{"title":"利用真空气相沉积技术在 cBN 颗粒表面镀 Ti-Cr 膜以增强抗压强度","authors":"Yufei Jiang , Lili Fang , Weifei Yang","doi":"10.1016/j.diamond.2024.111762","DOIUrl":null,"url":null,"abstract":"<div><div>In order to enhance compressive strength of the coating on cBN particles, this study proposes using vacuum vapor deposition to achieve a Titanium-Chromium (Ti-Cr) co-deposited coating on the surface of cBN particles. Base on deposition process of the Ti-Cr coating using vacuum vapor deposition technology, it proposed a simulation model by an Angular Coefficient Method (ACM), and conducts compressive strength experiments on the Ti-Cr coating of cBN particles. Using the simulation and analysis model, the effect of temperature on the formation of Ti-Cr coating during the reaction process was systematically analyzed, the molecular flow, the change of film thickness, and the deposition rate at different temperature stages was got, and verify the simulation results through experiments. The formation mechanism of Ti-Cr co-deposited coatings was derived by SEM, XRD characterization and reaction thermodynamic analysis. Experiments show that Ti-Cr co-deposited coatings are effective in increasing compressive strength, and the experimental results can be a guidance in controlling Ti/Cr amount in the coatings. In addition, it was found in experiments that by using vacuum vapor deposition technique, Ti/Cr powder mixing ratio of 1:1 provided the best compressive strength, and the compressive strength increased with higher Cr content in the coating after heating. This achievement is of significant importance for the formation of alloyed coatings on superhard materials, enhancing the wettability between the surfaces of superhard materials and their substrates under high-temperature conditions.</div></div>","PeriodicalId":11266,"journal":{"name":"Diamond and Related Materials","volume":"151 ","pages":"Article 111762"},"PeriodicalIF":4.3000,"publicationDate":"2024-11-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Enhanced compressive strength by Ti-Cr coating on cBN particle surface using vacuum vapor deposition\",\"authors\":\"Yufei Jiang , Lili Fang , Weifei Yang\",\"doi\":\"10.1016/j.diamond.2024.111762\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>In order to enhance compressive strength of the coating on cBN particles, this study proposes using vacuum vapor deposition to achieve a Titanium-Chromium (Ti-Cr) co-deposited coating on the surface of cBN particles. Base on deposition process of the Ti-Cr coating using vacuum vapor deposition technology, it proposed a simulation model by an Angular Coefficient Method (ACM), and conducts compressive strength experiments on the Ti-Cr coating of cBN particles. Using the simulation and analysis model, the effect of temperature on the formation of Ti-Cr coating during the reaction process was systematically analyzed, the molecular flow, the change of film thickness, and the deposition rate at different temperature stages was got, and verify the simulation results through experiments. The formation mechanism of Ti-Cr co-deposited coatings was derived by SEM, XRD characterization and reaction thermodynamic analysis. Experiments show that Ti-Cr co-deposited coatings are effective in increasing compressive strength, and the experimental results can be a guidance in controlling Ti/Cr amount in the coatings. In addition, it was found in experiments that by using vacuum vapor deposition technique, Ti/Cr powder mixing ratio of 1:1 provided the best compressive strength, and the compressive strength increased with higher Cr content in the coating after heating. This achievement is of significant importance for the formation of alloyed coatings on superhard materials, enhancing the wettability between the surfaces of superhard materials and their substrates under high-temperature conditions.</div></div>\",\"PeriodicalId\":11266,\"journal\":{\"name\":\"Diamond and Related Materials\",\"volume\":\"151 \",\"pages\":\"Article 111762\"},\"PeriodicalIF\":4.3000,\"publicationDate\":\"2024-11-09\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Diamond and Related Materials\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0925963524009750\",\"RegionNum\":3,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"MATERIALS SCIENCE, COATINGS & FILMS\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Diamond and Related Materials","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0925963524009750","RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"MATERIALS SCIENCE, COATINGS & FILMS","Score":null,"Total":0}
Enhanced compressive strength by Ti-Cr coating on cBN particle surface using vacuum vapor deposition
In order to enhance compressive strength of the coating on cBN particles, this study proposes using vacuum vapor deposition to achieve a Titanium-Chromium (Ti-Cr) co-deposited coating on the surface of cBN particles. Base on deposition process of the Ti-Cr coating using vacuum vapor deposition technology, it proposed a simulation model by an Angular Coefficient Method (ACM), and conducts compressive strength experiments on the Ti-Cr coating of cBN particles. Using the simulation and analysis model, the effect of temperature on the formation of Ti-Cr coating during the reaction process was systematically analyzed, the molecular flow, the change of film thickness, and the deposition rate at different temperature stages was got, and verify the simulation results through experiments. The formation mechanism of Ti-Cr co-deposited coatings was derived by SEM, XRD characterization and reaction thermodynamic analysis. Experiments show that Ti-Cr co-deposited coatings are effective in increasing compressive strength, and the experimental results can be a guidance in controlling Ti/Cr amount in the coatings. In addition, it was found in experiments that by using vacuum vapor deposition technique, Ti/Cr powder mixing ratio of 1:1 provided the best compressive strength, and the compressive strength increased with higher Cr content in the coating after heating. This achievement is of significant importance for the formation of alloyed coatings on superhard materials, enhancing the wettability between the surfaces of superhard materials and their substrates under high-temperature conditions.
期刊介绍:
DRM is a leading international journal that publishes new fundamental and applied research on all forms of diamond, the integration of diamond with other advanced materials and development of technologies exploiting diamond. The synthesis, characterization and processing of single crystal diamond, polycrystalline films, nanodiamond powders and heterostructures with other advanced materials are encouraged topics for technical and review articles. In addition to diamond, the journal publishes manuscripts on the synthesis, characterization and application of other related materials including diamond-like carbons, carbon nanotubes, graphene, and boron and carbon nitrides. Articles are sought on the chemical functionalization of diamond and related materials as well as their use in electrochemistry, energy storage and conversion, chemical and biological sensing, imaging, thermal management, photonic and quantum applications, electron emission and electronic devices.
The International Conference on Diamond and Carbon Materials has evolved into the largest and most well attended forum in the field of diamond, providing a forum to showcase the latest results in the science and technology of diamond and other carbon materials such as carbon nanotubes, graphene, and diamond-like carbon. Run annually in association with Diamond and Related Materials the conference provides junior and established researchers the opportunity to exchange the latest results ranging from fundamental physical and chemical concepts to applied research focusing on the next generation carbon-based devices.