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Sedimentary dynamics and sources at the “Tsunami conglomerate locality” (Fig Tree Group, 3.28–3.23 Ga, Barberton Greenstone Belt, South Africa) “海啸砾岩地区”的沉积动力学及物源(南非Barberton绿岩带3.28-3.23 Ga Fig Tree Group)
IF 3.2 2区 地球科学 Q2 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2026-06-01 Epub Date: 2026-02-21 DOI: 10.1016/j.precamres.2026.108060
Quentin Aquila , Marion Garçon , Nicolas Olivier , Christophe Thomazo , Johanna Marin-Carbonne
To illustrate the peculiarity of early Earth sedimentary dynamics and terrigenous pathways to the first oceans, a detailed sedimentological, petrographical, and geochemical study was conducted on a 40 m succession of the 3.28–3.23 Ga Mapepe Formation in the Barberton greenstone belt (South Africa). The “Tsunami conglomerate locality” includes terrigenous sediments (sandstones, conglomerates) and chemical sediments consisting of banded ferruginous chert (BFC) and banded iron formation (BIF). These deposits reflect a deep-water hemipelagic depositional system dominated by chemical sedimentation, punctuated by discrete terrigenous lobes and slope aprons. The 4.5-m-thick chert-plate conglomerate, known as the “Tsunami conglomerate”, represents high-density flow deposits, indicating gravity-driven instabilities near an abyssal plain. Although it lacks petrographically identifiable terrigenous material, these gravity-reworked BFC deposits exhibit a trace element signature indicating 10 % terrigenous inputs. Trace element signatures of terrigenous rocks indicate a source of 70 ± 10 % (ultra)mafic (75 % basalt, 25 % komatiite) and 30 ± 10 % felsic volcanic material, likely from erosion of the (ultra)mafic Onverwacht Group and related felsic volcanic deposits. These findings fill a gap in sample representativeness at the base of the Mapepe Formation in the Lower Manzimnyama Jaspillite Syncline and challenge previous interpretations of a gradual provenance shift from felsic to mafic sources. Instead, they suggest a predominantly mafic–ultramafic source for most of the Mapepe Formation, except for the lowermost Loenen Member, which consists almost entirely of felsic volcaniclastic material. Finally, most BFC, BIF, and terrigenous-rich units at the studied locality display highly variable Ce anomalies, suggesting that these rocks experienced syn- or post-depositional oxygenated conditions. In-situ analyses indicate that positive Ce anomalies are generally associated with goethite-rich cements, whereas negative anomalies are linked to sericite-(+/- rutile)-rich cements. The preferential distribution of Ce anomalies in secondary minerals demonstrates that these redox features were likely not acquired during sediment deposition, but rather during post-depositional history.
为了阐明早期地球沉积动力学的独特性和通往第一大洋的陆源通道,对南非巴伯顿绿岩带3.28-3.23 Ga Mapepe组40 m序列进行了详细的沉积学、岩石学和地球化学研究。“海啸砾岩区”包括陆源沉积物(砂岩、砾岩)和由带状含铁燧石(BFC)和带状铁地层(BIF)组成的化学沉积物。这些沉积反映了以化学沉积为主的深水半深海沉积体系,间或有陆源裂片和坡缘。4.5米厚的燧石板块砾岩,被称为“海啸砾岩”,代表高密度的流动沉积物,表明深海平原附近重力驱动的不稳定。虽然缺乏岩石学上可识别的陆源物质,但这些经过重力改造的BFC矿床显示出微量元素特征,表明10%的陆源输入。陆源岩石的微量元素特征表明,其来源为70±10%(超)基性(75%玄武岩,25%科马铁矿)和30±10%的长英质火山物质,可能来自(超)基性Onverwacht群和相关的长英质火山矿床的侵蚀。这些发现填补了下Manzimnyama碧石岩向斜Mapepe组底部样品代表性的空白,并挑战了以前关于物源逐渐从长英质向基性转变的解释。相反,他们认为,除了最底部的洛南段(Loenen Member)几乎完全由长英质火山碎屑物质组成外,大部分马佩组(Mapepe Formation)的主要来源是镁质-超镁质。最后,研究区域的大部分BFC、BIF和陆源富单元显示出高度变化的Ce异常,表明这些岩石经历了同沉积或沉积后的氧合条件。原位分析表明,正Ce异常通常与富含针铁矿的胶结物有关,而负Ce异常与富含绢云母(+/-金红石)的胶结物有关。次生矿物中Ce异常的优先分布表明,这些氧化还原特征可能不是在沉积过程中形成的,而是在沉积后形成的。
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引用次数: 0
3D magnetotelluric and multigeophysical constraints on the tectonic evolution of the Ribeira Orogen (Southeastern Brazil) 巴西东南部Ribeira造山带构造演化的三维大地电磁和多地球物理约束
