通过 LIBS 技术提高土壤地理识别能力:将联合偏度算法与反向传播神经网络相结合

IF 3.1 2区 化学 Q2 CHEMISTRY, ANALYTICAL Journal of Analytical Atomic Spectrometry Pub Date : 2024-10-08 DOI:10.1039/D4JA00251B
Weinan Zheng, Xun Gao, Kaishan Song, Hailong Yu, Qiuyun Wang, Lianbo Guo and Jingquan Lin
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引用次数: 0

摘要

细致的土壤区域划分工作是有效管理土壤资源和开发精确土壤分类系统的基础。这些系统对于有针对性地恢复、保护和提高土地资源至关重要。在这项研究中,我们引入了一种创新的土壤分类模型,该模型结合了张量理论中的联合偏度(JS)算法和反向传播神经网络(BPNN)。这一组合利用激光诱导击穿光谱仪(LIBS)的光谱数据对特定区域的土壤样本进行快速分类。该过程首先应用 JS 确定关键变量,然后优化 JS-BPNN 模型的结构。然后使用混淆矩阵、Kappa 系数和精确度等指标对模型的有效性进行评估,这些指标都强调了模型的可靠性。我们的实验结果验证了使用 JS 过滤 LIBS 光谱特征的有效性,它能有效地减少不必要的数据,同时保留光谱数据的内在物理特征。这大大增强了模型的分析能力。JS-BPNN 模型的分类准确率非常高,在测试数据集上达到了 99.8% 的峰值准确率。为了进一步验证 JS 方法在降低数据维度方面的有效性,并强调 JS-BPNN 模型的优越性,我们在土壤地理区域的分类和识别方面与其他算法(如 k-近邻(KNN)、随机森林(RF)和支持向量机(SVM))进行了比较分析。结果证实,JS 算法是降低 LIBS 光谱数据维度的有效方法,而且对于不同的分类模型,存在不同的最优特征变量,JS-BPNN 模型在土壤分类和识别任务中被证明是异常有效的。
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Enhancing soil geographic recognition through LIBS technology: integrating the joint skewness algorithm with back-propagation neural networks

The meticulous task of soil region classification is fundamental to the effective management of soil resources and the development of accurate soil classification systems. These systems are crucial for the targeted restoration, safeguarding, and enhancement of land resources. In this research, we introduce an innovative soil classification model that combines the Joint Skewness (JS) algorithm, which is grounded in tensor theory, with a Back-Propagation Neural Network (BPNN). This combination is utilized for the rapid categorization of soil samples in specified areas, making use of spectral data from Laser-Induced Breakdown Spectroscopy (LIBS). The process begins with the application of JS to identify key variables, followed by the optimization of the JS-BPNN model's structure. The effectiveness of the model is then evaluated using metrics such as the confusion matrix, Kappa coefficient, and precision, which all highlight the model's reliability. Our experimental results validate the use of JS in filtering LIBS spectral features, effectively minimizing unnecessary data while preserving the spectral data's intrinsic physical characteristics. This leads to a significant enhancement in the model's analytical capabilities. The JS-BPNN model has demonstrated remarkable classification accuracy, achieving a peak accuracy of 99.8% on the test dataset. To further validate the JS approach for reducing data dimensionality and emphasize the superiority of the JS-BPNN model, we conducted a comparative analysis with other algorithms, such as k-Nearest Neighbor (KNN), Random Forest (RF), and Support Vector Machine (SVM), for the classification and recognition of soil geographic regions. The results confirm that the JS algorithm is a potent method for reducing the dimensionality of LIBS spectral data, and for different classification models, there are different optimal characteristic variables, with the JS-BPNN model proving to be exceptionally effective in soil classification and recognition tasks.

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来源期刊
CiteScore
6.20
自引率
26.50%
发文量
228
审稿时长
1.7 months
期刊介绍: Innovative research on the fundamental theory and application of spectrometric techniques.
期刊最新文献
Back cover Laser-induced breakdown spectroscopy (LIBS): calibration challenges, combination with other techniques, and spectral analysis using data science High-precision MC-ICP-MS measurements of Cd isotopes using a novel double spike method without Sn isobaric interference† Magneto-electrical fusion enhancement of LIBS signals: a case of Al and Fe emission lines' characteristic analysis in soil Sensitive and rapid determination of the iodine/calcium ratio in carbonate rock samples by ICP-MS based on solution cathode glow discharge sampling†
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