利用真空气相沉积技术在 cBN 颗粒表面镀 Ti-Cr 膜以增强抗压强度

IF 4.3 3区 材料科学 Q2 MATERIALS SCIENCE, COATINGS & FILMS Diamond and Related Materials Pub Date : 2024-11-09 DOI:10.1016/j.diamond.2024.111762
Yufei Jiang , Lili Fang , Weifei Yang
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引用次数: 0

摘要

为了提高 cBN 颗粒涂层的抗压强度,本研究提出利用真空气相沉积技术在 cBN 颗粒表面实现钛铬(Ti-Cr)共沉积涂层。在利用真空气相沉积技术实现钛铬涂层沉积过程的基础上,提出了角度系数法(ACM)模拟模型,并对 cBN 颗粒的钛铬涂层进行了抗压强度实验。利用模拟分析模型,系统分析了反应过程中温度对 Ti-Cr 涂层形成的影响,得到了不同温度阶段的分子流动、膜厚变化和沉积速率,并通过实验验证了模拟结果。通过扫描电镜、XRD 表征和反应热力学分析,得出了 Ti-Cr 共沉积涂层的形成机理。实验表明,Ti-Cr 共沉积涂层能有效提高抗压强度,实验结果可作为控制涂层中 Ti/Cr 用量的指导。此外,实验还发现,采用真空气相沉积技术,钛/铬粉末混合比为 1:1 时,抗压强度最佳,加热后涂层中的铬含量越高,抗压强度越大。这一成果对于在超硬材料上形成合金涂层、提高超硬材料表面与其基体在高温条件下的润湿性具有重要意义。
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Enhanced compressive strength by Ti-Cr coating on cBN particle surface using vacuum vapor deposition
In order to enhance compressive strength of the coating on cBN particles, this study proposes using vacuum vapor deposition to achieve a Titanium-Chromium (Ti-Cr) co-deposited coating on the surface of cBN particles. Base on deposition process of the Ti-Cr coating using vacuum vapor deposition technology, it proposed a simulation model by an Angular Coefficient Method (ACM), and conducts compressive strength experiments on the Ti-Cr coating of cBN particles. Using the simulation and analysis model, the effect of temperature on the formation of Ti-Cr coating during the reaction process was systematically analyzed, the molecular flow, the change of film thickness, and the deposition rate at different temperature stages was got, and verify the simulation results through experiments. The formation mechanism of Ti-Cr co-deposited coatings was derived by SEM, XRD characterization and reaction thermodynamic analysis. Experiments show that Ti-Cr co-deposited coatings are effective in increasing compressive strength, and the experimental results can be a guidance in controlling Ti/Cr amount in the coatings. In addition, it was found in experiments that by using vacuum vapor deposition technique, Ti/Cr powder mixing ratio of 1:1 provided the best compressive strength, and the compressive strength increased with higher Cr content in the coating after heating. This achievement is of significant importance for the formation of alloyed coatings on superhard materials, enhancing the wettability between the surfaces of superhard materials and their substrates under high-temperature conditions.
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来源期刊
Diamond and Related Materials
Diamond and Related Materials 工程技术-材料科学:综合
CiteScore
6.00
自引率
14.60%
发文量
702
审稿时长
2.1 months
期刊介绍: DRM is a leading international journal that publishes new fundamental and applied research on all forms of diamond, the integration of diamond with other advanced materials and development of technologies exploiting diamond. The synthesis, characterization and processing of single crystal diamond, polycrystalline films, nanodiamond powders and heterostructures with other advanced materials are encouraged topics for technical and review articles. In addition to diamond, the journal publishes manuscripts on the synthesis, characterization and application of other related materials including diamond-like carbons, carbon nanotubes, graphene, and boron and carbon nitrides. Articles are sought on the chemical functionalization of diamond and related materials as well as their use in electrochemistry, energy storage and conversion, chemical and biological sensing, imaging, thermal management, photonic and quantum applications, electron emission and electronic devices. The International Conference on Diamond and Carbon Materials has evolved into the largest and most well attended forum in the field of diamond, providing a forum to showcase the latest results in the science and technology of diamond and other carbon materials such as carbon nanotubes, graphene, and diamond-like carbon. Run annually in association with Diamond and Related Materials the conference provides junior and established researchers the opportunity to exchange the latest results ranging from fundamental physical and chemical concepts to applied research focusing on the next generation carbon-based devices.
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