P.P. Bhattacharjee , N. Sai Teja , S. Paul , P.K. Ojha , R. Saha
{"title":"低堆积断层能(SFE)催化裂化材料的退火纹理:从二元合金到高熵合金 (HEA)","authors":"P.P. Bhattacharjee , N. Sai Teja , S. Paul , P.K. Ojha , R. Saha","doi":"10.1016/j.jalmes.2024.100130","DOIUrl":null,"url":null,"abstract":"<div><div>Although the origin of brass-type deformation texture in low SFE alloys has been extensively investigated, the annealing textures of such materials have received less attention, mostly limited to brass and different austenitic steels. On the other hand, the annealing textures of low SFE HEAs have been investigated more intensively recently; however, a comprehensive insight into annealing texture formation from HEAs down to binary systems is missing. To bridge the gap, the annealing texture of FCC single-phase Cu-11.6 at%Al alloy with SFE ∼10 <span><math><mrow><mi>mJ</mi><msup><mrow><mi>m</mi></mrow><mrow><mo>−</mo><mn>2</mn></mrow></msup></mrow></math></span> comparable to HEAs was first investigated as a model binary system and compared with selected low SFE binary, medium entropy (MEAs), and HEAs to understand the similarities and characteristic differences. The cold-rolled alloy showed massive nanostructure and a typical brass-type texture featured by a strong B ({110}<112>) component expected for a low SFE alloy. Annealing resulted in ultrafine recrystallized microstructure but extensive grain growth at higher temperatures, like other binary alloys but unlike HEAs. The annealing texture showed the retention of deformation components, weak α-fiber (ND//<110>) components and a high random fraction. These features were very similar to HEAs/MEAs and attributed to the absence of oriented nucleation (ON) or oriented growth (OG) mechanisms. However, striking differences such as strong BR ({236}<385>) and D ({113}<332>) components in the brass alloy, selective growth of the G ({110}<001>) and G/B ({110}<115>) in binary Ni-60wt%Co alloy, and strong retention of the {110}<112> component in the annealing texture of (FCC+B2) dual-phase AlCrFe<sub>2</sub>Ni<sub>2</sub> HEA were remarkable. These outcomes indicated underlying microstructural effects on annealing texture formation in low SFE binary to HEAs/MEAs and should motivate further research.</div></div>","PeriodicalId":100753,"journal":{"name":"Journal of Alloys and Metallurgical Systems","volume":"8 ","pages":"Article 100130"},"PeriodicalIF":0.0000,"publicationDate":"2024-11-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Annealing textures of low stacking fault energy (SFE) FCC materials: Traversing binary to high entropy alloys (HEAs)\",\"authors\":\"P.P. Bhattacharjee , N. Sai Teja , S. Paul , P.K. Ojha , R. Saha\",\"doi\":\"10.1016/j.jalmes.2024.100130\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>Although the origin of brass-type deformation texture in low SFE alloys has been extensively investigated, the annealing textures of such materials have received less attention, mostly limited to brass and different austenitic steels. On the other hand, the annealing textures of low SFE HEAs have been investigated more intensively recently; however, a comprehensive insight into annealing texture formation from HEAs down to binary systems is missing. To bridge the gap, the annealing texture of FCC single-phase Cu-11.6 at%Al alloy with SFE ∼10 <span><math><mrow><mi>mJ</mi><msup><mrow><mi>m</mi></mrow><mrow><mo>−</mo><mn>2</mn></mrow></msup></mrow></math></span> comparable to HEAs was first investigated as a model binary system and compared with selected low SFE binary, medium entropy (MEAs), and HEAs to understand the similarities and characteristic differences. The cold-rolled alloy showed massive nanostructure and a typical brass-type texture featured by a strong B ({110}<112>) component expected for a low SFE alloy. Annealing resulted in ultrafine recrystallized microstructure but extensive grain growth at higher temperatures, like other binary alloys but unlike