Iron Formations (IFs) are critical records for reconstructing the surface environment and geochemical evolution of early Earth. As economically significant Precambrian sedimentary rocks, they serve as key archives for reconstructing early Earth’s tectonic settings and paleoenvironmental conditions. This study focuses on a unique silicate IF at Nianpan (NP), Fushun area, northern Liaoning Province, which differs from typical Banded Iron Formations (BIFs) in its distinctive mineral assemblage. By integrating petrographic, mineral-chemical, geochemical, geochronological, and isotopic analyses, we reconstruct the protolith composition and depositional environment of this specific type of IF. The NP IF comprises two main rock types: magnetite-bearing two-pyroxene ore and banded ferrosilicate quartzite, both exhibiting a well-developed compositional banding. Thermobarometric calculations using the two-pyroxene thermometer and the garnet-orthopyroxene barometer constrain peak metamorphic conditions to granulite-facies (815 °C/1.05 GPa). Zircon U-Pb dating yields a depositional age of 2533.0 ± 6.8 Ma and a metamorphic age of 2485.7 ± 7.8 Ma. Systematic geochemical and isotopic analyses demonstrate that the protolith sediments were primarily derived from seawater, with a minor hydrothermal contribution (<0.1 %). The absence of a negative Ce anomaly (whole rock), coupled with significant enrichment in δ56Fe and the presence of pyrite, collectively suggest deposition occurred in a reducing, weakly acidic marine environment. Our results support a genetic model involving: (1) initial precipitation of ferruginous-siliceous sediments from seawater with minor hydrothermal input under anoxic conditions, followed by (2) regional granulite-facies metamorphism in the late Archean to early Paleoproterozoic, ultimately forming the distinctive silicate IF at NP in the Fushun area (northern Liaoning Province) of the North China Craton (NCC).
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