IF 3.2 2区 地球科学 Q2 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2026-06-01 Epub Date: 2026-02-24 DOI: 10.1016/j.precamres.2026.108047
Adevilson Oliveira Alves , Antonio Lopes Padilha , Sergio Luiz Fontes , Nina Silva Rocha , Artur Santos Benevides , Andrea Cristina Lima dos Santos Matos , Carlos Alberto Moreno Chaves , Maxwell Azuka Meju , Emanuele Francesco La Terra
The Ribeira Orogen in southeastern Brazil preserves the Neoproterozoic–Cambrian processes involved in the final assembly of West Gondwana. To investigate its largely uncharacterized deep lithospheric structure, this study integrates long-period magnetotelluric (MT) data with seismic tomography and geothermal heat-flow information. The MT dataset includes 61 stations along five NW–SE profiles spaced 15–25 km apart, with periods from 10 to 10,000 s. A 3D MT inversion produced a detailed resistivity model examined jointly with the complementary geophysical datasets. The results reveal three high-resistivity lithospheric blocks, bounded by major conductive zones, interpreted as fragments of Rodinia reassembled during the Brasiliano Orogeny. The western block represents the eastward extension of the São Francisco paleocontinent beneath the Ribeira Orogen. The central block, underlying the Paraíba do Sul Domain, corresponds to a preserved microcontinent (Paraíba do Sul–Embu), characterized by high P-wave velocities and low surface heat flow. The eastern block, beneath the Cabo Frio Terrane, is interpreted as a fragment of the Angola–Congo paleocontinent that remained attached to South America after the opening of the South Atlantic. Two main conductive anomalies correspond to distinct tectonic episodes. The older, beneath the Occidental Terrane, records eastward subduction of the São Francisco lithosphere during the Cryogenian–Ediacaran. The younger, located at the boundary with the Cabo Frio Terrane, is associated with Tonian–Cryogenian intra-oceanic magmatic arcs later accreted to the orogen during Cambrian collision. These findings provide robust geophysical evidence that southeastern Brazil evolved through subduction-related accretionary processes, rather than intracontinental deformation.
巴西东南部的里贝拉造山带保存了西冈瓦纳最终组合的新元古代-寒武纪过程。为了研究其深层岩石圈结构,本研究将长周期大地电磁(MT)数据与地震层析成像和地热热流信息相结合。MT数据集包括沿5条NW-SE剖面的61个站点,间隔15-25公里,周期从10到10,000 s。三维MT反演得到了详细的电阻率模型,并与互补的地球物理数据集进行了联合检验。结果显示,以主要导电带为界的三个高电阻率岩石圈块体被解释为在巴西利亚造山运动期间重新组合的Rodinia碎片。西部地块代表了里贝拉造山带下奥弗朗西斯科古大陆的向东延伸。位于Paraíba do Sul域中的中央地块对应于一个保存完好的微大陆(Paraíba do Sul - embu),其特征是高纵波速度和低表面热流。位于弗里奥角岩层下方的东部板块被解释为安哥拉-刚果古大陆的一块碎片,在南大西洋打开后,它仍然与南美洲相连。两个主要的导电异常对应不同的构造期次。较古老的,在西方地体之下,记录了在低温-埃迪卡拉纪期间,旧金山岩石圈向东俯冲。较年轻的位于卡波弗里奥地体的边界,与后来寒武纪碰撞期间增生到造山带的托尼-低温期洋内岩浆弧有关。这些发现提供了强有力的地球物理证据,表明巴西东南部是通过俯冲相关的增生过程而不是大陆内变形演化而来的。
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引用次数: 0
The Rio Salitre Volcano-Sedimentary Succession, São Francisco Craton, Eastern Brazil: Record of a Siderian-Orosirian tectonic cycle 巴西东部<s:1>圣弗朗西斯科克拉通bbb20盐层火山-沉积演替:锡德-奥罗世构造旋回的记录
IF 3.2 2区 地球科学 Q2 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2026-06-01 Epub Date: 2026-02-28 DOI: 10.1016/j.precamres.2026.108067
Carina G. Lopes-Mira , Fernando F. Alkmim , Cristiano C. Lana
