利用生物废弃物在盐水介质中制备低合金钢缓蚀纳米填料MA/LS(芒果核灰/月桂酸处理SiO2)共混环氧涂料

IF 4.3 3区 材料科学 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY Materials Chemistry and Physics Pub Date : 2024-11-23 DOI:10.1016/j.matchemphys.2024.130179
Meenakshi Thakran , Sakshi Khokher , Simran Ahlawat , Neeru Jhanjhariya , Priti Pahuja , Monika Dhanda , Meena Yadav , Bhaskaran , Suman Lata
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引用次数: 0

摘要

本研究利用从当地果汁店收集的芒果果生物废弃物,采用简单的溶胶-凝胶技术制备了MA/LS(芒果核灰/月桂酸处理SiO2)复合材料,制备了低成本、无害的环氧涂料纳米缓蚀填料。将制备好的复合材料作为纳米填料加入环氧树脂中,得到复合环氧涂料(EP/MA-LS),并利用EIS和盐雾分析对其耐蚀性进行了测试。通过EIS FRA测量,EP/MA-LS的Rp值为2.27 × 108 Ω cm2,即使在3.5% NaCl中延长暴露51天后,保护效率也达到89.32%(通过动电位线性极化测量)。润湿性测试表明EP/MA-LS具有较高的疏水性,接触角为122.3°。通过热重分析和扫描电镜分析,发现EP/MA-LS的热稳定性和致密性都有所提高。
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Biowaste utilisation to fabricate corrosion retarding nanofiller MA/LS (Mango kernel ash/Lauric acid treated SiO2) blended epoxy coating for low alloyed carbon steel in saline medium
In present work, Mango fruit biowaste (collected from local juice shop) was utilised to fabricate MA/LS (Mango kernel ash/Lauric acid treated SiO2) composite by simple sol-gel technique, to fabricate low cost and non-hazardous corrosion retarding nanofiller for epoxy coating. Fabricated composite was added as nanofiller in epoxy to get composite epoxy coating (EP/MA-LS) and then was examined for corrosion resistance by utilising EIS and salt spray analysis. EP/MA-LS has offered excellent Rp value of 2.27 × 108 Ω cm2 as observed from EIS FRA measurement and protection efficiency of 89.32 % (measured from potentiodynamic linear polarisation) even after 51 days of prolong exposure in 3.5 % NaCl. Wettability examination of EP/MA-LS has demonstrated high hydrophobicity with contact angle of 122.3°. Improved thermal stability and better compactness was also observed for EP/MA-LS on examining with TGA and SEM respectively.
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来源期刊
Materials Chemistry and Physics
Materials Chemistry and Physics 工程技术-材料科学:综合
CiteScore
8.70
自引率
4.30%
发文量
1515
审稿时长
69 days
期刊介绍: Materials Chemistry and Physics is devoted to short communications, full-length research papers and feature articles on interrelationships among structure, properties, processing and performance of materials. The Editors welcome manuscripts on thin films, surface and interface science, materials degradation and reliability, metallurgy, semiconductors and optoelectronic materials, fine ceramics, magnetics, superconductors, specialty polymers, nano-materials and composite materials.
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