperature and mixed solution ratio to achieve on-demand removal. The DGFA-D1G2 sample demonstrated superior self-healing and recyclability: surface scratches were almost completely healed after heating at 150 °C for 25 min, and the tensile strength of the recycled sample retained 77.8 % of the original value, indicating well-preserved mechanical properties.
为解决石油资源枯竭和环氧树脂循环利用面临的挑战,迫切需要开发绿色可循环利用的生物基双酚a型环氧树脂替代品。本研究以呋喃胺为原料合成呋喃衍生环氧单体(二缩水甘油酯呋喃胺,DGFA),并通过DOPO与马来酸酐加成制备了含有酯键的阻燃固化剂(9,10-二氢-9-氧-10-磷菲-10-氧化物-马来酸酐加合物,DOPO- ma)。采用DOPO-MA和戊二酸酐的比例混合物固化DGFA,制备了基于酯交换反应的呋喃衍生环氧树脂。阻燃复合材料(DGFA-D1G1、DGFA-D1G1.5、DGFA-D1G2)与纯玻璃体(DGFA-D0G1)相比均达到UL-94 V-0等级,极限氧指数(LOI)分别由23.0%提高到32.0%、30.0%和29.0%。峰值放热率(PHRR)和总放热率(THR)分别降低48.6%和56.4%。DOPO-MA的掺入使阻燃玻璃体的玻璃化转变温度(Tg)和刚性显著提高。值得注意的是,即使在强酸性条件下,这些复合材料也表现出优异的耐溶剂性,并且可以通过调节温度和混合溶液比例来定制降解速率,以实现按需去除。DGFA-D1G2样品表现出优异的自愈性和可回收性:在150℃加热25 min后,表面划痕几乎完全愈合,回收样品的抗拉强度保留了原始值的77.8%,表明力学性能保存良好。
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引用次数: 0
China's household water demand scenarios under the carbon neutrality transition 碳中和转型下的中国家庭用水需求情景
IF 1 1区 环境科学与生态学 Q1 ENGINEERING, ENVIRONMENTAL Pub Date : 2025-12-12 DOI: 10.1016/j.jclepro.2025.147229
Yu-Jie Jiao , Ke-Jun Jiang , Chen-Min He , Sha Chen , Pian-Pian Xiang
This paper aims to deeply analyze the structural changes in China's household water use under the carbon neutrality transition path and predict its future development trend. By integrating key factors such as climate change, household water use habits, efficiency of water-using appliances, penetration rate and household income level, this study constructed a household water use module in the IPAC-Tech Water model, which noticeably improved the accuracy and reliability of the model in predicting future changes in water resource demand. This paper first reveals the differential characteristics of household water use in various regions of China and its potential connection with climate change through case analysis. Then, this paper sets up eight different scenarios to simulate and analyze the future household water technology structure and water demand. The results show that temperature change is a significant factor affecting household water consumption. It is estimated that by 2050, the additional water consumption caused by rising temperatures will account for 29.3 % of the total water consumption. In the absence of water-saving measures, per capita water consumption may reach 219.2 L d−1 p−1; In the scenario of extreme water-saving measures and environmental constraints, water consumption can be reduced to 83.5 L d−1 p−1; In the most likely scenario, per capita water consumption is expected to reach 137.1 L d−1 p−1 in 2050. In addition, this study predicts that the market share of water-saving water-using appliances will increase notably before 2040, and the use of water-saving appliances will reduce water consumption by 60 %. This paper also comprehensively scores household water-using appliances with different water efficiency levels and quantifies the actual water-saving effect of water-saving appliances. The study further reveals the decoupling phenomenon between socioeconomic development and domestic water consumption, pointing out that water prices and income have limited impact on household domestic water consumption. This study emphasizes that when formulating water resources management and water conservation strategies, attention should be paid to the impact of temperature changes and the market share of domestic water-using appliances with different energy efficiency levels. These findings provide a scientific basis for policymakers, which will help formulate effective water resources management and water conservation strategies and promote the sustainable use of water resources.