The basement of the São Francisco Craton in eastern Brazil records a complex history of growth and deformation that extends from the Paleoarchean up to the Orosirian Period. It hosts a segment of the Minas-Bahia Orogen, likely developed during the Orosirian assembly of the Central African block, a continental mass that would encompass the São Francisco-Congo, Borborema, Trans-Saharian, Rio de la Plata, and Kalahari shield provinces of South America and Africa. Aiming to unravel the tectonic scenarios of the Minas-Bahia Orogen generation, we conducted a stratigraphic, structural, geochemical, and geochronological study of the Rio Salitre belt of the Gavião microcontinent, the largest terrane of the Minas-Bahia Orogen exposed in the northern São Francisco craton. The Rio Salitre succession comprises a basal sedimentary unit (A), a middle volcano-sedimentary package (B), and an upper clastic sedimentary assemblage (C). Intruded by small granitic bodies and diabase dikes of unknown age, and unconformably covered by Meso- to Neoproterozoic strata, the Rio Salitre succession experienced two phases of deformation, a WNW-ESE contraction, followed by a left-lateral transtensional shearing that led to the development of a large-scale synformal keel, bound on all sides by basement uplifts. U-Pb zircon dating reveals Neoarchean (2666 ± 13 Ma) and Orosirian (1936 ± 21 Ma) maximum depositional ages, respectively, for Units A and C, and a Rhyacian depositional age of c. 2200 Ma for Unit B calc-alkaline to shoshonitic metatuffs. Our results point to a three-stage tectonic evolution of the Gavião microcontinent. Unit A represents the fill of an interior depocenter likely connected to a continental margin after 2666 Ma, whereas Unit B records its conversion into an extensional back-arc basin in the time interval of 2200 and 2100 Ma. Eventually, the Rio Salitre Basin evolved into a retro-foreland depocenter and received the clastic wedge of Unit C, accumulated after the collision of the various components of the Minas Bahia orogen. Our findings support a correlation between the Rio Salitre succession and classic Paleoproterozoic units of the São Francisco, Congo, and Kalahari cratons, thus favoring the existence of the Orosirian Central African paleocontinent.
巴西东部奥弗朗西斯科克拉通的基底记录了一个复杂的生长和变形历史,从古太古代一直延伸到奥罗世。它拥有米纳斯-巴伊亚造山带的一部分,可能是在中非块体的奥罗西亚组合期间发展起来的,这是一个大陆块,将包括南美洲和非洲的弗朗西斯科-刚果,博尔博雷马,跨撒哈拉,里约热内卢de la Plata和喀拉哈里盾省。为了揭示米纳斯-巴伊亚造山带的构造情景,我们对暴露在弗朗西斯科克拉通北部的米纳斯-巴伊亚造山带中最大的地体加维微大陆的里约热内卢盐碱带进行了地层学、构造、地球化学和年代学研究。bbb10盐层序列由基底沉积单元(a)、中部火山-沉积包体(B)和上部碎屑沉积组合(C)组成。受年龄未知的小花岗岩体和辉绿岩脉侵入,并被中-新元古代地层不整合覆盖,bbb - salitite序列经历了两个阶段的变形,即WNW-ESE收缩,然后是左侧张拉剪切,导致大规模的同型龙骨发育,四面被基底隆升束缚。U-Pb锆石测年显示,A单元和C单元的最大沉积年龄分别为新太古代(2666±13 Ma)和奥陶纪(1936±21 Ma), B单元钙碱性-玄武质变质岩的最大沉积年龄为约2200 Ma。我们的研究结果表明,加维微大陆的构造演化分为三个阶段。A单元代表2666 Ma之后可能与大陆边缘相连的内部沉积中心的充填,而B单元记录了2200 - 2100 Ma之间向伸展弧后盆地的转变。最终,里约热内卢盐碱盆地演化为后前陆沉积中心,并接受了Minas Bahia造山带各组分碰撞后形成的C单元碎屑楔。我们的研究结果支持里约热内卢- Salitre演替与弗朗西斯科、刚果和卡拉哈里克拉通的经典古元古代单元之间的相关性,从而支持奥罗世-中非古大陆的存在。
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引用次数: 0
Precambrian ribbon structures of the Grand Canyon, Arizona 亚利桑那州大峡谷的前寒武纪带状结构
IF 3.2 2区 地球科学 Q2 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2026-06-01 Epub Date: 2026-02-25 DOI: 10.1016/j.precamres.2026.108058
J.W. Hagadorn , C.M. Dehler
Macroscopic ribbon-shaped structures occur in the late Tonian Carbon Canyon Member, Galeros Formation, Chuar Group in the Grand Canyon, Arizona. Ribbons are three-dimensional dolomite clasts, are ornamented by longitudinal striations on both sides, and are ∼1 cm wide, ∼1 mm thick, and range from 2 to ≥17 cm long. Ribbons were transported and are preserved in abundance on bedding planes, often stacked atop one another. Ribbons have jagged to shredded terminations and exhibit evidence of flexure, twisting and deformation—indicating that they were pliable and torn prior to deposition. Although ribbons are morphologically similar to casts of blade-like macroalgal stipes and thalli, they lack features common to fossilized benthic algae, such as carbonaceous films. Thus, we tentatively interpret ribbons as sedimentary structures.
