Ziting Yan , Dongdong Chu , Zhihua Yang , Shilie Pan , Min Zhang
{"title":"Ca3Al2B8O18：由 [AlO4] 单元诱导的具有两种拓扑六元环的石墨烯样层的硼酸盐","authors":"Ziting Yan , Dongdong Chu , Zhihua Yang , Shilie Pan , Min Zhang","doi":"10.1039/d4cc05571c","DOIUrl":null,"url":null,"abstract":"<div><div>A novel borate Ca<sub>3</sub>Al<sub>2</sub>B<sub>8</sub>O<sub>18</sub>, with two types of topological six-membered rings (6-MRs) in its graphene-like layer, was successfully fabricated by introducing [AlO<sub>4</sub>] tetrahedra. The 6-MRs [B<sub>5</sub>AlO<sub>17</sub>] in Ca<sub>3</sub>Al<sub>2</sub>B<sub>8</sub>O<sub>18</sub> can be identified as unique ones, and Ca<sub>3</sub>Al<sub>2</sub>B<sub>8</sub>O<sub>18</sub> exhibits a new fundamental building block [B<sub>8</sub>O<sub>19</sub>] greatly enriching the structural diversity of B–O configurations.</div></div>","PeriodicalId":67,"journal":{"name":"Chemical Communications","volume":"60 100","pages":"Pages 15047-15050"},"PeriodicalIF":4.3000,"publicationDate":"2024-11-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Ca3Al2B8O18: borate with a graphene-like layer featuring two types of topological six-membered rings induced by [AlO4] units†\",\"authors\":\"Ziting Yan , Dongdong Chu , Zhihua Yang , Shilie Pan , Min Zhang\",\"doi\":\"10.1039/d4cc05571c\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>A novel borate Ca<sub>3</sub>Al<sub>2</sub>B<sub>8</sub>O<sub>18</sub>, with two types of topological six-membered rings (6-MRs) in its graphene-like layer, was successfully fabricated by introducing [AlO<sub>4</sub>] tetrahedra. The 6-MRs [B<sub>5</sub>AlO<sub>17</sub>] in Ca<sub>3</sub>Al<sub>2</sub>B<sub>8</sub>O<sub>18</sub> can be identified as unique ones, and Ca<sub>3</sub>Al<sub>2</sub>B<sub>8</sub>O<sub>18</sub> exhibits a new fundamental building block [B<sub>8</sub>O<sub>19</sub>] greatly enriching the structural diversity of B–O configurations.</div></div>\",\"PeriodicalId\":67,\"journal\":{\"name\":\"Chemical Communications\",\"volume\":\"60 100\",\"pages\":\"Pages 15047-15050\"},\"PeriodicalIF\":4.3000,\"publicationDate\":\"2024-11-22\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Chemical Communications\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://www.sciencedirect.com/org/science/article/pii/S135973452402487X\",\"RegionNum\":2,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chemical Communications","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/org/science/article/pii/S135973452402487X","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Ca3Al2B8O18: borate with a graphene-like layer featuring two types of topological six-membered rings induced by [AlO4] units†
A novel borate Ca3Al2B8O18, with two types of topological six-membered rings (6-MRs) in its graphene-like layer, was successfully fabricated by introducing [AlO4] tetrahedra. The 6-MRs [B5AlO17] in Ca3Al2B8O18 can be identified as unique ones, and Ca3Al2B8O18 exhibits a new fundamental building block [B8O19] greatly enriching the structural diversity of B–O configurations.
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