本文旨在深入分析碳中和转型路径下中国家庭用水的结构变化,并预测其未来发展趋势。本研究通过整合气候变化、家庭用水习惯、用水器具效率、普及率、家庭收入水平等关键因素,在IPAC-Tech water模型中构建了家庭用水模块,显著提高了模型预测未来水资源需求变化的准确性和可靠性。本文首先通过案例分析揭示了中国不同地区家庭用水的差异特征及其与气候变化的潜在联系。然后,本文设置了八种不同的场景,模拟和分析了未来家庭用水技术结构和用水需求。结果表明,温度变化是影响居民用水的重要因素。据估计,到2050年,全球因气温上升而增加的用水量将占总用水量的29.3%。在不采取节水措施的情况下,人均用水量可能达到219.2 L d−1 p−1;在极端节水措施和环境约束情景下,用水量可降至83.5 L d−1 p−1;在最可能的情况下,2050年人均用水量预计将达到137.1 L d - 1 p - 1。此外,本研究预测,在2040年之前,节水用水器具的市场份额将显著增加,节水器具的使用将减少60%的用水量。本文还对不同用水效率水平的家用节水器具进行了综合评分,并对节水器具的实际节水效果进行了量化。研究进一步揭示了社会经济发展与家庭用水之间的脱钩现象,指出水价和收入对家庭生活用水的影响有限。本研究强调,在制定水资源管理和节水战略时,应注意温度变化的影响和不同能效水平的生活用水器具的市场份额。研究结果为决策者制定有效的水资源管理和节水战略,促进水资源的可持续利用提供了科学依据。
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引用次数: 0
Hybrid machine learning solutions for mitigating climate-induced productivity losses in sustainable construction management 混合机器学习解决方案,减轻可持续建筑管理中气候引起的生产力损失
IF 1 1区 环境科学与生态学 Q1 ENGINEERING, ENVIRONMENTAL Pub Date : 2025-12-12 DOI: 10.1016/j.jclepro.2025.147285
Ali Shehadeh , Odey Alshboul , Mohammad F. Tamimi
Climate change has contributed to increased weather extremes, which require new and proactive planning and workforce management practices in construction. This research created a hybrid machine learning model (HMLM) using XGBoost, LightGBM, and CatBoost to predict construction worker productivity across a variety of weather conditions. We trained these models for a decade-long dataset capturing daily weather parameters and productivity in U.S. construction sites. The ensemble methods were able to reduce the root mean square error (RMSE) to 4.50, a 10 % improvement over the best single model. Using the RCP 8.5 scenario, our analysis predicts substantial effects upon construction productivity due to climate change. The SHAP analysis showed that precipitation and temperature together contributed 15 % of the model’s total mean absolute SHAP importance on the test set, indicating their strong model-based influence on predicted productivity (not causation). On top of this, our findings showcase that temperature fluctuations from 15 °C to 35 °C and humidity from 40 % to 70 % could impact productivity by 7.5 %, while productivity under ideal conditions could be at 92.5 %. Accordingly, the understanding of these events used in project management has shown reductions in delays of up to 30 days while in adverse situations. A strong implementation of such a concept is found in this research showing how a construction firm could improve workforce performance and project duration by adapting for climate, and producing data-informed decision making by as much as 25 % -this research strongly advocates for a proactive management process around climate variability and uncertainty.