宏观带状构造出现在美国亚利桑那州大峡谷Chuar群Galeros组晚第三纪碳峡谷段。带状是三维白云岩碎屑,两侧有纵向条纹装饰,宽~ 1 cm,厚~ 1 mm,长度在2 ~≥17 cm之间。缎带被大量地运输和保存在铺层飞机上,通常一个叠一个。缎带的末端呈锯齿状,并显示出弯曲、扭曲和变形的迹象,表明它们在沉积之前是柔韧和撕裂的。虽然带状在形态上类似于叶片状的大型藻茎和菌体,但它们缺乏底栖藻类化石的共同特征,如碳质薄膜。因此,我们暂时将带状解释为沉积构造。
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引用次数: 0
Early Cambrian occurrence of multicellular algae Wengania: Survivors of the terminal Ediacaran Kotlinian Crisis 早寒武纪多细胞藻类Wengania的出现:埃迪卡拉末期Kotlinian危机的幸存者
IF 3.2 2区 地球科学 Q2 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2026-06-01 Epub Date: 2026-02-21 DOI: 10.1016/j.precamres.2026.108061
Huijuan You , Xiaodong Shang , Pengju Liu
The diversity of macroscopic life represented by Ediacara-type organisms remarkably declined at the terminal Ediacaran, previously recognized as the “Kotlinian Crisis”. Genus Wengania, a typical multicellular microalga from the Ediacaran Period, was previously thought to occur exclusively prior to the Kotlinian Crisis. In this study, well-preserved microfossils of Wengania are recovered from the early Cambrian Zhujiaqing Formation at the Xiaotan section in the Yunnan Province of South China, including Wengania exquisita and Wengania globosa. Acanthomorphic acritarch Comasphaeridium velvetum, four genera (eight species) of cyanobacteria, sponge spicules and small shelly fossils (SSFs) are also identified in the study, indicating an early Cambrian age for the Xiaotan assemblage. The occurrence of multicellular algae Wengania in the earliest Cambrian suggests that it survived the Kotlinian Crisis and extended across the Ediacaran–Cambrian boundary. To better understand the evolutionary pattern of multicellular microalgae during the transitional interval, we compiled the biodiversity data from Ediacaran to early Cambrian strata in South China, revealing a significant decrease in diversity during the terminal Ediacaran. The Xiaotan assemblage containing diverse primary producers and consumers indicates a recovery of the marine ecosystem following the end of Kotlinian Crisis. It expands the spatial and temporal distribution of typical Ediacaran multicellular algae and provides fossil evidence for the earliest stage of the Cambrian Explosion.
