Kirill V. Zaitsev, Andrei D. Trubachev, Victor A. Tafeenko, Yurii F. Oprunenko
{"title":"双（三唑）有机双芒衍生物：合成、结构和性质","authors":"Kirill V. Zaitsev, Andrei D. Trubachev, Victor A. Tafeenko, Yurii F. Oprunenko","doi":"10.1016/j.mencom.2024.10.016","DOIUrl":null,"url":null,"abstract":"<div><div>The synthesis and molecular structure of the triazole- containing organodigermane [(4,1-BnC<sub>2</sub>HN<sub>3</sub>)Ph<sub>2</sub>Ge]<sub>2</sub> (C<sub>2</sub>HN<sub>3</sub> is 1,2,3-triazole-4,1-diyl) obtained under various conditions of the copper(i)–azide/alkyne cycloaddition are reported. Effective σ,π-conjugation in the compound between Ge–Ge, aryl and heterocyclic groups was established. The optical properties (absorption and fluorescence) of the digermane in MeCN and MeCN/H<sub>2</sub>O were evaluated, indicating the influence of the solvent.</div></div>","PeriodicalId":18542,"journal":{"name":"Mendeleev Communications","volume":"34 6","pages":"Pages 819-821"},"PeriodicalIF":1.8000,"publicationDate":"2024-11-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Bis(triazole) derivatives of organodigermanes: synthesis, structure, and properties\",\"authors\":\"Kirill V. Zaitsev, Andrei D. Trubachev, Victor A. Tafeenko, Yurii F. Oprunenko\",\"doi\":\"10.1016/j.mencom.2024.10.016\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>The synthesis and molecular structure of the triazole- containing organodigermane [(4,1-BnC<sub>2</sub>HN<sub>3</sub>)Ph<sub>2</sub>Ge]<sub>2</sub> (C<sub>2</sub>HN<sub>3</sub> is 1,2,3-triazole-4,1-diyl) obtained under various conditions of the copper(i)–azide/alkyne cycloaddition are reported. Effective σ,π-conjugation in the compound between Ge–Ge, aryl and heterocyclic groups was established. The optical properties (absorption and fluorescence) of the digermane in MeCN and MeCN/H<sub>2</sub>O were evaluated, indicating the influence of the solvent.</div></div>\",\"PeriodicalId\":18542,\"journal\":{\"name\":\"Mendeleev Communications\",\"volume\":\"34 6\",\"pages\":\"Pages 819-821\"},\"PeriodicalIF\":1.8000,\"publicationDate\":\"2024-11-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Mendeleev Communications\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0959943624003146\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Mendeleev Communications","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0959943624003146","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Bis(triazole) derivatives of organodigermanes: synthesis, structure, and properties
The synthesis and molecular structure of the triazole- containing organodigermane [(4,1-BnC2HN3)Ph2Ge]2 (C2HN3 is 1,2,3-triazole-4,1-diyl) obtained under various conditions of the copper(i)–azide/alkyne cycloaddition are reported. Effective σ,π-conjugation in the compound between Ge–Ge, aryl and heterocyclic groups was established. The optical properties (absorption and fluorescence) of the digermane in MeCN and MeCN/H2O were evaluated, indicating the influence of the solvent.
期刊介绍：
Mendeleev Communications is the journal of the Russian Academy of Sciences, launched jointly by the Academy of Sciences of the USSR and the Royal Society of Chemistry (United Kingdom) in 1991. Starting from 1st January 2007, Elsevier is the new publishing partner of Mendeleev Communications.
Mendeleev Communications publishes short communications in chemistry. The journal primarily features papers from the Russian Federation and the other states of the former USSR. However, it also includes papers by authors from other parts of the world. Mendeleev Communications is not a translated journal, but instead is published directly in English. The International Editorial Board is composed of eminent scientists who provide advice on refereeing policy.
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