新型二茂铁和钌茂烯基镍螯合物

IF 1.7 4区 化学 Q3 CHEMISTRY, MULTIDISCIPLINARY Russian Chemical Bulletin Pub Date : 2024-12-06 DOI:10.1007/s11172-024-4399-z
S. V. Safronov, S. A. Kuklin, N. V. Abramova, Yu. V. Nelyubina
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引用次数: 0

摘要

首先合成了二茂铁镍螯合物NiCl[{2,5-(But2PCH2)2C5H2}Fe(C5H5)] (3a)和NiCl[{2,5-(But2PCH2)2C5H2}Ru(C5H5)] (3b),并用1H、31P{1H}和13C{1H} NMR对其进行了表征。通过单晶x射线衍射确定了配合物3b的结构。
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New ferrocene- and ruthenocene-based nickel pincer complexes

First ferrocene- and ruthenocene-based nickel pincer complexes, NiCl[{2,5-(But2PCH2)2C5H2}Fe(C5H5)] (3a) and NiCl[{2,5-(But2PCH2)2C5H2}Ru(C5H5)] (3b), respectively, were synthesized and characterized by 1H, 31P{1H}, and 13C{1H} NMR spectroscopy. The structure of complex 3b was established by single-crystal X-ray diffraction.

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来源期刊
Russian Chemical Bulletin
Russian Chemical Bulletin 化学-化学综合
CiteScore
2.70
自引率
47.10%
发文量
257
审稿时长
3-8 weeks
期刊介绍: Publishing nearly 500 original articles a year, by leading Scientists from Russia and throughout the world, Russian Chemical Bulletin is a prominent international journal. The coverage of the journal spans practically all areas of fundamental chemical research and is presented in five sections: General and Inorganic Chemistry; Physical Chemistry; Organic Chemistry; Organometallic Chemistry; Chemistry of Natural Compounds and Bioorganic Chemistry.
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