以埃迪卡拉类生物为代表的宏观生命多样性在埃迪卡拉末期显著下降,之前被认为是“Kotlinian危机”。Wengania属是埃迪卡拉纪的一种典型的多细胞微藻,以前被认为只出现在Kotlinian危机之前。本研究在云南小滩剖面的早寒武世朱家青组中发现了保存完好的温杖菌微化石,包括精美温杖菌(Wengania exquisita)和球形温杖菌(Wengania globosa)。研究还发现了棘状棘足类Comasphaeridium velvetum、4属(8种)蓝藻、海绵针状体和小壳类化石(SSFs),表明小滩组合处于早寒武纪。多细胞藻类Wengania在寒武纪早期的出现表明它在Kotlinian危机中幸存下来,并跨越了埃迪卡拉-寒武纪的边界。为了更好地了解多细胞微藻在过渡时期的进化模式,我们收集了中国南方埃迪卡拉纪至早寒武世地层的生物多样性数据,发现埃迪卡拉纪晚期多细胞微藻多样性明显减少。小滩组合包含不同的初级生产者和消费者,表明海洋生态系统在Kotlinian危机结束后恢复。它扩展了典型埃迪卡拉纪多细胞藻类的时空分布,为寒武纪大爆发的早期阶段提供了化石证据。
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引用次数: 0
Morphology and C-isotopic composition affirm biogenicity of Mesoarchean sphaeromorph organic-walled microfossils from the ∼3.0 Ga Farrel Quartzite, Western Australia 澳大利亚西部~ 3.0 Ga Farrel石英岩中太古代球型有机壁微化石的形态和碳同位素组成证实了其生物源性
IF 3.2 2区 地球科学 Q2 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2026-06-01 Epub Date: 2026-03-03 DOI: 10.1016/j.precamres.2026.108062
Kenichiro Sugitani , Kohei Sasaki , Akizumi Ishida , Motoko Igisu , Kaho Ishibashi , Mariko Yamamoto , Minako Hashiguchi , Heda Agić , Stanley M. Awramik
Carbonaceous cherts of the ca. 3.0 Ga Farrel Quartzite in the Pilbara Craton, Western Australia host abundant morphologically diverse microfossils including filaments, spheroids, and lenses of unknown biological affinities, as well as films. The Farrel Quartzite microfossils are organically walled, include forms similar to younger (Proterozoic) leiosphaerids, and some can be extracted by palynological acid maceration. Thus, they represent the oldest records of organic-walled microfossils (OWMs) and non-pollen palynomorphs. The Farrel Quartzite OWMs are composed largely of lenses, with subordinate of flexible-walled large spheroids (FWLSs) and films, among which the FWLSs and films have been poorly described and examined. In this study, we report morphology, texture, and chemical features including Raman spectra, Fourier transform infrared spectra, and carbon isotopic composition of the FWLSs, all of which point to their biogenicity. Their dispersed occurrence in petrographic thin sections and the lack of morphologies corresponding to reproduction stages such as budding and division imply that they represent resting stage, which remains to be explored further. The major axis of the extracted FWLSs (n = 185) ranges from 67 µm to 247 µm with the mean value of 180 µm, which are correlative to the Proterozoic and the 3.2 Ga South African OWMs that can be extractable by acid maceration. This study provides additional evidence of early evolution of microorganisms that could have produced flexible and acid-resistant sac-like large vesicles.
西澳皮尔巴拉克拉通约3.0 Ga Farrel石英岩的碳质燧石中含有大量形态多样的微化石,包括生物亲缘未知的细丝、球状体和透镜体,以及薄膜。法雷尔石英岩微化石为有机壁状,包括与较年轻的(元古代)球状生物相似的形态,部分可通过孢粉酸浸提取。因此,它们代表了最古老的有机壁微化石(OWMs)和非花粉微态化石的记录。Farrel石英岩owm主要由透镜组成,其次是柔性壁大球体(FWLSs)和薄膜,其中FWLSs和薄膜的描述和研究较少。在这项研究中,我们报告了fwls的形态,质地和化学特征,包括拉曼光谱,傅里叶变换红外光谱和碳同位素组成,所有这些都指向它们的生物原性。它们在岩石薄片中分布较分散,且缺乏与萌芽和分裂等繁殖阶段相对应的形态,这意味着它们代表着静止阶段,这有待进一步探讨。提取的fwlms (n = 185)长轴在67 ~ 247µm之间,平均值为180µm,与酸浸法可提取的元古代和3.2 Ga南非owm相关。这项研究为微生物的早期进化提供了额外的证据,这些微生物可以产生柔性和耐酸的囊状大囊泡。
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引用次数: 0
In situ Rb–Sr geochronology records multiple fluid pulses in Neoproterozoic sequences from the Lubambe-Mingomba Cu deposits in the Zambian Copperbelt 原位Rb-Sr年代学记录了赞比亚铜带Lubambe-Mingomba铜矿床新元古代序列中的多个流体脉冲
IF 3.2 2区 地球科学 Q2 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2026-06-01 Epub Date: 2026-02-20 DOI: 10.1016/j.precamres.2026.108059
Victor Ikechukwu Vincent , Koen Torremans , Darwinaji Subarkah , Sarah E. Gilbert , Juraj Farkaš , Alan S. Collins , Jon Stacey , Aileen L. Doran , Simon Jones , Murray W. Hitzman
