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引用次数: 0
摘要
许多离子液体 (IL) 都是由相互渗透的极性和非极性网络组成的。这些纳米级网络由不同的局部分子间相互作用和静电作用维持,其物理性质预计会有数量级的差异。尽管如此,用体积参数(如体积动态粘度)来描述 IL 的物理性质已是司空见惯。本研究通过应用 Saffman-Delbrück 模型解释同源系列 [Cnmim][NTf2] ILs 中离子的自扩散系数,解决了在纳米结构 ILs 中使用体积参数描述的局限性。我们证明脉冲场梯度 NMR 光谱可以有效地探测这些纯 IL 内极性/带电和非极性网络的相对粘度。我们计算出的极性粘度与文献模拟显示出良好的一致性。我们的方法为了解纳米结构介质内部的局部粘弹性环境提供了宝贵的见解。这项工作不仅有助于理解 IL 中的质量和电荷传输,还为更广泛地研究结构流体提供了新的实验视角。
Ion Diffusion Reveals Heterogeneous Viscosity in Nanostructured Ionic Liquids
Many ionic liquids (ILs) are composed of interpenetrating polar and apolar networks. These nanoscale networks are sustained by different local intermolecular and electrostatic interactions and are predicted to differ in their physical properties by orders of magnitude. Nonetheless, it is commonplace for the physical properties of ILs to be described by bulk parameters, such as the bulk dynamic viscosity. This study addresses the limitations of using bulk parameter descriptions in nanostructured ILs by applying the Saffman-Delbrück model to interpret the self-diffusion coefficient of ions within the homologous series of [Cnmim][NTf2] ILs. We demonstrate that pulsed field gradient NMR spectroscopy can effectively probe the relative viscosities of polar/charged and apolar networks within these pure ILs. Our calculated polar viscosities show good agreement with literature simulations. Our approach provides valuable insights into the local viscoelastic environments within nanostructured media. This work not only contributes to the understanding of mass and charge transport in ILs but also offers a new experimental perspective for studying structured fluids more broadly.
期刊介绍:
The Journal of Physical Chemistry (JPC) Letters is devoted to reporting new and original experimental and theoretical basic research of interest to physical chemists, biophysical chemists, chemical physicists, physicists, material scientists, and engineers. An important criterion for acceptance is that the paper reports a significant scientific advance and/or physical insight such that rapid publication is essential. Two issues of JPC Letters are published each month.