Josina L. Bohlen , Nele Wieprecht , Merle Arrowsmith , Alena Häfner , Marco Neder , Holger Braunschweig
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One-step selective synthesis of doubly and triply fused chiral boroloborole derivatives†
Chiral 3a,6a-dihydroborolo[3,2-b]boroles are obtained in one diastereoselective step from the reactions of ortho-(dihaloboryl)arenes with stannole derivatives via a complex rearrangement of 1-borolyl-2-(dihaloboryl)arene intermediates.
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