Beta-decay chronometers such as Rb–Sr are useful in constraining geological histories in Proterozoic basins. However, solution-based beta-decay Rb–Sr dating has limited applicability to resolve complex alteration history in Proterozoic basins affected by multiple thermal and fluid-flow events. This study applies tandem laser ablation ICP-MS/MS Rb–Sr dating to K-rich minerals to constrain depositional and alteration history of Neoproterozoic metasedimentary rocks in the Central African Copperbelt. Multiple generations of K-feldspar, muscovite, biotite-phlogopite and illite from the Lubambe-Mingomba Cu deposit yield both detrital (∼1700–920 Ma) and post-depositional ages (767–466 Ma) tied to successive alteration episodes. Altered K-feldspars show trace element redistribution and Rb–Sr resetting relative to detrital grains with broad depletion in Ba, Pb and Na and enrichment in Fe, Ti, Co and REEs. Cathodoluminescence emission broadly correlates with alteration intensity and style, suggesting its potential use as a proxy for feldspar alteration. The oldest alteration age (767 ± 95 Ma) records early diagenetic processes involving seawater-derived fluids, indicated by initial 87Sr/86Sr ratios similar to values for Tonian seawater and overlaps published Re–Os ages (820–770 Ma) for early Cu mineralization. Late Tonian ages (∼713 Ma) from altered detrital K-feldspars likely mark rift-driven thermal and fluid flow processes coeval with the break-up of Rodinia supercontinent. Ediacaran ages (636–600 Ma) likely record Congo–Kalahari convergence and brine migration associated with halokinesis. Early Cambrian (∼530 Ma) ages and late Cambrian-Ordovician ages (480–459 Ma) record peak Lufilian to post-Lufilian fluid flow. Phlogopite and fine-grained illite yield comparable Cambro-Ordovician ages (528–466 Ma), indicating widespread resetting during the Pan-African event in the Central African Copperbelt. These results show that in situ analysis coupled with detailed petrography can reveal progressive Rb–Sr re-equilibration in K-bearing minerals tied to tectono-hydrothermal episodes. This approach is useful for refining the chronostratigraphic framework for fluid flow in altered Proterozoic basins worldwide.
像Rb-Sr这样的β衰变计时器在限制元古代盆地的地质历史方面是有用的。然而,基于溶液的β衰变Rb-Sr测年在解决受多种热流体事件影响的元古代盆地复杂蚀变史方面适用性有限。利用串联激光烧蚀ICP-MS/MS Rb-Sr测年技术对中非铜带新元古代变质沉积岩的沉积蚀变历史进行了研究。来自Lubambe-Mingomba铜矿床的多代钾长石、白云母、黑云母-绿云母和伊利石产生了碎屑(~ 1700-920 Ma)和沉积后时代(767-466 Ma),与连续的蚀变事件有关。蚀变钾长石相对于碎屑颗粒表现出微量元素重分布和Rb-Sr重置,Ba、Pb和Na普遍亏缺,Fe、Ti、Co和ree富集。阴极发光发射与蚀变强度和样式广泛相关,表明其可能用作长石蚀变的代理。最古老的蚀变年龄(767±95 Ma)记录了早期成岩作用,包括海水衍生流体,其初始87Sr/86Sr比值与东尼亚海水相似,与早期铜成矿的Re-Os年龄(820 ~ 770 Ma)重叠。蚀变钾长石碎屑的晚托尼世年龄(~ 713 Ma)可能标志着与Rodinia超大陆分裂同时发生的裂谷驱动的热流体流动过程。埃迪卡拉纪(636-600 Ma)可能记录了刚果-喀拉哈里的辐合和与卤化作用相关的盐水迁移。早寒武世(~ 530 Ma)和晚寒武世—奥陶世(480 ~ 459 Ma)为陆菲连—后陆菲连流体流动高峰。辉云母和细粒伊利石的年龄可与寒武纪-奥陶纪相比较(528-466 Ma),表明中非铜带泛非事件期间广泛重置。这些结果表明,原位分析结合详细的岩石学可以揭示与构造-热液期有关的含钾矿物中Rb-Sr的渐进式再平衡。这种方法有助于完善世界范围内蚀变元古代盆地流体流动的年代地层格架。
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引用次数: 0
Beyond taxonomy: Raman spectroscopy reveals organic complexity in Precambrian-Cambrian microfossils from South China 超越分类学:拉曼光谱揭示华南前寒武纪-寒武纪微化石的有机复杂性
IF 3.2 2区 地球科学 Q2 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2026-06-01 Epub Date: 2026-02-23 DOI: 10.1016/j.precamres.2026.108057
Zhiji Ou , Fanwei Meng , Sebastian Willman , Jiqiang Liu , Yong Hong
Raman spectroscopy offers powerful insights into the structural characteristics of carbonaceous matter and holds promise for distinguishing phylogenetically distinct fossil groups based on differences in their organic precursors, which is essential for understanding the early evolution of eukaryotes and animals. This study applies Raman spectroscopy to organic microfossils preserved in cherts from the Precambrian–Phanerozoic boundary (∼538 Ma) in the Yangtiao section, Guizhou Province, South China. Although peak metamorphic temperatures estimated from three Raman geothermometers converge around 220 °C, significant spectral variation among fossil groups likely reflect differences in organic composition. The commonly used R1 ratio does not correlate monotonically with thermal maturity in low- to medium-grade carbonaceous matter and should not be used in isolation; instead, its relationship with other Raman parameters provides a more robust framework for assessing metamorphic maturity. Principal component analysis of Raman spectra and spectral parameters reveals that acritarchs, multicellular algae, prokaryotes, and sponge tissues form a coherent cluster, while over half of the sponge spicule spectra fall outside this group. These findings highlight the influence of organic precursors on Raman signals and demonstrate the potential of Raman spectroscopy as a rapid tool for identifying possible Precambrian animal remains.
