Heavy metals release in lead-zinc tailings: Effects of weathering and acid rain

Heavy metals (HMs) release from lead (Pb)-zinc (Zn) tailings poses significant environmental risks to surrounding areas. Furthermore, with the natural weathering and frequently happened acid rain events, the release of HMs could be elevated. This study conducted a series of laboratory column experiments with thermodynamics and hydrogeochemical analysis to investigate the environmental behavior of HMs release in Pb-Zn tailings under natural weathering conditions and acid rain events. Results showed that the weathering of calcite facilitates the release of Pb (17.9 mg/kg) and cadmium (Cd) (0.15 mg/kg), while acid rain promotes Zn release (10.5 mg/kg) from the Fe-Mn oxides, with no significant change for arsenic (As). Among the influencing factors during the column experiments, the oxidation-reduction potential (ORP) was identified as the primary indicator for the predictions of the HMs release behavior based upon the Random Forest model (R² = 0.973 - 0.997). Correlation analysis revealed a strong relationship between coexistent ions and HM release patterns. Therefore, saturation index (SI) could effectively identify the influence range of each mineral phase on HM release. This study provides scientific evidence for effective management in carbonate-type tailings ponds.