冲击压缩对NiCo2O4纳米颗粒光伏性能的影响

IF 3.2 4区 化学 Q2 CHEMISTRY, ANALYTICAL Luminescence Pub Date : 2024-12-02 DOI:10.1002/bio.70043
J. Bosco Franklin, P. Saravanan, S. Suruthi, F. Irine Maria Bincy, S. John Sundaram, S. A. Martin Britto Dhas, Mohammad Ahmad Wadaan, Jothi Vinoth Kumar, R. Mythili
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引用次数: 0

摘要

采用简单的溶胶-凝胶法合成了球形钴酸镍纳米颗粒,并在600℃下煅烧。x射线衍射(XRD)分析显示,对照样品的晶粒尺寸发生了显著变化,平均为23 nm,经过50次冲击波后观察到变化。傅里叶变换红外光谱(FTIR)证实了金属氧拉伸,表明结构完整。紫外-可见吸收研究表明,在冲击处理后,光学带隙发生了变化,这表明带隙可调性可用于光电和光伏应用。该材料表现出良好的光吸收,可达600 nm,使其适合于光收集设备。振动样品磁强计(VSM)检测到偶极矩和磁饱和度的变化,所有样品都显示出顺磁性行为。经过冲击处理的样品显示出增强的磁性,这在磁存储设备中是有用的。通过冲击波处理的带隙和磁性能的组合可调性强调了这些纳米颗粒在光伏、自旋电子学和储能系统中的应用潜力。
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Impact of Shock Compression on the Photovoltaic Performance of NiCo2O4 Nanoparticles

Spherical-shaped nickel cobaltite (NC) nanoparticles were synthesized via a simple sol–gel technique and calcined at 600°C. X-ray diffraction (XRD) analysis revealed significant changes in crystallite size, with an average of 23 nm for the control sample and variations observed after 50 shockwaves. Fourier transform infrared spectroscopy (FTIR) confirmed metal-oxygen stretching, indicating structural integrity. UV–visible absorption studies showed changes in the optical band gap, which increased after shock treatments, suggesting bandgap tunability for optoelectronic and photovoltaic applications. The material exhibited good optical absorption up to 600 nm, making it suitable for light-harvesting devices. Vibrating sample magnetometry (VSM) detected shifts in dipole moments and magnetic saturation, with all samples displaying paramagnetic behavior. The shock-treated samples showed enhanced magnetic properties, which could be useful in magnetic storage devices. The combined tunability of bandgap and magnetic properties via shock wave treatment underscores the potential of these nanoparticles for applications in photovoltaics, spintronics, and energy storage systems.

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来源期刊
Luminescence
Luminescence 生物-生化与分子生物学
CiteScore
5.10
自引率
13.80%
发文量
248
审稿时长
3.5 months
期刊介绍: Luminescence provides a forum for the publication of original scientific papers, short communications, technical notes and reviews on fundamental and applied aspects of all forms of luminescence, including bioluminescence, chemiluminescence, electrochemiluminescence, sonoluminescence, triboluminescence, fluorescence, time-resolved fluorescence and phosphorescence. Luminescence publishes papers on assays and analytical methods, instrumentation, mechanistic and synthetic studies, basic biology and chemistry. Luminescence also publishes details of forthcoming meetings, information on new products, and book reviews. A special feature of the Journal is surveys of the recent literature on selected topics in luminescence.
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