拉曼光谱为碳质物质的结构特征提供了强有力的见解,并有望根据其有机前体的差异区分系统发育上不同的化石群,这对于理解真核生物和动物的早期进化至关重要。本文利用拉曼光谱技术对贵州省杨条剖面前寒武纪-显生宙界(~ 538 Ma)石英岩中的有机微化石进行了研究。虽然三个拉曼地温计估计的峰值变质温度大约在220°C左右,但化石组之间的显著光谱变化可能反映了有机成分的差异。在中低品位碳质物质中,常用的R1比值与热成熟度不是单调相关的,不宜单独使用;相反,它与其他拉曼参数的关系为评估变质成熟度提供了更可靠的框架。拉曼光谱和光谱参数的主成分分析表明,栖生物、多细胞藻类、原核生物和海绵组织形成了一个相干簇,而超过一半的海绵针状体光谱不在这个簇内。这些发现突出了有机前体对拉曼信号的影响,并证明了拉曼光谱作为识别可能的前寒武纪动物遗骸的快速工具的潜力。
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引用次数: 0
Insights into gold mineralization in the Arkawit area, NE Sudan: A structural, geochemical, and isotopic approach 苏丹东北部Arkawit地区金矿化研究:构造、地球化学和同位素方法
IF 3.2 2区 地球科学 Q2 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2026-06-01 Epub Date: 2026-03-02 DOI: 10.1016/j.precamres.2026.108066
Talha Mohamed Yousif , Olawale Kayode Aromolaran , Khalid Mustafa Kheiralla
Gold mineralization within the Haya Terrane (HT) of the Arabian–Nubian Shield (ANS) in NE Sudan remains genetically ambiguous due to unresolved relationships between deformation, fluid sources, and metal transport that occurred during Pan-African tectonism. Specifically, the relative contributions of structurally focused metamorphic fluids in contrast to potential magmatic inputs in gold formation have not been sufficiently constrained. This study employs an integrated approach that encompasses structural analysis, petrography, whole-rock geochemistry, in-situ LA-ICP-MS, and stable oxygen–hydrogen isotope data to establish a robust genetic model for the Arkawit gold deposit. Field and structural investigations have identified four distinct deformation phases (D1–D4). The NE–SW-trending dextral shear zones that developed during the D3 phase serve as primary conduits for hydrothermal fluid flow and the emplacement of auriferous quartz veins. Petrographic observations indicate extensive hydrothermal alteration zones, initially dominated by epidotization, followed by the formation of chlorite–sericite assemblages. Geochemical analyses reveal a moderate positive correlation between Au and Pb, alongside a negative correlation with Cu, thereby suggesting fluid evolution and metal decoupling throughout the mineralization process. Three generations of pyrite (Py1–Py3) have been distinguished based on their morphology, paragenesis, and trace element chemistry. Py1 is interpreted as magmatic, characterized by elevated levels of Ni and Co and reduced levels of Au and As. In contrast, Py2 is identified as hydrothermal in origin, exhibiting enrichment in As, Ag, and Pb. Stable isotope data indicate that the ore-forming fluids were predominantly metamorphic in nature. The δ18O values of quartz range from + 8.26‰ to + 11.73‰, with an average of + 9.68‰ and the calculated average δ18O water value is + 3‰, while the δD values of fluid inclusion water average − 44‰. These isotope values fall within the compositional range typical of metamorphic fluids in orogenic gold systems. However, limited overlap with magmatic fields suggests a minor contribution from adjacent intrusions. This study provides novel constraints on the structural and fluid controls governing gold mineralization in the HT. It confirms that structurally focused metamorphic-hydrothermal fluids were the predominant agents of ore formation. The findings present practical criteria for exploration within the ANS, emphasizing NE–SW shear zones, arsenian pyrite, and associated alteration halos as critical targets for orogenic gold exploration.
