具有五烯并[1,2-b:4,5-b']二芴核心的扩展四硫杂戊烯--一种供体-受体多重氧化还原系统。

IF 2.9 3区化学 Q1 CHEMISTRY, ORGANIC Organic & Biomolecular Chemistry Pub Date : 2024-11-20 DOI:10.1039/d4ob01755b

Jeppe Granhøj, Viktor Bliksted Roug Pedersen, Kurt V Mikkelsen, Mogens Brøndsted Nielsen

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引用次数: 0

摘要

通过引入大的五烯并[1,2-b:4,5-b']二芴作为中心多环芳烃分子，制备出了一种新型的扩展四硫富戊烯。该化合物是一个多氧化还原体系，可以可逆地呈现六种氧化还原状态（-1、0、+1、+2、+3、+4）。该化合物在可见光区域表现出很强的吸收能力，其末端吸收几乎达到 700 纳米。

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Extended tetrathiafulvalene with a pentaleno[1,2-b:4,5-b']difluorene core - a donor-acceptor multi-redox system.

A novel extended tetrathiafulvalene was prepared by introducing the large pentaleno[1,2-b:4,5-b']difluorene as a central polycyclic aromatic hydrocarbon moiety. This compound behaved as a multi-redox system that could take reversibly six redox states (-1, 0, +1, +2, +3, +4). The compound exhibited strong absorptions in the visible region with an end-absorption almost reaching to 700 nm.

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