用于储能的纳米级 Li2FeS2 的另一种合成途径。

IF 4.3 2区 化学 Q2 CHEMISTRY, MULTIDISCIPLINARY Chemical Communications Pub Date : 2024-11-27 DOI:10.1039/d4cc04748f
Ryan H DeBlock, Hunter O Ford, Meghanne E Tighe, Debra R Rolison, Jeffrey W Long
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引用次数: 0

摘要

富锂硫化铁(Li2FeS2)通过阳离子和阴离子位点表现出可逆的电荷存储能力,可存储近 400 mA h g-1,但其合成仅限于固态方法,会产生较大的原生颗粒。我们介绍了另一种基于溶液、以氧化还原为介导的方法来使黄铁矿 FeS2 锂化,最终形成纳米级的 Li2FeS2。
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An alternate synthetic pathway to nanoscopic Li2FeS2 for energy storage.

Lithium-rich iron sulphide, Li2FeS2, exhibits reversible charge-storage via both cationic and anionic sites, storing nearly 400 mA h g-1, but its synthesis is limited to solid-state methods that result in large primary particles. We describe an alternate solution-based, redox-mediated method to lithiate pyrite FeS2, ultimately forming nanoscale Li2FeS2.

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来源期刊
Chemical Communications
Chemical Communications 化学-化学综合
CiteScore
8.60
自引率
4.10%
发文量
2705
审稿时长
1.4 months
期刊介绍: ChemComm (Chemical Communications) is renowned as the fastest publisher of articles providing information on new avenues of research, drawn from all the world''s major areas of chemical research.
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