Greenstone belt-hosted Mesoarchaean Mbarga BIF prospect, NW Congo Craton (southern Cameroon): Petrography, geochemistry, Sr-Nd isotopes, zircon u-pb geochronology, petrogenetic, and tectonic implications

Banded Iron Formations (BIFs) interbedded with schists characterize the Mbarga prospect in the Ntem Complex at the northwest edge of the Congo Craton. This study presents new whole-rock geochemical, Sr-Nd, and zircon U-Pb isotopic data for the BIFs and schists to constrain the timing and geodynamic setting of the deposit. The abundances of SiO₂ (52.81 to 79.14 wt%) and Na₂O+K₂O (4.24 to 8.54 wt%) in the schists indicate andesitic, dacitic, to rhyolitic protoliths. Trace element signatures, such as high Ba and depleted Nb-Ta concentrations, suggest a volcanic arc affinity. A well-defined U-Pb zircon age of 2890 ± 4 Ma implies a Mesoarchaean protolith age, while an imprecise Rb-Sr whole-rock age of ca. 2.65 Ga is consistent with known tectonothermal events (∼2.75 and 2.65 Ga) in the Ntem Complex. Initial ε_Nd(2.89) values of + 0.8 to + 2.0 for the schists indicate an unevolved, mantle-like source for the protoliths. The BIFs show partial to extensive alterations of magnetite to hematite-martite and are of the Algoma type. They are characterized by high Fe₂O₃ (∼54.06 wt%) and SiO₂ (∼45.40 wt%) but low Al₂O₃ (∼0.14 wt%), TiO₂ (∼0.1 wt%), Zr (∼4.92 ppm), Th (∼0.11 ppm), and REE-Y contents. Rare earth patterns marked by LREE depletion, positive Eu anomalies (∼2), mild Ce depletion (Ce/Ce* 0.67 to 1.16), and super-chondritic Y/Ho ratios (∼34) suggest formation under anoxic to suboxic Archaean marine conditions, possibly involving mixing of Archaean seawater with minor (0.1–1 %) contributions from medium- to high-T hydrothermal fluids. Sparse 2951 ± 24 Ma zircons, presumably of detrital origin, establish a depositional link to the associated schists, redefining the age of BIF deposition within the Ntem Complex to ca. 2.95–2.89 Ga. However, whole-rock Sm-Nd isotope data for five BIF samples define a scattered array with an imprecise slope equivalent to an age near 1004 ± 78 Ma, which may reflect a previously unrecognized recrystallization event in the BIFs. The initial ε_Nd of this array (−11.1 ± 2.0) suggests a crustal source. The mineralogical, geochemical, and isotopic datasets reconcile the Mbarga BIF prospect with arc magmatism in the Late Archaean, suggesting their formation in a back-arc basin setting.