Yuyang Dai , Yu Wang , Liliang Wang , Fan Qi , Qianli Li , Lingbing Kong
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Crystalline potassium boryl dithiolate and diselenolate†
Both the B–S and S–S bonds of 1,2,4,3,5-trithiadiborolane 1 could be cleaved by potassium graphite (KC8) to give the first isolable boryl dithiolate DmpB(SK)2, whereas the reduction of 1,2,4-triselena-3,5-diborolane with KC8 afforded the boryl diselenolate DmpB(SeK)(SeSeK) , showcasing the unprecedented structural authentication of ligand substituted diselenolate.
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