Kyuhyun Kim, Minsoo Kim, Yerim Kim, Jinhyeong Kim, Jihwan Lim, Woojin Lee, Han Seong Kim, Dong-Hyun Cho, Jaejun Lee, Sejin Choi
{"title":"用于塑料废物再利用的机械回收聚酰胺 6 与化学回收聚酰胺 6 的熔融纺丝性比较。","authors":"Kyuhyun Kim, Minsoo Kim, Yerim Kim, Jinhyeong Kim, Jihwan Lim, Woojin Lee, Han Seong Kim, Dong-Hyun Cho, Jaejun Lee, Sejin Choi","doi":"10.3390/polym16223152","DOIUrl":null,"url":null,"abstract":"<p><p>With the increasing volume of synthetic fiber waste, interest in plastic reuse technologies has grown. To address this issue, physical and chemical recycling techniques for polyamide, a major component of textile waste, have been developed. This study investigates the remelting and reforming properties of four types of pristine and recycled polyamide 6, focusing on how the microstructural arrangement of recycled polyamides affects polymer fiber formation. DSC and FT-IR were used to determine the thermal properties and chemical composition of the reformed thin films. Differences in the elongation behavior of molten fibers during the spinning process were also observed, and the morphology of the resulting fibers was examined via SEM. Birefringence analysis revealed that the uniformity of the molecular structure greatly influenced differences in the re-fiberization process, suggesting that chemically recycled polyamide is the most suitable material for re-fiberization with its high structural similarity to pristine polyamide.</p>","PeriodicalId":20416,"journal":{"name":"Polymers","volume":"16 22","pages":""},"PeriodicalIF":4.7000,"publicationDate":"2024-11-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Melt Spinnability Comparison of Mechanically and Chemically Recycled Polyamide 6 for Plastic Waste Reuse.\",\"authors\":\"Kyuhyun Kim, Minsoo Kim, Yerim Kim, Jinhyeong Kim, Jihwan Lim, Woojin Lee, Han Seong Kim, Dong-Hyun Cho, Jaejun Lee, Sejin Choi\",\"doi\":\"10.3390/polym16223152\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p><p>With the increasing volume of synthetic fiber waste, interest in plastic reuse technologies has grown. To address this issue, physical and chemical recycling techniques for polyamide, a major component of textile waste, have been developed. This study investigates the remelting and reforming properties of four types of pristine and recycled polyamide 6, focusing on how the microstructural arrangement of recycled polyamides affects polymer fiber formation. DSC and FT-IR were used to determine the thermal properties and chemical composition of the reformed thin films. Differences in the elongation behavior of molten fibers during the spinning process were also observed, and the morphology of the resulting fibers was examined via SEM. Birefringence analysis revealed that the uniformity of the molecular structure greatly influenced differences in the re-fiberization process, suggesting that chemically recycled polyamide is the most suitable material for re-fiberization with its high structural similarity to pristine polyamide.</p>\",\"PeriodicalId\":20416,\"journal\":{\"name\":\"Polymers\",\"volume\":\"16 22\",\"pages\":\"\"},\"PeriodicalIF\":4.7000,\"publicationDate\":\"2024-11-12\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Polymers\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://doi.org/10.3390/polym16223152\",\"RegionNum\":3,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"POLYMER SCIENCE\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Polymers","FirstCategoryId":"5","ListUrlMain":"https://doi.org/10.3390/polym16223152","RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"POLYMER SCIENCE","Score":null,"Total":0}
Melt Spinnability Comparison of Mechanically and Chemically Recycled Polyamide 6 for Plastic Waste Reuse.
With the increasing volume of synthetic fiber waste, interest in plastic reuse technologies has grown. To address this issue, physical and chemical recycling techniques for polyamide, a major component of textile waste, have been developed. This study investigates the remelting and reforming properties of four types of pristine and recycled polyamide 6, focusing on how the microstructural arrangement of recycled polyamides affects polymer fiber formation. DSC and FT-IR were used to determine the thermal properties and chemical composition of the reformed thin films. Differences in the elongation behavior of molten fibers during the spinning process were also observed, and the morphology of the resulting fibers was examined via SEM. Birefringence analysis revealed that the uniformity of the molecular structure greatly influenced differences in the re-fiberization process, suggesting that chemically recycled polyamide is the most suitable material for re-fiberization with its high structural similarity to pristine polyamide.
期刊介绍:
Polymers (ISSN 2073-4360) is an international, open access journal of polymer science. It publishes research papers, short communications and review papers. Our aim is to encourage scientists to publish their experimental and theoretical results in as much detail as possible. Therefore, there is no restriction on the length of the papers. The full experimental details must be provided so that the results can be reproduced. Polymers provides an interdisciplinary forum for publishing papers which advance the fields of (i) polymerization methods, (ii) theory, simulation, and modeling, (iii) understanding of new physical phenomena, (iv) advances in characterization techniques, and (v) harnessing of self-assembly and biological strategies for producing complex multifunctional structures.