碘辅助钯催化丙烯的等选择氢甲酰化反应

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摘要

在本来文中,计算tof(更替频率)的公式中出现了笔误,导致原出版物中图234、5所报告的数值高出10倍。(图7中与丙烯以外的烯烃反应的数据没有错误)。修改后的数值正确的数字如下图1234所示。此外,所有TOF值在修订后的原始出版物的主要文本和修订后的支持信息附在原始出版物中进行了更正。该误差不影响所开发的含碘钯催化剂获得的等选择性,因此,它不影响论文的结论。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

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BERICHTIGUNG: Isoselective Hydroformylation of Propylene by Iodide-Assisted Palladium Catalysis

In this Communication, a clerical error was made in the formula for calculating TOFs (turnover frequencies), which resulted in 10-fold higher values reported in Figures 234, 5 in the original publication. (There are no errors in the data in Figure 7 for reactions with alkenes other than propylene). The revised figures with correct values are depicted below as Figures 1234. Furthermore, all TOF values were corrected in the revised main text of the original publication and the revised Supporting Information attached to the original publication. This error does not influence the isoselectivity obtained by the developed iodide-containing palladium catalysts, and as such, it does not impact the conclusions of the manuscript.

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Angewandte Chemie
Angewandte Chemie 化学科学, 有机化学, 有机合成
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