Ca3Al2B8O18：由 [AlO4] 单元诱导的具有两种拓扑六元环的石墨烯样层的硼酸盐

IF 4.3 2区化学 Q2 CHEMISTRY, MULTIDISCIPLINARY Chemical Communications Pub Date : 2024-11-22 DOI:10.1039/d4cc05571c

Ziting Yan, Dongdong Chu, Zhihua Yang, Shilie Pan, Min Zhang

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引用次数: 0

摘要

通过引入[AlO4]四面体，成功制备了一种新型硼酸盐 Ca3Al2B8O18，其类石墨烯层中含有两种拓扑六元环（6-MR）。可以确定 Ca3Al2B8O18 中的 6-MRs [B5AlO17] 是独一无二的，并且 Ca3Al2B8O18 显示出一种新的基本结构单元 [B8O19]，极大地丰富了 B-O 构型的结构多样性。

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Ca3Al2B8O18: Borate with Graphene-like Layer Featuring Two Types of Topological Six-Membered Rings Induced by [AlO4] Unit

A novel borate Ca3Al2B8O18, with two types of topological six-membered rings (6-MRs) in its Graphene-like layer, was successfully fabricated by introducing [AlO4] tetrahedra. The 6-MRs [B5AlO17] in Ca3Al2B8O18 can be identified as a unique one, and Ca3Al2B8O18 exhibits a new fundamental building block [B8O19] greatly enriching the structural diversity of B-O configurations.

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来源期刊

Chemical Communications 化学-化学综合

CiteScore

8.60

自引率

4.10%

发文量

2705

审稿时长

1.4 months

期刊介绍： ChemComm (Chemical Communications) is renowned as the fastest publisher of articles providing information on new avenues of research, drawn from all the world''s major areas of chemical research.