气候变化导致了极端天气的增加,这就要求建筑行业采取新的、积极的规划和劳动力管理措施。本研究创建了一个混合机器学习模型(HMLM),使用XGBoost、LightGBM和CatBoost来预测各种天气条件下建筑工人的生产力。我们对这些模型进行了长达十年的数据集训练,这些数据集捕获了美国建筑工地的日常天气参数和生产力。集成方法能够将均方根误差(RMSE)降低到4.50,比最佳单一模型提高10%。使用RCP 8.5情景,我们的分析预测了气候变化对建筑生产力的实质性影响。SHAP分析表明,降水和温度共同贡献了模型在测试集上的总平均绝对SHAP重要性的15%,表明它们对预测生产率有很强的基于模型的影响(而不是因果关系)。最重要的是,我们的研究结果表明,温度在15°C到35°C之间波动,湿度在40%到70%之间波动,可能会对生产率产生7.5%的影响,而理想条件下的生产率可能达到92.5%。因此,对项目管理中使用的这些事件的理解表明,在不利情况下,最多可减少30天的延误。在本研究中发现了这一概念的有力实施,该研究显示了建筑公司如何通过适应气候来提高员工绩效和项目持续时间,并产生多达25%的数据知情决策-本研究强烈主张围绕气候变化和不确定性进行主动管理过程。
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引用次数: 0
Relationship between CO2 emissions and energy consumption sub-types under impact of AI-related patents and energy-related R&D investments: Evidence from the USA by novel quantile-based methods 人工智能相关专利和能源相关研发投资影响下二氧化碳排放与能源消费子类型的关系:来自美国的基于新分位数方法的证据
IF 1 1区 环境科学与生态学 Q1 ENGINEERING, ENVIRONMENTAL Pub Date : 2025-12-12 DOI: 10.1016/j.jclepro.2025.147299
Mustafa Tevfik Kartal , Eonsoo Kim , Shahriyar Mukhtarov , Dilvin Taşkın , Derviş Kirikkaleli , Serpil Kılıç Depren , Jinsu Park
The importance of AI and R&D investments has become increasingly salient in the context of rising carbon dioxide (CO2) emissions. So, this study examines how CO2 emissions relate to energy consumption (EC) sub-types and whether AI-related patents (AIP) and energy-related R&D investments (ERD) moderate the relationship. In this vein, the study focuses on the USA, uses EC sub-types as explanatory variables, considers the moderating role of AIP and ERD, and applies novel quantile-based methods on data from 1981/Q2 to 2020/Q4. The results indicate that (i) oil and coal EC are associated with higher CO2 emissions across quantiles in both bivariate and multivariate models; (ii) while gas EC increases CO2 emissions across all quantiles in bivariate and multivariate cases, there is a decreasing impact at lower quantiles with ERD moderation; (iii) nuclear EC increases CO2 emissions across all quantiles in bivariate case, whereas the impact changes under the moderating impacts of AIP and ERD; (iv) renewable EC decreases CO2 emissions across all quantiles in bivariate case, while the reducing impact is almost same under the moderating impacts of AIP and ERD; (v) AIP has a much stronger moderating impact than ERD on relationship between CO2 emissions and EC sub-types; (vi) there are generally causal impacts across quantiles, except for some lower, middle, and higher ones, where the causal impact varies across the variables pairs. Accordingly, the study outlines policy options consistent with the distributional patterns observed.
