(2E)-3 芳基-2-(4-芳基噻唑-2-基)丙烯腈的区域选择性硝化反应

IF 0.9 4区 化学 Q4 CHEMISTRY, MULTIDISCIPLINARY Russian Journal of General Chemistry Pub Date : 2024-11-19 DOI:10.1134/S1070363224100025
N. A. Pakholka, V. V. Dotsenko, N. А. Aksenov, I. V. Aksenova, S. G. Krivokolysko
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引用次数: 0

摘要

(2E)-3-芳基-2-(4-芳基-1,3-噻唑-2-基)丙烯腈与过量硝酸在 AcOH 中的反应进行了选择性反应,以 82-96% 的收率得到了之前未知的 (2E)-3-芳基-2-(4-芳基-5-硝基-1,3-噻唑-2-基)丙烯腈。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

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Regioselective Nitration of (2E)-3-Aryl-2-(4-arylthiazol-2-yl)acrylonitriles

The reaction of (2E)-3-aryl-2-(4-aryl-1,3-thiazol-2-yl)acrylonitriles with an excess of nitric acid in AcOH proceeds regioselectively to afford previously unknown (2E)-3-aryl-2-(4-aryl-5-nitro-1,3-thiazol-2-yl)acrylonitriles in 82–96% yields.

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来源期刊
CiteScore
1.40
自引率
22.20%
发文量
252
审稿时长
2-4 weeks
期刊介绍: Russian Journal of General Chemistry is a journal that covers many problems that are of general interest to the whole community of chemists. The journal is the successor to Russia’s first chemical journal, Zhurnal Russkogo Khimicheskogo Obshchestva (Journal of the Russian Chemical Society ) founded in 1869 to cover all aspects of chemistry. Now the journal is focused on the interdisciplinary areas of chemistry (organometallics, organometalloids, organoinorganic complexes, mechanochemistry, nanochemistry, etc.), new achievements and long-term results in the field. The journal publishes reviews, current scientific papers, letters to the editor, and discussion papers.
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