CuI/MnO2 纳米催化合成具有生物活性的 2-取代苯并咪唑

IF 4.4 3区化学 Q1 CHEMISTRY, INORGANIC & NUCLEAR Inorganic Chemistry Communications Pub Date : 2024-11-17 DOI:10.1016/j.inoche.2024.113556

Nisha , Sahil Kohli , Khushboo Aggarwal , Snigdha Singh , Neera Sharma , Ramesh Chandra

{"title":"CuI/MnO2 纳米催化合成具有生物活性的 2-取代苯并咪唑","authors":"Nisha , Sahil Kohli , Khushboo Aggarwal , Snigdha Singh , Neera Sharma , Ramesh Chandra","doi":"10.1016/j.inoche.2024.113556","DOIUrl":null,"url":null,"abstract":"<div><div>This work focusses on the development and characterization of efficient CuI/MnO<sub>2</sub> nano catalyst, characterized using XPS, XRD, EDAX, FTIR, FESEM, BET (surface area: 8.01 m<sup>2</sup>/g, a pore radius: 17.052 Å and a pore volume: 0.011 cm<sup>3</sup>/g) and TEM techniques. The reactivity of this catalyst was evaluated for the synthesis of biologically active 2-substituted benzimidazoles through condensation of <em>o</em>-phenylenediamine with benzaldehydes. The process features short reaction time, high TON (997.35), green conditions, high yield, easy work-up, good green metrices values such as low E-factor (0.17) and Process mass efficiency (PMI) (1.16) high Reaction mass efficiency (RME) value (91.2 %) and carbon efficiency (CE) (94 %) are good characteristics of the synthesized catalyst.</div></div>","PeriodicalId":13609,"journal":{"name":"Inorganic Chemistry Communications","volume":"171 ","pages":"Article 113556"},"PeriodicalIF":4.4000,"publicationDate":"2024-11-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"CuI/MnO2 nanocatalysed synthesis of bioactive 2-substituted benzimidazoles\",\"authors\":\"Nisha , Sahil Kohli , Khushboo Aggarwal , Snigdha Singh , Neera Sharma , Ramesh Chandra\",\"doi\":\"10.1016/j.inoche.2024.113556\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>This work focusses on the development and characterization of efficient CuI/MnO<sub>2</sub> nano catalyst, characterized using XPS, XRD, EDAX, FTIR, FESEM, BET (surface area: 8.01 m<sup>2</sup>/g, a pore radius: 17.052 Å and a pore volume: 0.011 cm<sup>3</sup>/g) and TEM techniques. The reactivity of this catalyst was evaluated for the synthesis of biologically active 2-substituted benzimidazoles through condensation of <em>o</em>-phenylenediamine with benzaldehydes. The process features short reaction time, high TON (997.35), green conditions, high yield, easy work-up, good green metrices values such as low E-factor (0.17) and Process mass efficiency (PMI) (1.16) high Reaction mass efficiency (RME) value (91.2 %) and carbon efficiency (CE) (94 %) are good characteristics of the synthesized catalyst.</div></div>\",\"PeriodicalId\":13609,\"journal\":{\"name\":\"Inorganic Chemistry Communications\",\"volume\":\"171 \",\"pages\":\"Article 113556\"},\"PeriodicalIF\":4.4000,\"publicationDate\":\"2024-11-17\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Inorganic Chemistry Communications\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S1387700324015466\",\"RegionNum\":3,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, INORGANIC & NUCLEAR\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Inorganic Chemistry Communications","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S1387700324015466","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}

引用次数: 0

摘要

这项工作的重点是开发和表征高效的 CuI/MnO2 纳米催化剂，并使用 XPS、XRD、EDAX、傅立叶变换红外光谱、FESEM、BET（表面积：8 01 m2/g，孔径：17 052 Å，孔体积：0 011 cm3/g）和 TEM 技术对其进行表征：8.01 m2/g，孔半径：17.052 Å，孔体积：0.011 cm3/g）和 TEM 技术进行表征。在通过邻苯二胺与苯甲醛缩合合成具有生物活性的 2-取代苯并咪唑时，对该催化剂的反应活性进行了评估。该工艺具有反应时间短、吨重高（997.35）、绿色条件、产率高、易于操作、绿色指标值好等特点，如低 E 系数（0.17）和过程质量效率（PMI）（1.16）、高反应质量效率（RME）值（91.2 %）和碳效率（CE）（94 %），这些都是合成催化剂的良好特性。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

摘要图片

查看原文

微信好友朋友圈 QQ好友复制链接

本刊更多论文

CuI/MnO2 nanocatalysed synthesis of bioactive 2-substituted benzimidazoles

This work focusses on the development and characterization of efficient CuI/MnO₂ nano catalyst, characterized using XPS, XRD, EDAX, FTIR, FESEM, BET (surface area: 8.01 m²/g, a pore radius: 17.052 Å and a pore volume: 0.011 cm³/g) and TEM techniques. The reactivity of this catalyst was evaluated for the synthesis of biologically active 2-substituted benzimidazoles through condensation of o-phenylenediamine with benzaldehydes. The process features short reaction time, high TON (997.35), green conditions, high yield, easy work-up, good green metrices values such as low E-factor (0.17) and Process mass efficiency (PMI) (1.16) high Reaction mass efficiency (RME) value (91.2 %) and carbon efficiency (CE) (94 %) are good characteristics of the synthesized catalyst.

求助全文

通过发布文献求助，成功后即可免费获取论文全文。去求助

来源期刊

Inorganic Chemistry Communications 化学-无机化学与核化学

CiteScore

5.50

自引率

7.90%

发文量

1013

审稿时长

53 days

期刊介绍： Launched in January 1998, Inorganic Chemistry Communications is an international journal dedicated to the rapid publication of short communications in the major areas of inorganic, organometallic and supramolecular chemistry. Topics include synthetic and reaction chemistry, kinetics and mechanisms of reactions, bioinorganic chemistry, photochemistry and the use of metal and organometallic compounds in stoichiometric and catalytic synthesis or organic compounds.