制备掺杂有机聚合物的 SiC-Al2O3 纳米陶瓷,用于柔性纳米电子学和光学应用

IF 2.8 3区 材料科学 Q3 CHEMISTRY, PHYSICAL Silicon Pub Date : 2024-10-16 DOI:10.1007/s12633-024-03172-9
Ahmed Hashim, Hamed Ibrahim, Aseel Hadi
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引用次数: 0

摘要

本研究的目标是制作 PS-SiC-Al2O3 多功能纳米复合薄膜,将其作为一种有前途的纳米材料,用于未来的纳米电子学和光学领域。与其他纳米复合薄膜相比,PS-SiC-Al2O3 薄膜具有对紫外辐射的高吸收率、柔韧性、低带隙和价格低廉等特点。研究了 PS-SiC-Al2O3 薄膜的微观结构和光学特性。微观结构和形态特性包括傅立叶变换红外光谱(FTIR)和可见光光谱(OM)。研究结果表明,PS-SiC-Al2O3 薄膜在近红外和紫外光谱下的吸光度较高。这些结果表明,PS-SiC-Al2O3 薄膜有望用于近红外传感、紫外线屏蔽和光电子学方法。在 λ = 320 nm 和 SiC-Al2O3 含量为 2.4 wt.% 时,PS 吸光度的增量比为 30.9%。PS 带隙为 3.8 eV,随着 SiC-Al2O3 NPs 含量增至 2.4 wt.%,带隙降至 3.13 eV。这种性能使得 PS-SiC-Al2O3 薄膜在各种光电子和光电领域受到欢迎。随着 SiC-Al2O3 NPs 含量的增加,PS 的光学因子:消光系数、吸收系数、实介电常数、虚介电常数、折射率和光导率都得到了提高,这些结果使得 PS-SiC-Al2O3 薄膜适用于光学领域。最后,这些结果证实了 PS-SiC-Al2O3 薄膜是纳米电子学和光学领域的关键材料。
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Fabrication of SiC-Al2O3 Nanoceramic Doped Organic Polymer For Flexible Nanoelectronics and Optical Applications

The current study goals to create of PS-SiC-Al2O3 multifunctional nanocomposites films as a promising nanomaterials to exploit in futuristic nanoelectronics and optical fields. By comparing with other nanocomposites films, the PS-SiC-Al2O3 films have high absorption for UV-radiation, flexible, low band gap, and inexpensive. The microstructure and optical characteristics of PS-SiC-Al2O3 films were investigated. The microstructure and morphological properties included FTIR and OM. The realized results indicated that the values absorbance for PS-SiC-Al2O3 films are high at NIR and UV spectrums. These results build the films of PS-SiC-Al2O3 are promising for NIR sensing, UV shielding and optoelectronics approaches. The increment ratio of PS absorbance is 30.9% for λ = 320 nm and SiC-Al2O3 content is 2.4 wt.%. The PS band gap is 3.8 eV and its reduced to 3.13 eV with increasing SiC-Al2O3 NPs content to 2.4 wt.%.. This performance leads to make the PS-SiC-Al2O3 films are welcomed in various optoelectronics and photonics fields. The optical factors: extinction coefficient; absorption coefficient; real and imaginary dielectric constants, refractive index; and optical conductivity of PS were enhanced with increasing SiC-Al2O3 NPs content; these results of lead to made the PS-SiC-Al2O3 films are suitable for optical fields. Finally, the achieved results confirmed that the PS-SiC-Al2O3 films could be as a key for promising nanoelectronics and optical fields.

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来源期刊
Silicon
Silicon CHEMISTRY, PHYSICAL-MATERIALS SCIENCE, MULTIDISCIPLINARY
CiteScore
5.90
自引率
20.60%
发文量
685
审稿时长
>12 weeks
期刊介绍: The journal Silicon is intended to serve all those involved in studying the role of silicon as an enabling element in materials science. There are no restrictions on disciplinary boundaries provided the focus is on silicon-based materials or adds significantly to the understanding of such materials. Accordingly, such contributions are welcome in the areas of inorganic and organic chemistry, physics, biology, engineering, nanoscience, environmental science, electronics and optoelectronics, and modeling and theory. Relevant silicon-based materials include, but are not limited to, semiconductors, polymers, composites, ceramics, glasses, coatings, resins, composites, small molecules, and thin films.
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