L. S. Konstantinova, A. S. Chechulina, N. V. Obruchnikova, E. A. Knyazeva, Bin Kan, Tainan Duan, Yongsheng Chen, O. A. Rakitin
{"title":"萘[2,3-c][1,2,5]噻二唑-4,9-二酮的溴化","authors":"L. S. Konstantinova, A. S. Chechulina, N. V. Obruchnikova, E. A. Knyazeva, Bin Kan, Tainan Duan, Yongsheng Chen, O. A. Rakitin","doi":"10.1007/s11172-024-4420-6","DOIUrl":null,"url":null,"abstract":"<div><p>Investigations of bromination of naphtho[2,3-<i>c</i>][1,2,5]thiadiazole-4,9-dione revealed that the reaction proceeded most efficiently with <i>N</i>-bromosuccinimide in sulfuric acid and depending on the reaction conditions, can give mono-, di-, tri- and tetrabromo derivatives of naphtho[2,3-<i>c</i>][1,2,5]thiadiazole-4,9-dione. A series of the major isomers was isolated, and their structure was proven using heteronuclear multiple bond correlation NMR spectroscopy and high-resolution mass spectrometry.</p></div>","PeriodicalId":756,"journal":{"name":"Russian Chemical Bulletin","volume":"73 10","pages":"3038 - 3044"},"PeriodicalIF":1.7000,"publicationDate":"2024-12-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Bromination of naphtho[2,3-c][1,2,5]thiadiazole-4,9-dione\",\"authors\":\"L. S. Konstantinova, A. S. Chechulina, N. V. Obruchnikova, E. A. Knyazeva, Bin Kan, Tainan Duan, Yongsheng Chen, O. A. Rakitin\",\"doi\":\"10.1007/s11172-024-4420-6\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Investigations of bromination of naphtho[2,3-<i>c</i>][1,2,5]thiadiazole-4,9-dione revealed that the reaction proceeded most efficiently with <i>N</i>-bromosuccinimide in sulfuric acid and depending on the reaction conditions, can give mono-, di-, tri- and tetrabromo derivatives of naphtho[2,3-<i>c</i>][1,2,5]thiadiazole-4,9-dione. A series of the major isomers was isolated, and their structure was proven using heteronuclear multiple bond correlation NMR spectroscopy and high-resolution mass spectrometry.</p></div>\",\"PeriodicalId\":756,\"journal\":{\"name\":\"Russian Chemical Bulletin\",\"volume\":\"73 10\",\"pages\":\"3038 - 3044\"},\"PeriodicalIF\":1.7000,\"publicationDate\":\"2024-12-06\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Russian Chemical Bulletin\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s11172-024-4420-6\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Russian Chemical Bulletin","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1007/s11172-024-4420-6","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Bromination of naphtho[2,3-c][1,2,5]thiadiazole-4,9-dione
Investigations of bromination of naphtho[2,3-c][1,2,5]thiadiazole-4,9-dione revealed that the reaction proceeded most efficiently with N-bromosuccinimide in sulfuric acid and depending on the reaction conditions, can give mono-, di-, tri- and tetrabromo derivatives of naphtho[2,3-c][1,2,5]thiadiazole-4,9-dione. A series of the major isomers was isolated, and their structure was proven using heteronuclear multiple bond correlation NMR spectroscopy and high-resolution mass spectrometry.
期刊介绍:
Publishing nearly 500 original articles a year, by leading Scientists from Russia and throughout the world, Russian Chemical Bulletin is a prominent international journal. The coverage of the journal spans practically all areas of fundamental chemical research and is presented in five sections:
General and Inorganic Chemistry;
Physical Chemistry;
Organic Chemistry;
Organometallic Chemistry;
Chemistry of Natural Compounds and Bioorganic Chemistry.