{"title":"锅炉过热管深峰过程氧化膜失效行为分析","authors":"Chuang He, Tingshan Guo, Qinxin Zhao, Zhiyuan Liang","doi":"10.1016/j.supflu.2024.106474","DOIUrl":null,"url":null,"abstract":"<div><div>High-temperature components in the supercritical power plant experienced alternating thermal stresses under deep peak regulation, accelerating the cracking and spalling of the oxide film formed on the steam-side of super-heaters and re-heaters. This study employed the corrosion testing and finite element simulations to investigate the failure behavior of oxide films on super-heaters made by heat-resistant steelsT91 and austenitic HR3C during deep peak conditions. The experimental results indicate that the oxide film on T91was a double layer film containing Fe<sub>3</sub>O<sub>4</sub> and Fe-Cr oxides, which was much thicker than that on HR3C. The spalling of the outer oxide film on T91 was more severe than that of HR3C. The analysis of thermal stress-strain under various loads and oxide film thicknesses revealed the significant shear stress between Fe<sub>3</sub>O<sub>4</sub> and Fe-Cr within the oxide film on T91 steel. The significant shear stress caused the bigger strain within the oxide film on T91 steel, causing the spalling of the oxide film. Compared to the strain within the oxide film on T91 steel, the stress-strain within Cr<sub>2</sub>O<sub>3</sub> oxide film on HR3C steel was notably lower than that on T91 steel. The failure behaviors of the oxide film on T91 and HR3C were quantitatively explained through experimental result and stress-strain simulation with the oxide film. The failure models of the oxide film on investigated steels were put forward.</div></div>","PeriodicalId":17078,"journal":{"name":"Journal of Supercritical Fluids","volume":"218 ","pages":"Article 106474"},"PeriodicalIF":4.4000,"publicationDate":"2025-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Failure behavior analysis of oxide film formed on super-heater tubes of boiler during deep peak process\",\"authors\":\"Chuang He, Tingshan Guo, Qinxin Zhao, Zhiyuan Liang\",\"doi\":\"10.1016/j.supflu.2024.106474\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>High-temperature components in the supercritical power plant experienced alternating thermal stresses under deep peak regulation, accelerating the cracking and spalling of the oxide film formed on the steam-side of super-heaters and re-heaters. This study employed the corrosion testing and finite element simulations to investigate the failure behavior of oxide films on super-heaters made by heat-resistant steelsT91 and austenitic HR3C during deep peak conditions. The experimental results indicate that the oxide film on T91was a double layer film containing Fe<sub>3</sub>O<sub>4</sub> and Fe-Cr oxides, which was much thicker than that on HR3C. The spalling of the outer oxide film on T91 was more severe than that of HR3C. The analysis of thermal stress-strain under various loads and oxide film thicknesses revealed the significant shear stress between Fe<sub>3</sub>O<sub>4</sub> and Fe-Cr within the oxide film on T91 steel. The significant shear stress caused the bigger strain within the oxide film on T91 steel, causing the spalling of the oxide film. Compared to the strain within the oxide film on T91 steel, the stress-strain within Cr<sub>2</sub>O<sub>3</sub> oxide film on HR3C steel was notably lower than that on T91 steel. The failure behaviors of the oxide film on T91 and HR3C were quantitatively explained through experimental result and stress-strain simulation with the oxide film. The failure models of the oxide film on investigated steels were put forward.</div></div>\",\"PeriodicalId\":17078,\"journal\":{\"name\":\"Journal of Supercritical Fluids\",\"volume\":\"218 \",\"pages\":\"Article 106474\"},\"PeriodicalIF\":4.4000,\"publicationDate\":\"2025-04-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Supercritical Fluids\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0896844624003097\",\"RegionNum\":3,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"2024/11/27 0:00:00\",\"PubModel\":\"Epub\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, PHYSICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Supercritical Fluids","FirstCategoryId":"5","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0896844624003097","RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"2024/11/27 0:00:00","PubModel":"Epub","JCR":"Q2","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
Failure behavior analysis of oxide film formed on super-heater tubes of boiler during deep peak process
High-temperature components in the supercritical power plant experienced alternating thermal stresses under deep peak regulation, accelerating the cracking and spalling of the oxide film formed on the steam-side of super-heaters and re-heaters. This study employed the corrosion testing and finite element simulations to investigate the failure behavior of oxide films on super-heaters made by heat-resistant steelsT91 and austenitic HR3C during deep peak conditions. The experimental results indicate that the oxide film on T91was a double layer film containing Fe3O4 and Fe-Cr oxides, which was much thicker than that on HR3C. The spalling of the outer oxide film on T91 was more severe than that of HR3C. The analysis of thermal stress-strain under various loads and oxide film thicknesses revealed the significant shear stress between Fe3O4 and Fe-Cr within the oxide film on T91 steel. The significant shear stress caused the bigger strain within the oxide film on T91 steel, causing the spalling of the oxide film. Compared to the strain within the oxide film on T91 steel, the stress-strain within Cr2O3 oxide film on HR3C steel was notably lower than that on T91 steel. The failure behaviors of the oxide film on T91 and HR3C were quantitatively explained through experimental result and stress-strain simulation with the oxide film. The failure models of the oxide film on investigated steels were put forward.
期刊介绍：
The Journal of Supercritical Fluids is an international journal devoted to the fundamental and applied aspects of supercritical fluids and processes. Its aim is to provide a focused platform for academic and industrial researchers to report their findings and to have ready access to the advances in this rapidly growing field. Its coverage is multidisciplinary and includes both basic and applied topics.
Thermodynamics and phase equilibria, reaction kinetics and rate processes, thermal and transport properties, and all topics related to processing such as separations (extraction, fractionation, purification, chromatography) nucleation and impregnation are within the scope. Accounts of specific engineering applications such as those encountered in food, fuel, natural products, minerals, pharmaceuticals and polymer industries are included. Topics related to high pressure equipment design, analytical techniques, sensors, and process control methodologies are also within the scope of the journal.
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