在二氧化碳排放量不断上升的背景下,人工智能和研发投资的重要性变得越来越突出。因此,本研究考察了二氧化碳排放与能源消耗(EC)亚型之间的关系,以及人工智能相关专利(AIP)和能源相关研发投资(ERD)是否调节了这种关系。在此基础上,本研究以美国为研究对象,采用EC亚型作为解释变量,考虑AIP和ERD的调节作用,并对1981/ 2季度至2020/ 4季度的数据采用新颖的基于分位数的方法。结果表明:(1)在双变量和多变量模型中,石油和煤炭EC与更高的CO2排放量相关;(ii)尽管在双变量和多变量情况下,天然气EC增加了所有分位数的二氧化碳排放,但随着ERD的缓和,较低分位数的影响会减少;(3)在双变量情况下,核EC增加了所有分位数的二氧化碳排放,而在AIP和ERD的缓和影响下,影响发生了变化;(iv)在双变量情况下,可再生能源EC减少了所有分位数的二氧化碳排放,而在AIP和ERD的缓和影响下,减少的影响几乎相同;(五)AIP对CO2排放与EC亚型关系的调节作用比ERD强得多;(vi)除了一些低、中、高的分位数外,其他分位数之间普遍存在因果影响,这些分位数的因果影响在变量对之间有所不同。因此,该研究概述了与所观察到的分配格局相一致的政策选择。
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引用次数: 0
The paradox of environmental awareness improvement and carbon footprint: a Maslow's Need-hierarchy perspective analysis in rural China 环境意识提升与碳足迹的悖论:马斯洛需求层次视角下的中国农村分析
IF 1 1区 环境科学与生态学 Q1 ENGINEERING, ENVIRONMENTAL Pub Date : 2025-12-12 DOI: 10.1016/j.jclepro.2025.147304
Mingxing Sun , Shaoyue Ma
High environmental awareness is deemed as the prerequisite of green consumption behavior; however, the improvement of the environmental awareness might need more consumption, which means that the emergence of environmental awareness may come at the cost of the environment. To verify this paradox, this study examines the relationship between environmental awareness and household carbon footprint in rural China through the lens of Maslow's Need-hierarchy theory. Leveraging micro-survey data from 3002 rural households across five provinces in 2019 and 2023, we employ an Environmentally Extended Multi-Regional Input-Output model to calculate the carbon footprint associated with various consumption categories—clothing, food, housing, and transportation—and stratify the consumables consumption and related carbon footprint into physiological, safety, social, and developmental needs according to adjusted Maslow's Need-hierarchy theory. Results reveal a 6.6 % increase in per capita carbon footprint from 2018 to 2022 (2081.18 to 2218.34 kg CO2e), driven predominantly by housing and food consumption. Regression analyses demonstrate a significant positive association between environmental awareness and consumables carbon footprint: a one-unit increase in awareness elevates total consumables-related emissions by 22.86 kg CO2e, with layer-specific increases of 6.26 kg CO2e (safety), 7.73 kg CO2e (social), and 4.62 kg CO2e (developmental needs), respectively. These findings challenge assumptions that environmental awareness inherently reduces emissions, emphasizing the necessity of structural interventions to align awareness with low-carbon transitions. Only when certain quality lifestyle achieved can environmental awareness reach the inflection point where it drives meaningful reductions in carbon emissions. The study advances theoretical discourse by integrating Maslow's hierarchy theory into environmental behavior analysis, offering policymakers evidence-based strategies to reconcile environmental awareness improvement with climate goals.
