十二烷基硫酸钠、偶氮二甲酰胺和十二烷基三甲基溴化铵水泥基尾填料的结构特征

IF 4.5 2区 工程技术 Q2 ENGINEERING, CHEMICAL Powder Technology Pub Date : 2024-11-28 DOI:10.1016/j.powtec.2024.120507
Tingting Jiang , Shuai Cao , Erol Yilmaz
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引用次数: 0

摘要

水泥基尾填料的沉降和孔隙分布不均匀严重影响矿山充填采场的安全。为了进一步改善采空区的稳定性,发现发泡剂可以改善CTF的沉降特性。为了更好地配制含fa的矿山充填体,现有研究采用了三种主要的fa,即十二烷基硫酸钠(SDS)、偶氮二甲酰胺(AC)和十二烷基三甲基溴化铵(DTAB)。通过UCS试验和微观结构解释对FCTF试样的宏微观性能进行了全面的研究。实验结果表明,不同类型的FA可增强CTF的作用:SDS;dtab - 0.4%、ac - 0.4%和sds - 0.6%为最佳剂量率,等效峰强度分别为0.7 MPa、0.43 MPa和0.55 MPa。与None相比,FCTF试件的强度进步分别提高了22%、- 27%和- 7%。此外,沿加载方向观察到FCTF的破坏形式以剪切破坏形式发生。CTF试样在应力-应变曲率上表现出明显的延性,说明FA能很好地抑制裂纹的扩展。综上所述,研究成果为尾矿综合利用提供了一条新的途径。
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Structural characteristics of cement-based tail fill with sodium dodecyl sulfate, azodicarbonamide, and dodecyl trimethyl ammonium bromide
The safety of mine-filled stopes is seriously affected by settlement and uneven pore distribution of cement-based tail fill (CTF). To further improve the mined-out areas' stability, it is found that foaming agents (FAs) can improve CTF's settlement characteristics. To better formulate FA-covered mine backfills (FCTFs), three principal FAs, namely, sodium dodecyl sulfate (SDS), azodicarbonamide (AC), and dodecyl trimethylammonium bromide (DTAB), were embraced in the existing research. Macro/micro properties of FCTF specimens were thoroughly examined by UCS tests and microstructure interpretations. Lab findings illustrate that diverse types of FA enhance CTF effects: DTAB>AC > SDS; DTAB-0.4 %, AC-0.4 % and SDS-0.6 % are the best dosage rates, and equivalent peak intensities are 0.7 MPa, 0.43 MPa and 0.55 MPa, respectively. Compared to None, the strength progress of FCTF specimens increased by 22 %, −27 %, and −7 %, respectively. Besides, FCTF's failure style is observed to happen in the form of shear failure along the loading direction. CTF specimens showed obvious ductility on stress-strain curvature, indicating that FA could well inhibit the expansion of cracks. To sum up, the research results can deliver a new way for comprehensive utilization of tailings.
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来源期刊
Powder Technology
Powder Technology 工程技术-工程:化工
CiteScore
9.90
自引率
15.40%
发文量
1047
审稿时长
46 days
期刊介绍: Powder Technology is an International Journal on the Science and Technology of Wet and Dry Particulate Systems. Powder Technology publishes papers on all aspects of the formation of particles and their characterisation and on the study of systems containing particulate solids. No limitation is imposed on the size of the particles, which may range from nanometre scale, as in pigments or aerosols, to that of mined or quarried materials. The following list of topics is not intended to be comprehensive, but rather to indicate typical subjects which fall within the scope of the journal's interests: Formation and synthesis of particles by precipitation and other methods. Modification of particles by agglomeration, coating, comminution and attrition. Characterisation of the size, shape, surface area, pore structure and strength of particles and agglomerates (including the origins and effects of inter particle forces). Packing, failure, flow and permeability of assemblies of particles. Particle-particle interactions and suspension rheology. Handling and processing operations such as slurry flow, fluidization, pneumatic conveying. Interactions between particles and their environment, including delivery of particulate products to the body. Applications of particle technology in production of pharmaceuticals, chemicals, foods, pigments, structural, and functional materials and in environmental and energy related matters. For materials-oriented contributions we are looking for articles revealing the effect of particle/powder characteristics (size, morphology and composition, in that order) on material performance or functionality and, ideally, comparison to any industrial standard.
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