[北京地区PM2.5重金属污染特征、来源、健康风险变化及政策效果评价]。

Q2 Environmental Science 环境科学 Pub Date : 2024-11-08 DOI:10.13227/j.hjkx.202312063
Wei Zhang, Tong Lü, Jian-Wei Liu, Yue Gao, Xu Zhou, Hong-Bin Cao
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引用次数: 0

摘要

为了评价北京市大气污染防治措施的效果,本研究通过对北京市城区4年PM2.5日采样(n = 934),测量了13种金属元素的含量,其中包括7种重金属元素[As、Cd、Co、Cr(Ⅵ)、Ni、Pb和V]。分析了不同金属浓度水平的年际变化和采暖季与非采暖季的差异,采用正定矩阵分解(PMF)模型进行定量来源分析,并采用健康风险评价方法对6种金属的健康风险进行评价。结果表明,除Cr(Ⅵ)、Ni等少数金属元素浓度在个别年份呈上升趋势外,各元素总体浓度呈下降趋势。采暖季V、Co、Pb、Mn等10种金属浓度显著高于非采暖季(P<0.05)。北京市大气重金属污染源主要有五大类型:扬尘源、交通源、煤炭源、工业源和燃油燃烧源。其中,煤炭来源占比总体呈下降趋势。各金属的HQ值均小于1,无非致癌健康风险。Ni、Cd的致癌风险可以忽略,而As、Co、Cr(Ⅵ)每年的R值在10-6 ~ 10-4之间,具有一定的致癌风险。大气浓度、污染源和健康风险的年际变化趋势表明,北京市大气污染防治措施取得了积极成效。
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[Characteristics, Sources, and Health Risk Changes of Heavy Metal Pollution Carried by PM2.5 in Beijing and Evaluation of Policy Effectiveness].

To evaluate the effectiveness of air pollution prevention and control measures in Beijing, this study measured the content of 13 metal elements, including seven heavy metal elements [As, Cd, Co, Cr(Ⅵ), Ni, Pb, and V], through daily PM2.5 sampling (n = 934) in the urban area of Beijing for four years. We analyzed the interannual changes in the concentration levels of various metals and the differences between heating and non-heating seasons, used a positive definite matrix factorization (PMF) model for quantitative source analysis, and used health risk assessment methods to evaluate the health risks of six metals. The results showed that, except for a few metal elements such as Cr(Ⅵ) and Ni, which showed an increase in concentration in individual years, the overall concentration of each element showed a downward trend. The concentrations of ten metals, including V, Co, Pb, and Mn, during the heating season were significantly higher than those during the non-heating season (P<0.05). There were five main types of atmospheric heavy metal pollution sources in Beijing: dust sources, transportation sources, coal sources, industrial sources, and fuel oil combustion sources. Among them, the proportion of coal sources was generally decreasing. The HQ values of each metal were all less than 1, indicating no non-carcinogenic health risk. The carcinogenic risk of Ni and Cd could be ignored, while the R values of As, Co, and Cr(Ⅵ) in each year were between 10-6 and 10-4, indicating a certain carcinogenic risk. The interannual trends in atmospheric concentration, sources, and health risks indicate that the relevant measures for air pollution prevention and control in Beijing have achieved positive results.

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来源期刊
环境科学
环境科学 Environmental Science-Environmental Science (all)
CiteScore
4.40
自引率
0.00%
发文量
15329
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