由于泛非构造运动期间发生的变形、流体来源和金属运输之间尚未解决的关系,苏丹东北部阿拉伯-努比亚盾(ANS)的哈亚地体(HT)内的金矿化在遗传学上仍然不明确。具体来说,与潜在的岩浆输入相比,构造集中的变质流体的相对贡献还没有得到充分的限制。本研究综合运用构造分析、岩石学、全岩地球化学、原位LA-ICP-MS和稳定的氧氢同位素数据,建立了Arkawit金矿床可靠的成因模型。野外和构造调查确定了四个不同的变形阶段(D1-D4)。D3期发育的ne - sw向右旋剪切带是热液流体流动和含金石英脉侵位的主要通道。岩石学观察显示广泛的热液蚀变带,最初以绿帘石为主,随后形成绿泥石-绢云母组合。地球化学分析表明,Au和Pb呈中等正相关,与Cu呈负相关,表明成矿过程中流体演化和金属解耦。根据黄铁矿的形态、共生特征和微量元素化学特征,划分了三代黄铁矿(Py1-Py3)。Py1为岩浆成因,其特征为Ni、Co含量升高,Au、as含量降低。Py2为热液成因,主要富集as、Ag和Pb。稳定同位素资料表明,成矿流体以变质流体为主。石英的δ18O值为+ 8.26‰~ + 11.73‰,平均为+ 9.68‰,计算得到的平均δ18O值为+ 3‰,流体包裹体水的δD值平均为- 44‰。这些同位素值落在造山带金系统中典型变质流体的组成范围内。然而,与岩浆场的有限重叠表明邻近侵入物的贡献很小。该研究为高温下构造和流体控制金矿化提供了新的约束条件。证实了构造聚焦型变质热液是成矿的主要因素。这些发现为ANS内的找矿提供了实用标准,强调NE-SW剪切带、砷-黄铁矿及其相关蚀变晕是造山带找金的关键目标。
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引用次数: 0
Quality matters: A comparison of geochemical data for Precambrian mafic volcanic rocks before and after data cleaning 质量问题:前寒武纪基性火山岩地球化学数据清洗前后的比较
IF 3.2 2区 地球科学 Q2 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2026-06-01 Epub Date: 2026-02-25 DOI: 10.1016/j.precamres.2026.108063
Chun-Tao Liu, J. ZhangZhou
The secular evolution of igneous rock compositions offers a global perspective on the evolution of the habitable Earth. Widely recognized geochemical databases, including EarthChem and GEOROC, serve as critical repositories for globally curated published data, significantly advancing our understanding of Earth’s global-scale evolution, such as the formation and evolution of plate tectonics, the continental crust, and surface environments. However, unintended errors in igneous data within the widely used databases undermines the applicability and credibility of statistical analyses and machine learning methods based on those data. These errors have arisen due to a lack of data publication principles to which researchers can adhere. Here, we address this issue by meticulously verifying age and geochemical data for Precambrian mafic volcanics against their original publications (∼1500), thereby cleaning the dataset to eliminate errors and enhance accuracy. Our cleaned dataset (n = 8162) reveals a gradual decrease in mantle partial melting during ∼2.8–2.5 Ga, contrasting with the more abrupt change previously interpreted from the raw dataset. This study highlights the critical importance of high-quality data, particularly age information, when re-evaluating previous time-series analyses of geochemical datasets.
火成岩成分的长期演化为宜居地球的演化提供了一个全球视角。广泛认可的地球化学数据库,包括EarthChem和GEOROC,作为全球整理出版数据的关键存储库,极大地促进了我们对地球全球尺度演化的理解,如板块构造、大陆地壳和地表环境的形成和演化。然而,在广泛使用的数据库中,火成岩数据中的意外错误破坏了基于这些数据的统计分析和机器学习方法的适用性和可信度。这些错误是由于缺乏研究人员可以遵守的数据发表原则而产生的。在这里,我们通过仔细验证前寒武纪基性火山的年龄和地球化学数据与原始出版物(~ 1500)来解决这个问题,从而清理数据集以消除错误并提高准确性。我们清理后的数据集(n = 8162)显示,在~ 2.8-2.5 Ga期间,地幔部分熔融逐渐减少,与之前从原始数据集解释的更为突然的变化形成对比。这项研究强调了在重新评估以前的地球化学数据集时间序列分析时,高质量数据,特别是年龄信息的重要性。
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引用次数: 0
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Precambrian Research
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