海洋泡沫含有来自宇宙尘埃的血甘肽†。

IF 3.9 3区 化学 Q2 CHEMISTRY, MULTIDISCIPLINARY RSC Advances Pub Date : 2024-11-20 DOI:10.1039/D4RA06881E
Julie E. M. McGeoch and Malcolm W. McGeoch
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引用次数: 0

摘要

宇宙尘埃的内坠在化石和现代叠层石中留下了陨石聚合物酰胺的证据。为了寻找当今陨石继续下落的证据,我们从罗德岛的两个海滩收集了海泡石,并对其进行了 Folch 萃取,以将两亲成分浓缩在氯仿-水-甲醇相间层中。之前通过 MALDI 质谱法鉴定的陨石和叠层石中的血甘素聚合物酰胺分子在海泡石中被直接或通过其碎裂模式进行了鉴定。残留同位素富集表明其来源于地外。海泡石独特的弹性可能是由于形成了扩展的半甘氨酸晶格,从而稳定了其闭孔结构,而其轻质可能是由于光解产氢造成的。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

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Sea foam contains hemoglycin from cosmic dust†

In-falling cosmic dust has left evidence of meteoritic polymer amide in stromatolites, both fossil and modern. In search of evidence for continued present day in-fall, sea foam was collected from two beaches in Rhode Island and subjected to Folch extraction to concentrate amphiphilic components in a chloroform water–methanol interphase layer. Hemoglycin polymer amide molecules previously characterized by MALDI mass spectrometry in meteorites and stromatolites were identified in sea foam either directly, or via their fragmentation patterns. Residual isotope enrichment pointed to an extra-terrestrial origin. The unique resiliency of sea foam may be due to the formation of extended hemoglycin lattices that stabilize its closed-cell structure and its lightness can potentially be explained by photolytic hydrogen production.

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来源期刊
RSC Advances
RSC Advances chemical sciences-
CiteScore
7.50
自引率
2.60%
发文量
3116
审稿时长
1.6 months
期刊介绍: An international, peer-reviewed journal covering all of the chemical sciences, including multidisciplinary and emerging areas. RSC Advances is a gold open access journal allowing researchers free access to research articles, and offering an affordable open access publishing option for authors around the world.
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