具有五烯并[1,2-b:4,5-b']二芴核心的扩展四硫杂戊烯--一种供体-受体多重氧化还原系统。

IF 2.7 3区化学 Q1 CHEMISTRY, ORGANIC Organic & Biomolecular Chemistry Pub Date : 2024-09-02 Epub Date: 2024-11-13 DOI:10.1039/d4ob01755b

Jeppe Granhøj , Viktor Bliksted Roug Pedersen , Kurt V. Mikkelsen , Mogens Brøndsted Nielsen

{"title":"具有五烯并[1,2-b:4,5-b']二芴核心的扩展四硫杂戊烯--一种供体-受体多重氧化还原系统。","authors":"Jeppe Granhøj , Viktor Bliksted Roug Pedersen , Kurt V. Mikkelsen , Mogens Brøndsted Nielsen","doi":"10.1039/d4ob01755b","DOIUrl":null,"url":null,"abstract":"<div><div>A novel extended tetrathiafulvalene was prepared by introducing the large pentaleno[1,2-<em>b</em>:4,5-<em>b</em>′]difluorene as a central polycyclic aromatic hydrocarbon moiety. This compound behaved as a multi-redox system that could take reversibly six redox states (−1, 0, +1, +2, +3, +4). The compound exhibited strong absorptions in the visible region with an end-absorption almost reaching to 700 nm.</div></div>","PeriodicalId":96,"journal":{"name":"Organic & Biomolecular Chemistry","volume":"22 47","pages":"Pages 9259-9265"},"PeriodicalIF":2.7000,"publicationDate":"2024-09-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Extended tetrathiafulvalene with a pentaleno[1,2-b:4,5-b′]difluorene core – a donor–acceptor multi-redox system†\",\"authors\":\"Jeppe Granhøj , Viktor Bliksted Roug Pedersen , Kurt V. Mikkelsen , Mogens Brøndsted Nielsen\",\"doi\":\"10.1039/d4ob01755b\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>A novel extended tetrathiafulvalene was prepared by introducing the large pentaleno[1,2-<em>b</em>:4,5-<em>b</em>′]difluorene as a central polycyclic aromatic hydrocarbon moiety. This compound behaved as a multi-redox system that could take reversibly six redox states (−1, 0, +1, +2, +3, +4). The compound exhibited strong absorptions in the visible region with an end-absorption almost reaching to 700 nm.</div></div>\",\"PeriodicalId\":96,\"journal\":{\"name\":\"Organic & Biomolecular Chemistry\",\"volume\":\"22 47\",\"pages\":\"Pages 9259-9265\"},\"PeriodicalIF\":2.7000,\"publicationDate\":\"2024-09-02\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Organic & Biomolecular Chemistry\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://www.sciencedirect.com/org/science/article/pii/S1477052024009376\",\"RegionNum\":3,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"2024/11/13 0:00:00\",\"PubModel\":\"Epub\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, ORGANIC\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Organic & Biomolecular Chemistry","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/org/science/article/pii/S1477052024009376","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"2024/11/13 0:00:00","PubModel":"Epub","JCR":"Q1","JCRName":"CHEMISTRY, ORGANIC","Score":null,"Total":0}

引用次数: 0

摘要

通过引入大的五烯并[1,2-b:4,5-b']二芴作为中心多环芳烃分子，制备出了一种新型的扩展四硫富戊烯。该化合物是一个多氧化还原体系，可以可逆地呈现六种氧化还原状态（-1、0、+1、+2、+3、+4）。该化合物在可见光区域表现出很强的吸收能力，其末端吸收几乎达到 700 纳米。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

摘要图片

查看原文

微信好友朋友圈 QQ好友复制链接

本刊更多论文

Extended tetrathiafulvalene with a pentaleno[1,2-b:4,5-b′]difluorene core – a donor–acceptor multi-redox system†

A novel extended tetrathiafulvalene was prepared by introducing the large pentaleno[1,2-b:4,5-b′]difluorene as a central polycyclic aromatic hydrocarbon moiety. This compound behaved as a multi-redox system that could take reversibly six redox states (−1, 0, +1, +2, +3, +4). The compound exhibited strong absorptions in the visible region with an end-absorption almost reaching to 700 nm.

求助全文

通过发布文献求助，成功后即可免费获取论文全文。去求助

来源期刊

Organic & Biomolecular Chemistry 化学-有机化学

CiteScore

5.50

自引率

9.40%

发文量

1056

审稿时长

1.3 months

期刊介绍： Organic & Biomolecular Chemistry is an international journal using integrated research in chemistry-organic chemistry. Founded in 2003 by the Royal Society of Chemistry, the journal is published in Semimonthly issues and has been indexed by SCIE, a leading international database. The journal focuses on the key research and cutting-edge progress in the field of chemistry-organic chemistry, publishes and reports the research results in this field in a timely manner, and is committed to becoming a window and platform for rapid academic exchanges among peers in this field. The journal's impact factor in 2023 is 2.9, and its CiteScore is 5.5.