基于废风扇叶片回收玻璃纤维合成 MCM-41 介孔分子筛

IF 5 3区 材料科学 Q2 CHEMISTRY, PHYSICAL Sustainable Energy & Fuels Pub Date : 2024-10-04 DOI:10.1039/D4SE01318B
Nianxuan Wang, Song Wang, Ke Zhuang, Yun Xu, Dewang Zeng, Kai Zhou, Qian Zhang, Rui Xiao and Jingxin Xu
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引用次数: 0

摘要

清洁能源的发展导致退役风力涡轮机叶片的大量增加,这些叶片已成为一种新型固体废物。玻璃纤维是这些叶片的主要成分,可通过热解回收利用。然而,回收玻璃纤维在尺寸和机械性能方面的缺陷阻碍了其进一步的高价值利用。本文介绍了一种创新方法,即利用回收玻璃纤维作为硅源和铝源,通过碱熔融-水热法合成 Si-Al MCM-41 介孔分子筛。研究了水热合成过程中模板剂配比、水比、pH 值、水热温度和水热时间对分子筛合成的影响。结果表明,在最佳条件下合成的 MCM-41 分子筛具有均匀的介孔结构,比表面积为 831 m2 g-1,硅和铝元素分布均匀。此外,它对碱性污染物罗丹明 B 的吸附容量为 223 mg g-1。这项研究为回收玻璃纤维的高值化利用提供了一条可行的途径,并建立了一种具有优异吸附性能的新型 MCM-41 合成方法。
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Synthesis of MCM-41 mesoporous molecular sieves based on recycled glass fibers from waste fan blades

The development of clean energy leads to a significant increase in decommissioned wind turbine blades, which have become a new type of solid waste. Glass fiber, which is the main component of these blades, can be recycled through pyrolysis. However, the deficiencies in size and mechanical properties of recycled glass fibers preclude their further high-value utilization. This paper presents an innovative approach to the high-value utilization of recycled glass fibers as Si and Al sources for the synthesis of Si–Al MCM-41 mesoporous molecular sieves by the alkali fusion–hydrothermal method. The influences of the templating agent ratio, water ratio, pH, hydrothermal temperature, and hydrothermal time on the synthesis of molecular sieves during the hydrothermal synthesis process were investigated. The results show that the MCM-41 molecular sieve synthesized under optimal conditions exhibited a uniform mesoporous structure, with a specific surface area of 831 m2 g−1 and a uniform distribution of Si and Al elements. Additionally, it exhibits an adsorption capacity of 223 mg g−1 for alkaline pollutant rhodamine B. This research provides a viable path for the high-value utilization of recycled glass fibers and establishes a novel synthesis approach for MCM-41 with excellent adsorption performance.

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来源期刊
Sustainable Energy & Fuels
Sustainable Energy & Fuels Energy-Energy Engineering and Power Technology
CiteScore
10.00
自引率
3.60%
发文量
394
期刊介绍: Sustainable Energy & Fuels will publish research that contributes to the development of sustainable energy technologies with a particular emphasis on new and next-generation technologies.
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Back cover Back cover Recent advances and opportunities in perovskite-based triple-junction tandem solar cells Enhanced thermoelectric properties of Cu1.8S via the introduction of ZnS nanostructures† Back cover
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