高度的环境意识被认为是绿色消费行为的前提;然而,环保意识的提高可能需要更多的消费,这意味着环保意识的出现可能是以环境为代价的。为了验证这一悖论,本研究通过马斯洛的需求层次理论考察了中国农村环境意识与家庭碳足迹之间的关系。利用2019年和2023年中国五省3002户农村家庭的微观调查数据,我们采用环境扩展的多区域投入产出模型,计算了与服装、食品、住房和交通等不同消费类别相关的碳足迹,并根据调整后的马斯洛需求层次理论,将消耗品消费和相关碳足迹分为生理需求、安全需求、社会需求和发展需求。结果显示,从2018年到2022年,人均碳足迹增加了6.6%(2081.18至2218.34千克二氧化碳当量),主要受住房和食品消费的推动。回归分析表明,环境意识与消耗品碳足迹之间存在显著的正相关关系:意识每提高一个单位,与消耗品相关的总排放量就会增加22.86千克二氧化碳当量,具体到各个阶层,分别增加6.26千克二氧化碳当量(安全)、7.73千克二氧化碳当量(社会)和4.62千克二氧化碳当量(发展需求)。这些发现挑战了环境意识本质上可以减少排放的假设,强调了结构性干预的必要性,以使意识与低碳转型保持一致。只有实现了某种高质量的生活方式,环保意识才能达到拐点,从而推动有意义的碳排放减少。本研究通过将马斯洛层次理论整合到环境行为分析中,推进了理论论述,为政策制定者提供了基于证据的策略,以协调环境意识的提高与气候目标。
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引用次数: 0
Synthesis and performance of an environmentally friendly dust depressant based on sodium lignosulfonate-acrylamide graft polymer 木质素磺酸钠-丙烯酰胺接枝聚合物环保型降尘剂的合成与性能研究
IF 1 1区 环境科学与生态学 Q1 ENGINEERING, ENVIRONMENTAL Pub Date : 2025-12-12 DOI: 10.1016/j.jclepro.2025.147311
Shohreh Ebrahimi, Ahmad Ramazani Saadatabadi, Hossein Ebrahimi
This study reports the synthesis and application of an environmentally friendly dust suppression polymer (DSP) prepared via solution graft polymerization of sodium lignosulfonate (SLS) and acrylamide. This work aims to reduce dependence on conventional chemical stabilizers by utilizing renewable lignin derivatives, thereby improving polymer biodegradability and promoting sustainable soil stabilization with minimal environmental impact. The synthesized DSP was employed for desert soil stabilization, and its performance was comprehensively evaluated through unconfined compressive strength (UCS), wetting–drying durability, wind erosion resistance, water retention, and water penetration tests. The results demonstrated that DSP treatment markedly enhanced soil strength, cohesion, and resistance to environmental degradation. Rheological analyses of storage and loss moduli provided insights into the viscoelastic behavior of stabilized soils, showing a strong correlation with UCS and durability outcomes. Microstructural analyses, including FE-SEM, zeta potential measurements, and EDX, revealed a continuous polymeric network around soil particles, where electrostatic and ionic interactions further reinforced interparticle bonding. Among all formulations, the 5 wt% DSP achieved the optimal balance between mechanical performance and sustainability. The novelty of this work lies in its comprehensive integration of molecular structural characterization, soil–polymer interaction mechanisms, rheological behavior, and macro-scale performance evaluation to elucidate the multi-scale mechanisms governing soil stabilization. Overall, the synthesized DSP represents a novel, high-performance, and eco-sustainable soil stabilizer, advancing the development of green geoengineering materials for erosion control and dust suppression in arid environments.
本文报道了木质素磺酸钠(SLS)与丙烯酰胺溶液接枝聚合制备的环保型抑尘聚合物(DSP)的合成与应用。本研究旨在通过利用可再生木质素衍生物来减少对传统化学稳定剂的依赖,从而提高聚合物的生物降解性,并在对环境影响最小的情况下促进可持续的土壤稳定。将合成的DSP用于荒漠土壤稳定,并通过无侧限抗压强度(UCS)、干湿耐久性、抗风蚀性、保水性能、渗透性能等试验对其进行综合评价。结果表明,DSP处理显著提高了土壤的强度、黏聚力和抗环境退化能力。存储和损失模量的流变分析提供了对稳定土壤粘弹性行为的深入了解,显示了与UCS和耐久性结果的强相关性。微观结构分析,包括FE-SEM, zeta电位测量和EDX,揭示了土壤颗粒周围的连续聚合物网络,其中静电和离子相互作用进一步加强了颗粒间的结合。在所有配方中,5%的DSP实现了机械性能和可持续性之间的最佳平衡。这项工作的新颖之处在于它将分子结构表征、土壤-聚合物相互作用机制、流变行为和宏观尺度性能评价综合起来,阐明了土壤稳定的多尺度机制。综上所述,合成的DSP代表了一种新型、高性能、生态可持续的土壤稳定剂,推动了干旱环境下治理侵蚀和降尘的绿色地球工程材料的发展。
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Journal of Cleaner Production
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