HEAs. The annealing texture showed the retention of deformation components, weak α-fiber (ND//<110>) components and a high random fraction. These features were very similar to HEAs/MEAs and attributed to the absence of oriented nucleation (ON) or oriented growth (OG) mechanisms. However, striking differences such as strong BR ({236}<385>) and D ({113}<332>) components in the brass alloy, selective growth of the G ({110}<001>) and G/B ({110}<115>) in binary Ni-60wt%Co alloy, and strong retention of the {110}<112> component in the annealing texture of (FCC+B2) dual-phase AlCrFe<sub>2</sub>Ni<sub>2</sub> HEA were remarkable. These outcomes indicated underlying microstructural effects on annealing texture formation in low SFE binary to HEAs/MEAs and should motivate further research.</div></div>\",\"PeriodicalId\":100753,\"journal\":{\"name\":\"Journal of Alloys and Metallurgical Systems\",\"volume\":\"8 \",\"pages\":\"Article 100130\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2024-11-14\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Alloys and Metallurgical Systems\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S2949917824000798\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Alloys and Metallurgical Systems","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S2949917824000798","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 0
摘要
虽然低 SFE 合金中黄铜型变形纹理的起源已得到广泛研究,但此类材料的退火纹理却较少受到关注,主要局限于黄铜和不同的奥氏体钢。另一方面,近来对低 SFE HEA 的退火纹理进行了更深入的研究;然而,还缺少对从 HEA 到二元体系的退火纹理形成的全面了解。为了弥补这一空白,我们首先将 SFE ∼10 mJm-2 的 FCC 单相 Cu-11.6 at%Al 合金作为二元模型系统进行了退火纹理研究,并与选定的低 SFE 二元、中等熵(MEA)和 HEA 进行了比较,以了解其相似性和特征差异。冷轧合金显示出大量的纳米结构和典型的黄铜型纹理,其特点是具有低 SFE 合金应有的强 B({110}<112>)成分。退火会导致超细再结晶微观结构,但在较高温度下会出现大量晶粒生长,这与其他二元合金相同,但与 HEA 不同。退火纹理显示了变形成分的保留、弱α纤维(ND//<110>)成分和高无规成分。这些特征与 HEAs/MEAs 非常相似,并归因于缺乏取向成核(ON)或取向生长(OG)机制。然而,黄铜合金中的 BR({236}<385>)和 D({113}<332>)成分很强,G({110}<001>)和 G/B ({110}<;115>)的选择性增长,以及在(FCC+B2)双相铝铬铁镍二元 HEA 的退火纹理中{110}<112>成分的强烈保留。这些结果表明,微观结构对低 SFE 双相 HEA/MEA 的退火纹理形成有潜在影响,因此应推动进一步的研究。
Annealing textures of low stacking fault energy (SFE) FCC materials: Traversing binary to high entropy alloys (HEAs)
Although the origin of brass-type deformation texture in low SFE alloys has been extensively investigated, the annealing textures of such materials have received less attention, mostly limited to brass and different austenitic steels. On the other hand, the annealing textures of low SFE HEAs have been investigated more intensively recently; however, a comprehensive insight into annealing texture formation from HEAs down to binary systems is missing. To bridge the gap, the annealing texture of FCC single-phase Cu-11.6 at%Al alloy with SFE ∼10 comparable to HEAs was first investigated as a model binary system and compared with selected low SFE binary, medium entropy (MEAs), and HEAs to understand the similarities and characteristic differences. The cold-rolled alloy showed massive nanostructure and a typical brass-type texture featured by a strong B ({110}<112>) component expected for a low SFE alloy. Annealing resulted in ultrafine recrystallized microstructure but extensive grain growth at higher temperatures, like other binary alloys but unlike HEAs. The annealing texture showed the retention of deformation components, weak α-fiber (ND//<110>) components and a high random fraction. These features were very similar to HEAs/MEAs and attributed to the absence of oriented nucleation (ON) or oriented growth (OG) mechanisms. However, striking differences such as strong BR ({236}<385>) and D ({113}<332>) components in the brass alloy, selective growth of the G ({110}<001>) and G/B ({110}<115>) in binary Ni-60wt%Co alloy, and strong retention of the {110}<112> component in the annealing texture of (FCC+B2) dual-phase AlCrFe2Ni2 HEA were remarkable. These outcomes indicated underlying microstructural effects on annealing texture formation in low SFE binary to HEAs/MEAs and should motivate further research.